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4-FLUOROPHENYLMAGNESIUM BROMIDE

4-FLUOROPHENYLMAGNESIUM BROMIDE structure

CAS No.: 352-13-6

Chemical Name:: 4-FLUOROPHENYLMAGNESIUM BROMIDE

Synonyms: 4-FL;uorophenyL;4-FluorophenylMagnes;4-FLUOROPHENYLMAGNESIUM BROMIDE;4-flourophenylmagnesium bromide;magnesium,fluorobenzene,bromide;p-Fluoro-phenylmagnesium bromide;Magnesium, bromo(4-fluorophenyl)-;4-fluorophenylmagnesiumbromidesol.;4-Fluorophenylmagnesium bromide 1.0

CBNumber:: CB3166792

Molecular Formula:: C6H4BrFMg

Molecular Weight:: 199.3

MDL Number:: MFCD00009667

MOL File:: 352-13-6.mol

MSDS File:: SDS

Last updated:2023-04-23 13:52:06

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4-FLUOROPHENYLMAGNESIUM BROMIDE Properties

Melting point	5 °C
Boiling point	66°C
Density	1.043 g/mL at 25 °C
Flash point	−40 °F
storage temp.	Flammables + water-Freezer (-20°C)e area
form	Solution
color	Clear yellow to red-brown
Water Solubility	It reacts violently with water.
Sensitive	Air & Moisture Sensitive
BRN	636802
InChIKey	QYBFFRXNNFXREA-UHFFFAOYSA-M
CAS DataBase Reference	352-13-6
EPA Substance Registry System	Magnesium, bromo(4-fluorophenyl)- (352-13-6)

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS02,GHS05,GHS07,GHS08

Signal word

Danger

Hazard statements

H225-H302-H314-H335-H351-H336-H318-H371-H372

Precautionary statements

P233-P240-P241+P242+P243-P264-P270-P271-P301+P330+P331+P310-P303+P361+P353+P310+P363-P304+P340+P310-P305+P351+P338+P310-P308+P311-P403+P233-P405-P501-P260h-P303+P361+P353-P501a-P210-P260-P280-P305+P351+P338-P370+P378-P403+P235-P261-P310

Hazard Codes

F+,C,F

Risk Statements

12-14-22-34-66-67-11-40-37-19

Safety Statements

16-26-36/37/39-43-45-7/8-33-8-7

RIDADR

UN 2924 3/PG 2

WGK Germany

10-21

TSCA

Yes

HazardClass

PackingGroup

HS Code

29319090

NFPA 704

	3
3		2
	W

4-FLUOROPHENYLMAGNESIUM BROMIDE price More Price(15)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	328820	4-Fluorophenylmagnesium bromide solution 1.0?M in THF	352-13-6	4X25ML	$99.6	2024-03-01	Buy
Sigma-Aldrich	245550	4-Fluorophenylmagnesium bromide solution 2.0M in diethyl ether	352-13-6	100ml	$97.2	2024-03-01	Buy
Sigma-Aldrich	245550	4-Fluorophenylmagnesium bromide solution 2.0M in diethyl ether	352-13-6	800ml	$207	2024-03-01	Buy
TCI Chemical	F0673	4-Fluorophenylmagnesium Bromide (ca. 19% in Tetrahydrofuran, ca. 1.0mol/L)	352-13-6	250g	$103	2024-03-01	Buy
Sigma-Aldrich	328820	4-Fluorophenylmagnesium bromide solution 1.0 M in THF	352-13-6	100ml	$68.2	2024-03-01	Buy

Product number	Packaging	Price	Buy
328820	4X25ML	$99.6	Buy
245550	100ml	$97.2	Buy
245550	800ml	$207	Buy
F0673	250g	$103	Buy
328820	100ml	$68.2	Buy

4-FLUOROPHENYLMAGNESIUM BROMIDE Chemical Properties,Uses,Production

Chemical Properties

clear yellow to red-brown solution

Uses

4-Fluorophenylmagnesium bromide solution (Grignard reagent) can be used as a reagent in the synthesis of:

Useful key intermediate in the synthesis of paroxetine.
Arylsulfides via cross-coupling reaction with thiols.
4-Arylmethyl-1-phenylpyrazole and 4-aryloxy-1-phenylpyrazole derivatives as androgen receptor antagonists.
Grignard intermediate for preparing aprepitant.

Uses

4-Fluorophenylmagnesium bromide is used as a reagent for the introduction of the 4-Fluorophenyl group.

4-FLUOROPHENYLMAGNESIUM BROMIDE synthesis

Synthesis of 4-FLUOROPHENYLMAGNESIUM BROMIDE from 4-Bromofluorobenzene

4-FLUOROPHENYLMAGNESIUM BROMIDE Preparation Products And Raw materials

Raw materials

Preparation Products

4-Fluorobenzeneboronic acid 4-(4-FLUORO-PHENYL)-PIPERIDIN-4-OL HYDROCHLORIDE 1-Fluoro-4-(1-methylethenyl)benzene 2-(4-Fluorophenyl)-pyrrolidine 4-Fluoro-1,1'-biphenyl

BIS-(4-FLUORO-PHENYL)-PHENYL-METHANOL (3R,4S)-4-[4-(Benzyloxy)phenyl]-1-(4-fluorophenyl)-3-[3-(4-fluorophenyl)-3-oxopropyl]azetidin-2-one

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4-FLUOROPHENYLMAGNESIUM BROMIDE Suppliers

Global( 209)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Hangzhou FandaChem Co.,Ltd.	008657128800458; +8615858145714	fandachem@gmail.com	China	9348	55
Nanjing ChemLin Chemical Industry Co., Ltd.	025-83697070	product@chemlin.com.cn	CHINA	3012	60
career henan chemical co	+86-0371-86658258	sales@coreychem.com	China	29914	58
SHANDONG ZHI SHANG CHEMICAL CO.LTD	+86 18953170293	sales@sdzschem.com	China	2931	58
Hubei xin bonus chemical co. LTD	86-13657291602	linda@hubeijusheng.com	CHINA	22968	58
Chongqing Chemdad Co., Ltd	+86-023-61398051 +8613650506873	sales@chemdad.com	China	39916	58
CONIER CHEM AND PHARMA LIMITED	+8618523575427	sales@conier.com	China	49390	58
Zhengzhou Alfa Chemical Co.,Ltd	+8618530059196	sale04@alfachem.cn	China	12468	58
SIMAGCHEM CORP	+86-13806087780	sale@simagchem.com	China	17367	58
Hefei TNJ Chemical Industry Co.,Ltd.	0551-65418671	sales@tnjchem.com	China	34572	58

Supplier	Advantage
Hangzhou FandaChem Co.,Ltd.	55
Nanjing ChemLin Chemical Industry Co., Ltd.	60
career henan chemical co	58
SHANDONG ZHI SHANG CHEMICAL CO.LTD	58
Hubei xin bonus chemical co. LTD	58
Chongqing Chemdad Co., Ltd	58
CONIER CHEM AND PHARMA LIMITED	58
Zhengzhou Alfa Chemical Co.,Ltd	58
SIMAGCHEM CORP	58
Hefei TNJ Chemical Industry Co.,Ltd.	58

View Lastest Price from 4-FLUOROPHENYLMAGNESIUM BROMIDE manufacturers

Image	Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
	2019-07-06	4-Fluorophenylmagnesium bromide 352-13-6	US $1.00 / kg	1kg	99%	Customized	Career Henan Chemical Co

4-Fluorophenylmagnesium bromide
352-13-6
US $1.00 / kg
99%
Career Henan Chemical Co

352-13-6(4-FLUOROPHENYLMAGNESIUM BROMIDE)Related Search:

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4-FLUOROPHENYLMAGNESIUM BROMIDE Diethyl ether PHENYLMAGNESIUM BROMIDE

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