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Quinoxaline

CAS No.
91-19-0
Chemical Name:
Quinoxaline
Synonyms
1,4-BENZODIAZINE;BENZOPYRAZINE;BENZOPARADIAZINE;1,4-Naphthyridine;QuinoxaL;Quinazine;Chinoxalin;QUINOXALINE;usafek-7094;Phenpiazine
CBNumber:
CB0737379
Molecular Formula:
C8H6N2
Molecular Weight:
130.15
MDL Number:
MFCD00006719
MOL File:
91-19-0.mol
MSDS File:
SDS
Last updated:2023-05-25 18:00:57

Quinoxaline Properties

Melting point 29-32 °C (lit.)
Boiling point 220-223 °C (lit.)
Density 1.124 g/mL at 25 °C (lit.)
refractive index nD48 1.6231
Flash point 209 °F
storage temp. 2-8°C
solubility alcohol: freely soluble(lit.)
pka 0.56(at 20℃)
form Crystalline Low Melting Solid
color Light yellow to brown
Water Solubility SOLUBLE
Merck 14,8078
BRN 109351
Stability Light Sensitive
LogP 1.320
CAS DataBase Reference 91-19-0(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII QM4AR6M6T8
NIST Chemistry Reference Quinoxaline(91-19-0)
EPA Substance Registry System Quinoxaline (91-19-0)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P280a-P304+P340-P305+P351+P338-P405-P501a-P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313
Hazard Codes  Xi
Risk Statements  36/37/38-36/38
Safety Statements  26-36-37/39
WGK Germany  3
RTECS  VD1225000
Hazard Note  Irritant
TSCA  Yes
HS Code  29339990
NFPA 704
1
2 0

Quinoxaline price More Price(26)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TCI Chemical Q0020 Quinoxaline >99.0%(GC)(T) 91-19-0 25g $64 2024-03-01 Buy
Alfa Aesar A14055 Quinoxaline, 98+% 91-19-0 100g $53.65 2024-03-01 Buy
Alfa Aesar A14055 Quinoxaline, 98+% 91-19-0 500g $212.65 2024-03-01 Buy
Sigma-Aldrich Q1603 Quinoxaline 99% 91-19-0 25g $39.1 2024-03-01 Buy
Alfa Aesar A14055 Quinoxaline, 98+% 91-19-0 2500g $987 2021-12-16 Buy
Product number Packaging Price Buy
Q0020 25g $64 Buy
A14055 100g $53.65 Buy
A14055 500g $212.65 Buy
Q1603 25g $39.1 Buy
A14055 2500g $987 Buy

Quinoxaline Chemical Properties,Uses,Production

Chemical Properties

light yellow to brown crystalline

Uses

Organic synthesis.

Uses

Quinoxaline is a reagent used in the synthesis of quinoxaline diimides as small molecule non-fullerene acceptors for organic solar cells.

Definition

ChEBI: A naphthyridine in which the nitrogens are at positions 1 and 4.

Synthesis Reference(s)

Journal of the American Chemical Society, 69, p. 795, 1947 DOI: 10.1021/ja01196a015
The Journal of Organic Chemistry, 55, p. 1744, 1990 DOI: 10.1021/jo00293a014
Organic Syntheses, Coll. Vol. 4, p. 824, 1963

General Description

Transition metal-free acylation of quinoxaline derivatives, by cross dehydrogenative coupling (CDC) reaction, were studied.

Purification Methods

Crystallise quinoxaline from pet ether. It crystallises as the monohydrate on addition of water to a pet ether solution. It has UV: at 242 and 331nm (Ho –2); 234 and 316nm (pH 7.1). The picrate has m 161-162o.[Albert & Phillips J Chem Soc 1294 1956, Beilstein 23 H 176, 23 II 177, 23 III/IV 1226, 23/7 V 135.]

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View Lastest Price from Quinoxaline manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Quinoxaline pictures 2022-09-27 Quinoxaline
91-19-0
US $0.00-0.00 / KG 1KG 98% 1ton Henan Aochuang Chemical Co.,Ltd.
Quinoxaline  pictures 2022-03-04 Quinoxaline
91-19-0
US $1.10 / g 1g 99.00% 100 Tons Dideu Industries Group Limited
Quinoxaline pictures 2021-10-14 Quinoxaline
91-19-0
US $10.00 / KG 1KG 99% 20 tons Hebei Zhanyao Biotechnology Co. Ltd
  • Quinoxaline pictures
  • Quinoxaline
    91-19-0
  • US $0.00-0.00 / KG
  • 98%
  • Henan Aochuang Chemical Co.,Ltd.
  • Quinoxaline  pictures
  • Quinoxaline
    91-19-0
  • US $1.10 / g
  • 99.00%
  • Dideu Industries Group Limited
  • Quinoxaline pictures
  • Quinoxaline
    91-19-0
  • US $10.00 / KG
  • 99%
  • Hebei Zhanyao Biotechnology Co. Ltd
1,4-Benxodiazine Phenopiazine Phenpiazine Quinazine USAF EK-7094 usafek-7094 QUINOXALINE PHENPYRAZINE BENZO(A)PYRAZINE 1,4-DIAZANAPHTHALENE QUINOXALINE 98% Quinoxaline,97% 1,4-Benzodiazine,Benzopyrazine POTASSIUMSODIUMDEHYDROANDROGRAPOLIDESUCCINATE Quinoxaline, 98+% Benzo-p-azine Quinoxaline,99% Quinoxaline,1,4-Benzodiazine, Benzopyrazine (5R,8S,9S,10S,13S,14S,17S)-17-hydroxy-10,13,17-trimethyl-2,3,4,5,6,7,8,9,12,14,15,16-dodecahydro-1H-cyclopenta[a]phenanthren-11-one Quinoxaline > QuinoxaL Quinoxaline ISO 9001:2015 REACH 1,4-Naphthyridine BENZOPARADIAZINE BENZOPYRAZINE 1,4-BENZODIAZINE Chinoxalin 91-19-0 Building Blocks Heterocyclic Building Blocks Quinoxalines Building Blocks Chemical Synthesis Heterocyclic Building Blocks Quinoxalines Benzenes Quinolines, Quinazolines and derivatives Heterocyclic Compounds