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4'-(4-AMINOPHENYL)-2,2':6',2''-TERPYRIDINE

4'-(4-AMINOPHENYL)-2,2':6',2''-TERPYRIDINE structure

CAS No.: 178265-65-1

Chemical Name:: 4'-(4-AMINOPHENYL)-2,2':6',2''-TERPYRIDINE

Synonyms: 4'-(4-Aminophenyl)-2,2':6',2;4'-(4-aminophenyl)-2,2':6',2-terpyridine;4-(2,6-dipyridin-2-ylpyridin-4-yl)aniline;4-([2,2':6',2''-Terpyridin]-4'-yl)aniline;4'-(4-AMINOPHENYL)-2,2':6',2''-TERPYRIDINE;4'-(4-aminophenyl)-2,2':6',2"-tribipyridine;BenzenaMine, 4-[2,2':6',2''-terpyridin]-4'-yl-

CBNumber:: CB2486288

Molecular Formula:: C21H16N4

Molecular Weight:: 324.38

MDL Number:: MFCD06796989

MOL File:: 178265-65-1.mol

MSDS File:: SDS

Last updated:2025-07-24 18:13:43

Product description	Number	Pack Size	Price
4-([2,2':6',2''-Terpyridin]-4'-yl)aniline	0885CS	5g	$625
4-([2,2':6',2''-Terpyridin]-4'-yl)aniline	0885CS	100mg	$108
4-([2,2':6',2''-Terpyridin]-4'-yl)aniline 97%	A494540	1g	$139
4-([2,2':6',2''-Terpyridin]-4'-yl)aniline 95+%	CD11229767	250mg	$223
4-([2,2':6',2''-Terpyridin]-4'-yl)aniline 97%	A494540	5g	$419

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4'-(4-AMINOPHENYL)-2,2':6',2''-TERPYRIDINE Properties

Melting point	253-254 °C
Boiling point	513.0±45.0 °C(Predicted)
Density	1.213±0.06 g/cm3(Predicted)
storage temp.	Keep in dark place,Inert atmosphere,Room temperature
pka	4.72±0.22(Predicted)
Appearance	Off-white to yellow Solid
InChI	InChI=1S/C21H16N4/c22-17-9-7-15(8-10-17)16-13-20(18-5-1-3-11-23-18)25-21(14-16)19-6-2-4-12-24-19/h1-14H,22H2
InChIKey	CYISWQZYBSHTNN-UHFFFAOYSA-N
SMILES	C1(N)=CC=C(C2C=C(C3=NC=CC=C3)N=C(C3=NC=CC=C3)C=2)C=C1

SAFETY

Risk and Safety Statements

Symbol(GHS)	GHS07
Signal word	Warning
Hazard statements	H302-H315-H320-H335
Precautionary statements	P261-P280-P301+P312-P302+P352-P305+P351+P338

4'-(4-AMINOPHENYL)-2,2':6',2''-TERPYRIDINE price

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
AK Scientific	0885CS	4-([2,2':6',2''-Terpyridin]-4'-yl)aniline	178265-65-1	5g	$625	2021-12-16	Buy
AK Scientific	0885CS	4-([2,2':6',2''-Terpyridin]-4'-yl)aniline	178265-65-1	100mg	$108	2021-12-16	Buy
Ambeed	A494540	4-([2,2':6',2''-Terpyridin]-4'-yl)aniline 97%	178265-65-1	1g	$139	2021-12-16	Buy
Crysdot	CD11229767	4-([2,2':6',2''-Terpyridin]-4'-yl)aniline 95+%	178265-65-1	250mg	$223	2021-12-16	Buy
Ambeed	A494540	4-([2,2':6',2''-Terpyridin]-4'-yl)aniline 97%	178265-65-1	5g	$419	2021-12-16	Buy

Product number	Packaging	Price	Buy
0885CS	5g	$625	Buy
0885CS	100mg	$108	Buy
A494540	1g	$139	Buy
CD11229767	250mg	$223	Buy
A494540	5g	$419	Buy

4'-(4-AMINOPHENYL)-2,2':6',2''-TERPYRIDINE Chemical Properties,Uses,Production

Synthesis

4'-(4-NITROPHENYL)-2,2':6',2''-TERPYRIDINE

129077-51-6

178265-65-1

The general procedure for the synthesis of 4'-(4-aminophenyl)-2,2':6',2''-terpyridine from 4'-(4-nitrophenyl)-2,2':6',2''-terpyridine is as follows: the synthesis was carried out by referring to the method reported by Das et al. with appropriate modifications [30]. The procedure was as follows: in a 500 mL round bottom flask, 0.95 g of 4'-(4-nitrophenyl)-2,2':6',2''-terpyridine (2.7 mmol), 250 mg of palladium-carbon catalyst (5% Pd loading), and 200 mL of anhydrous ethanol were added. The resulting suspension was purged with argon for 15 min, followed by refluxing under argon protection. 3.4 mL of hydrazine monohydrate (3.5 g, 70 mmol) was added to the reaction system and refluxing was continued under argon protection for 2 h until 4'-(4-nitrophenyl)-2,2':6',2''-terpyridine was completely dissolved. After completion of the reaction, the reaction solution was cooled to room temperature, the catalyst was removed by vacuum filtration through a short column of diatomaceous earth and the filter cake was washed with dichloromethane (3 x 100 mL). The filtrate was concentrated under reduced pressure to about 75 mL until white needle-like crystals were observed to start precipitating. Subsequently, the saturated solution was placed at 4 °C for overnight crystallization. The precipitated crystals were collected by vacuum filtration and washed with cold ethanol (3 x 50 mL) to give the final 4'-(4-aminophenyl)-2,2':6',2''-terpyridine as white needle-like crystals. Yield: 547 mg (1.7 mmol, 63% yield). The 1H NMR spectrum of the product was in agreement with data reported in the literature [30].

References

[1] Journal of the American Chemical Society, 2002, vol. 124, # 7, p. 1364 - 1377
[2] Journal of the American Chemical Society, 2011, vol. 133, # 23, p. 8961 - 8971
[3] Chemical Communications, 2007, # 19, p. 1899 - 1901
[4] Organic and Biomolecular Chemistry, 2013, vol. 11, # 28, p. 4602 - 4612
[5] European Journal of Inorganic Chemistry, 2018, vol. 2018, # 18, p. 1882 - 1890

4'-(4-AMINOPHENYL)-2,2':6',2''-TERPYRIDINE synthesis

Synthesis of 4'-(4-AMINOPHENYL)-2,2':6',2''-TERPYRIDINE from 4-Nitrobenzaldehyde

4'-(4-AMINOPHENYL)-2,2':6',2''-TERPYRIDINE Preparation Products And Raw materials

Raw materials

2-Propen-1-one, 3-(4-bromophenyl)-1-(2-pyridinyl)-, (2E)- 2-Propen-1-one, 3-(4-nitrophenyl)-1-(2-pyridinyl)-, (2E)- 4'-(4-NITROPHENYL)-2,2':6',2''-TERPYRIDINE PyridiniuM, 1-[2-oxo-2-(2-pyridinyl)ethyl]-, iodide 4'-(4-BROMOPHENYL)-2,2':6',2''-TERPYRIDINE

4-Acetamidobenzaldehyde 4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)aniline 4'-CHLORO-2,2':6',2''-TERPYRIDINE 2-Acetylpyridine 4-Bromobenzaldehyde

4-Aminobenzaldehyde 4-Nitrobenzaldehyde

1of3

Preparation Products

4'-(4-AMINOPHENYL)-2,2':6',2''-TERPYRIDINE Suppliers

Global( 61)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Shanghai UCHEM Inc.	+862156762820 +86-13564624040	sales@myuchem.com	China	8792	58
career henan chemical co	+86-0371-86658258 +8613203830695	factory@coreychem.com	China	29795	58
Shanghai Daeyeon Chemicals Co., Ltd	021-64478606 +8615900664856	daeyeon001@vip.163.com	China	2062	58
Henan Alfa Chemical Co., Ltd	+8615838112936	sale03@alfachem.cn	China	9659	58
Alfa Chemistry	+1-5166625404;	Info@alfa-chemistry.com	United States	20405	58
SUZHOU SENFEIDA CHEMICAL CO.,LTD	+86-0512-83500002 +8618662433356	3899766280@qq.com	China	26362	58
HANGZHOU LEAP CHEM CO., LTD.	+86-571-87711850	market18@leapchem.com	China	43333	58
Jilin Chinese Academy of Sciences-yanshen Technology	+undefined18143011203	info@chemextension.com	China	42056	58
Aladdin Scientific		tp@aladdinsci.com	United States	52923	58
Shanghai Hanhong Scientific Co., Ltd.	+undefined17612118332	Lucky@hanhonggroup.com	China	5844	58

Supplier	Advantage
Shanghai UCHEM Inc.	58
career henan chemical co	58
Shanghai Daeyeon Chemicals Co., Ltd	58
Henan Alfa Chemical Co., Ltd	58
Alfa Chemistry	58
SUZHOU SENFEIDA CHEMICAL CO.,LTD	58
HANGZHOU LEAP CHEM CO., LTD.	58
Jilin Chinese Academy of Sciences-yanshen Technology	58
Aladdin Scientific	58
Shanghai Hanhong Scientific Co., Ltd.	58

View Lastest Price from 4'-(4-AMINOPHENYL)-2,2':6',2''-TERPYRIDINE manufacturers

Image	Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
	2026-04-29	4'-(4-Aminophenyl)-2,2':6',2 178265-65-1	US $92.00-620.00 / g	1g	0.97	25kg	Shanghai UCHEM Inc.
	2020-02-02	4'-(4-AMINOPHENYL)-2,2':6',2''-TERPYRIDINE 178265-65-1	US $3.00 / KG	1KG	98%	100KG	Career Henan Chemical Co

4'-(4-Aminophenyl)-2,2':6',2
178265-65-1
US $92.00-620.00 / g
0.97
Shanghai UCHEM Inc.

4'-(4-AMINOPHENYL)-2,2':6',2''-TERPYRIDINE
178265-65-1
US $3.00 / KG
98%
Career Henan Chemical Co

4'-(4-AMINOPHENYL)-2,2':6',2''-TERPYRIDINE Spectrum

4'-(4-AMINOPHENYL)-2,2':6',2''-TERPYRIDINE(178265-65-1)¹HNMR

178265-65-1(4'-(4-AMINOPHENYL)-2,2':6',2''-TERPYRIDINE)Related Search:

4'-PHENYL-2,2':6',2''-TERPYRIDINE 4'-(4-NITROPHENYL)-2,2':6',2''-TERPYRIDINE 4-(PYRIDIN-4-YL)ANILINE 4'-(4-AMINOPHENYL)-2,2':6',2''-TERPYRIDINE

4'-(4-AMINOPHENYL)-2,2':6',2''-TERPYRIDINE BenzenaMine, 4-[2,2':6',2''-terpyridin]-4'-yl- 4-([2,2':6',2''-Terpyridin]-4'-yl)aniline 4-(2,6-dipyridin-2-ylpyridin-4-yl)aniline 4'-(4-Aminophenyl)-2,2':6',2 4'-(4-aminophenyl)-2,2':6',2-terpyridine 4'-(4-aminophenyl)-2,2':6',2"-tribipyridine 178265-65-1