METHYL 2-(3-BROMO-4-HYDROXYPHENYL)ACETATE
- CAS No.
- 34918-57-5
- Chemical Name:
- METHYL 2-(3-BROMO-4-HYDROXYPHENYL)ACETATE
- Synonyms
- METHYL 2-(3-BROMO-4-HYDROXYPHENYL)ACETATE;Benzeneacetic acid, 3-bromo-4-hydroxy-, methyl ester
- CBNumber:
- CB13561567
- Molecular Formula:
- C9H9BrO3
- Molecular Weight:
- 245.07
- MDL Number:
- MFCD16293381
- MOL File:
- 34918-57-5.mol
- MSDS File:
- SDS
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|---|---|
| Signal word | Warning |
| Hazard statements | H315-H319 |
| Precautionary statements | P264-P280-P302+P352-P337+P313-P305+P351+P338-P362+P364-P332+P313 |
METHYL 2-(3-BROMO-4-HYDROXYPHENYL)ACETATE price
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Ambeed | A213006 | Methyl2-(3-bromo-4-hydroxyphenyl)acetate 95% | 34918-57-5 | 100mg | $30 | 2021-12-16 | Buy |
| Ambeed | A213006 | Methyl2-(3-bromo-4-hydroxyphenyl)acetate 95% | 34918-57-5 | 250mg | $40 | 2021-12-16 | Buy |
| Ambeed | A213006 | Methyl2-(3-bromo-4-hydroxyphenyl)acetate 95% | 34918-57-5 | 1g | $98 | 2021-12-16 | Buy |
| Ambeed | A213006 | Methyl2-(3-bromo-4-hydroxyphenyl)acetate 95% | 34918-57-5 | 5g | $327 | 2021-12-16 | Buy |
| Chemenu | CM252396 | Methyl2-(3-bromo-4-hydroxyphenyl)acetate 95% | 34918-57-5 | 1g | $385 | 2021-12-16 | Buy |
METHYL 2-(3-BROMO-4-HYDROXYPHENYL)ACETATE Chemical Properties,Uses,Production
Synthesis
67-56-1
38692-80-7
34918-57-5
Step 1: Synthesis of methyl 2-(3-bromo-4-hydroxyphenyl)acetate 3-Bromo-4-hydroxyphenylacetic acid (0.3 g, 1.3 mmol, 1.0 equiv) and concentrated H2SO4 (2.77 μL, 0.05 mmol, 0.04 equiv) were dissolved in methanol (10 mL). The reaction mixture was stirred for 1 h at room temperature. Upon completion of the reaction, the reaction was quenched with NaOH solution and subsequently extracted with ethyl acetate (EtOAc). The organic layers were combined, dried with anhydrous Na2SO4 and concentrated under reduced pressure. The crude product was purified by silica gel column chromatography (eluent: hexane/EtOAc = 5:1) to afford the target compound methyl 2-(3-bromo-4-hydroxyphenyl)acetate (0.2 g, 63% yield).LCMS m/z 245.0 [M + 1]+.
References
[1] Patent: WO2004/62661, 2004, A1. Location in patent: Page/Page column 28
[2] Patent: WO2010/138901, 2010, A1. Location in patent: Page/Page column 155
[3] Yakugaku Zasshi, 1933, vol. 53, p. 557,563; dtsch. Ref. S. 92
[4] Chem.Abstr., 1933, p. 4223
[5] Patent: WO2004/50637, 2004, A2. Location in patent: Page 74
METHYL 2-(3-BROMO-4-HYDROXYPHENYL)ACETATE Preparation Products And Raw materials
Raw materials
Preparation Products
METHYL 2-(3-BROMO-4-HYDROXYPHENYL)ACETATE Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| CR Corporation Limited | +8613062833949 | fred.wen@crcorporation.cn | China | 8647 | 58 |
| Hangzhou MolCore BioPharmatech Co.,Ltd. | +86-057181025280; +8617767106207 | sales@molcore.com | China | 49734 | 58 |
| Shandong Liteng Biotechnology Co. , Ltd. | +86-18663721413 +86-15552573001 | rosy@litengpharm.com | China | 3285 | 58 |
| Amadis Chemical Company Limited | 571-89925085 | sales@amadischem.com | China | 131957 | 58 |
| Bide Pharmatech Ltd. | 400-164-7117 13681763483 | product02@bidepharm.com | China | 42446 | 60 |
| Shanghai Na Qian Chemical Technology Co. Ltd. | 0373-7129549; 13598610367 | 2841375912@qq.com | China | 2768 | 52 |
| DebyeTec.com Inc. | 18086626237 15327221536; | sales@debyesci.com | China | 3001 | 56 |
| Shanghai SuperLan Chemcial Technique Centre | 0-2022843681 15618226720 | chaolaichem@foxmail.com | China | 9989 | 58 |
| Dalian lichuang Chemical Co., Ltd | 0411-0411-00000000 13644282108 | 3500508746@qq.com | China | 2896 | 55 |
| Rhawn Reagent | 400-400-1332688 18019345275 | amy@rhawn.cn | China | 15497 | 58 |
