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methyl 2-[[2-methyl-3-[4-(1-methylethyl)phenyl]propylidene]amino]benzoate

CAS No.
91-50-9
Chemical Name:
methyl 2-[[2-methyl-3-[4-(1-methylethyl)phenyl]propylidene]amino]benzoate
Synonyms
Einecs 202-072-0;CYCLAMENALDEHYDEMETHYLANTHRANILATE;Cyclamen aldehyde-methyl anthranilate (Schiff base);Methyl-2-[[2-methyl-3-[4-(1-methylethyl)phenyl]propyliden]amino]benzoat;methyl 2-[[2-methyl-3-[4-(1-methylethyl)phenyl]propylidene]amino]benzoate;Benzoic acid, 2-2-methyl-3-4-(1-methylethyl)phenylpropylideneamino-, methyl ester;2-((2-Methyl-3-(4-(1-methylethyl)phenyl)propylidene)amino)benzoic acid, methyl ester
CBNumber:
CB0901482
Molecular Formula:
C21H25NO2
Molecular Weight:
323.43
MDL Number:
MOL File:
91-50-9.mol
Last updated:2024-06-24 17:38:28

methyl 2-[[2-methyl-3-[4-(1-methylethyl)phenyl]propylidene]amino]benzoate Properties

Boiling point 461.2±45.0 °C(Predicted)
Density 1.01±0.1 g/cm3(Predicted)
pka 3.90±0.50(Predicted)
Odor at 50.00 % in dipropylene glycol. fresh lily of the valley neroli orange flower
Odor Type floral
LogP 7.249 (est)
CAS DataBase Reference 91-50-9
FDA UNII 78J2J6IE6R
EPA Substance Registry System Benzoic acid, 2-[[2-methyl-3-[4-(1-methylethyl)phenyl]propylidene]amino]-, methyl ester (91-50-9)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H317
Precautionary statements  P261-P272-P280-P302+P352-P333+P313-P321-P363-P501

methyl 2-[[2-methyl-3-[4-(1-methylethyl)phenyl]propylidene]amino]benzoate Chemical Properties,Uses,Production

Chemical Properties

Yellowish viscous liquid, barely pourable at room temperature. Almost insoluble in water and Propylene glycol. Soluble in alcohol and perfume oils. Intensely sweet, fresh-floral odor of great tenacity, somewhat reminiscent of the flowers of the Lemon tree. Greener and more diffusive than Hydroxycitronellal-Methylanthranilate.

Uses

Finds some use in perfume compositions, probably ranking No. 3 among Schiff’s bases after Aurantiol and Acaciol. Its fresher odor type and less “Orangeblossom”’-character are its main assets.

Synthesis

Methyl 2-[[2-methyl-3-[4-(1-methylethyl)phenyl]propylidene]amino]benzoate is prepared by condensation of Cyclamenaldehyde and Methylanthranilate.

methyl 2-[[2-methyl-3-[4-(1-methylethyl)phenyl]propylidene]amino]benzoate Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 3)Suppliers
Supplier Tel Email Country ProdList Advantage
Hubei Jusheng Technology Co.,Ltd.
18871490254 linda@hubeijusheng.com CHINA 28180 58
TCI (Shanghai) Chemical Trading Co., Ltd. 021-61109150 13761280536; sales@tcisct.com China 31163 58
Shaanxi DIDU pharmaceutical and Chemical Co., Ltd 15229059051 1027@dideu.com China 9965 58

91-50-9(methyl 2-[[2-methyl-3-[4-(1-methylethyl)phenyl]propylidene]amino]benzoate )Related Search:

methyl 2-[[2-methyl-3-[4-(1-methylethyl)phenyl]propylidene]amino]benzoate Benzoic acid, 2-2-methyl-3-4-(1-methylethyl)phenylpropylideneamino-, methyl ester CYCLAMENALDEHYDEMETHYLANTHRANILATE Cyclamen aldehyde-methyl anthranilate (Schiff base) Methyl-2-[[2-methyl-3-[4-(1-methylethyl)phenyl]propyliden]amino]benzoat 2-((2-Methyl-3-(4-(1-methylethyl)phenyl)propylidene)amino)benzoic acid, methyl ester Einecs 202-072-0 91-50-9