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(1R,2R)-(+)-1-PHENYLPROPYLENE OXIDE

(1R,2R)-(+)-1-PHENYLPROPYLENE OXIDE structure

CAS No.: 14212-54-5

Chemical Name:: (1R,2R)-(+)-1-PHENYLPROPYLENE OXIDE

Synonyms: (2r-trans)-oxiran;1-phenylpropylene oxide;(r,r)-phenylpropyleneoxide;2-epoxypropyl)benzene(1r,2r)-(;(1,2-epoxypropyl)-,(1r,2r)-benzen;[(2R,3R)-3-Methyloxiranyl]benzene;(1R,2R)-(+)-1-PHENYLPROPYLENE OXIDE;(2R,3R)-(+)-2-METHYL-3-PHENYLOXIRANE;[2R,3R,(+)]-3-Methyl-2-phenyloxirane;(1r,2r)-(+)-1-phenyl-1,2-epoxypropane

CBNumber:: CB2263647

Molecular Formula:: C9H10O

Molecular Weight:: 134.18

MDL Number:: MFCD00064482

MOL File:: 14212-54-5.mol

Last updated:2022-11-11 11:01:00

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(1R,2R)-(+)-1-PHENYLPROPYLENE OXIDE Properties

Boiling point	201-207 °C(lit.)
Density	1.006 g/mL at 25 °C(lit.)
refractive index	n20/D 1.518(lit.)
Flash point	156 °F
optical activity	[α]20/D +110°, neat

SAFETY

Risk and Safety Statements

Symbol(GHS)	GHS07
Signal word	Warning
Hazard statements	H315-H319-H335
Precautionary statements	P261-P305+P351+P338
Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	26-36
WGK Germany	3
RTECS	DA0177000

(1R,2R)-(+)-1-PHENYLPROPYLENE OXIDE price More Price(2)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
American Custom Chemicals Corporation	CCH0002952	(1R,2R)-(+)-1-PHENYLPROPYLENE OXIDE 95.00%	14212-54-5	1G	$751.3	2021-12-16	Buy
AHH	MT-21263	(1R,2R)-(+)-1-Phenylpropylene oxide 97%	14212-54-5	10g	$425	2021-12-16	Buy

Product number	Packaging	Price	Buy
CCH0002952	1G	$751.3	Buy
MT-21263	10g	$425	Buy

(1R,2R)-(+)-1-PHENYLPROPYLENE OXIDE Chemical Properties,Uses,Production

Synthesis

A solution of 0.05 M Na2HPO4 (10.0 mL) was added to a 25-mL solution of undiluted commercial household bleach (Clorox). The pH of the resulting buffered solution (0.55 M in NaOCl) was adjusted to pH 11.3 by addition of a few drops of 1 M NaOH solution. This solution was cooled to 0 °C and then added at once to a 0 °C solution of the manganese catalyst (260 mg, 0.4 mmol) and cis-o-methylstyrene (1.18 g, 10 mmol) in 10 mL of CH2Cl2. The two-phase mixture was stirred at room temperature, and the reaction progress was monitored by TLC. After 3 h, 100 mL of hexane was added to the mixture and the brown organic phase was separated, washed twice with 100 mL of H2O and once with 100 mL of saturated NaCl solution, and then dried (Na2SO4). After solvent removal, the residue was purifified by flflash chromatography on silica gel to afford the epoxide (0.912 g, 68%). The ee of the epoxide was determined to be 84% by 1 H NMR analysis in the presence of Eu(hfc)3.
(1R,2R)-(+)-1-PHENYLPROPYLENE OXIDE
Reference: Zhang, W.; Jacobsen, E. N. J. Org. Chem. 1991, 56, 2296−2298.

Uses

Chiral building block. Tool for studying enzyme hydrolysis rates.

(1R,2R)-(+)-1-PHENYLPROPYLENE OXIDE synthesis

Synthesis of (1R,2R)-(+)-1-PHENYLPROPYLENE OXIDE from TRANS-BETA-METHYLSTYRENE

(1R,2R)-(+)-1-PHENYLPROPYLENE OXIDE Preparation Products And Raw materials

Raw materials

CIS-STILBENE OXIDE TRANS-BETA-METHYLSTYRENE β-Methylstyrene CIS-STILBENE

Preparation Products

Oxirane, 2-methyl-3-phenyl-, (2R,3S)- (1S,2S)-(-)-1-PHENYLPROPYLENE OXIDE Benzaldehyde

(1R,2R)-(+)-1-PHENYLPROPYLENE OXIDE Suppliers

Global( 12)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Energy Chemical	021-021-58432009 400-005-6266	sales8178@energy-chemical.com	China	44751	61
Sigma-Aldrich	021-61415566 800-8193336	orderCN@merckgroup.com	China	51471	80
Shandong Ono Chemical Co., Ltd.	0539-6362799 20）		China	9998	58
Aikon International Limited	025-66113011 18112977050	sales01@aikonchem.com	China	16028	58
Nanjing Shizhou Biology Technology Co.,Ltd	13675144456	sean.lv@synzest.com	China	10787	58
QUALITY CONTROL SOLUTIONS LTD.	0755-66853366 13670046396	orders@qcsrm.com	China	18810	58

Supplier	Advantage
Energy Chemical	61
Sigma-Aldrich	80
Shandong Ono Chemical Co., Ltd.	58
Aikon International Limited	58
Nanjing Shizhou Biology Technology Co.,Ltd	58
QUALITY CONTROL SOLUTIONS LTD.	58

View Lastest Price from (1R,2R)-(+)-1-PHENYLPROPYLENE OXIDE manufacturers

Image	Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
	2021-07-02	(1R,2R)-(+)-1-Phenylpropylene oxide 14212-54-5	US $15.00-10.00 / KG	1KG	99%+ HPLC	Monthly supply of 1 ton	Zhuozhou Wenxi import and Export Co., Ltd

(1R,2R)-(+)-1-Phenylpropylene oxide
14212-54-5
US $15.00-10.00 / KG
99%+ HPLC
Zhuozhou Wenxi import and Export Co., Ltd

(1R,2R)-(+)-1-PHENYLPROPYLENE OXIDE Spectrum

(1R,2R)-(+)-1-PHENYLPROPYLENE OXIDE(14212-54-5)¹HNMR (1R,2R)-(+)-1-PHENYLPROPYLENE OXIDE(14212-54-5)Raman

14212-54-5((1R,2R)-(+)-1-PHENYLPROPYLENE OXIDE)Related Search:

2-PHENYLPROPYLENE OXIDE (1S,2S)-(-)-1-PHENYLPROPYLENE OXIDE (1R,2R)-(+)-1-PHENYLPROPYLENE OXIDE 2,2-DIMETHYL-3,3-DIPHENYLOXIRANE Methyl 3-(4-methoxyphenyl)oxirane-2-carboxylate

6A-METHYL-5A,6,6A,7,8,9,9A,9B,10,11-DECAHYDROCYCLOPENTA[7,8]PHENANTHRO[4B,5-B]OXIRENE-2,7-DIOL dynemicin A TRANS-STILBENE OXIDE [3-(2-NITROPHENYL)OXIRAN-2-YL](PHENYL)METHANONE TETRAPHENYLETHYLENE OXIDE

TRANS-1,3-DIPHENYL-2,3-EPOXYPROPAN-1-ONE TRANS-4-PHENYLCHALCONE OXIDE HYPOTHEMYCIN (2R,3R)-3-PHENYLGLYCIDOL 2-(ACETYLOXY)-6A-METHYL-5A,6,6A,7,8,9,9A,9B,10,11-DECAHYDROCYCLOPENTA[7,8]PHENANTHRO[4B,5-B]OXIREN-7-YL ACETATE

(2R,3R)-(+)-2,3-EPOXY-3-(4-NITROPHENYL)-1-PROPANOL

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(1R,2R)-(+)-1-PHENYLPROPYLENE OXIDE 1-phenylpropylene oxide [(2R,3R)-3-Methyloxiranyl]benzene [2R,3R,(+)]-3-Methyl-2-phenyloxirane (1R,2R)-(+)-1-Phenylpropylene oxide 97% (1,2-epoxypropyl)-,(1r,2r)-benzen (1r,2r)-(+)-1-phenyl-1,2-epoxypropane (2r-trans)-oxiran (r,r)-phenylpropyleneoxide 2-epoxypropyl)benzene(1r,2r)-( (2R,3R)-(+)-2-METHYL-3-PHENYLOXIRANE Oxirane, 2-methyl-3-phenyl-, (2R,3R)- (9CI) Oxirane, 2-methyl-3-phenyl-, (2R,3R)- 14212-54-5 Epoxides Organic Building Blocks Chiral Building Blocks Asymmetric Synthesis EPOXYDE