ChemicalBook >> CAS DataBase List >>CHLOZOLINATE

CHLOZOLINATE

CAS No.
84332-86-5
Chemical Name:
CHLOZOLINATE
Synonyms
SERINAL;Manderol;SDS 65311;Clozolinate;CHLOZOLINATE;Chlozolinate 1;Einecs 282-714-4;Chlozolinate [iso];Chlozolinate Standard;chlozolinate (bsi,iso)
CBNumber:
CB4358743
Molecular Formula:
C13H11Cl2NO5
Molecular Weight:
332.14
MDL Number:
MFCD00143964
MOL File:
84332-86-5.mol
Last updated:2023-05-04 17:34:43

CHLOZOLINATE Properties

Melting point 110-114 °C
Boiling point 420.8±55.0 °C(Predicted)
Density 1.479
vapor pressure 1.3 x 10-5 Pa (25 °C)
Flash point 100 °C
storage temp. 0-6°C
Water Solubility 2 mg l-1 (25 °C)
pka -4.24±0.40(Predicted)
EWG's Food Scores 2
FDA UNII 6YW05QFN1Y

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS02,GHS07,GHS08,GHS09
Signal word  Danger
Hazard statements  H225-H304-H315-H336-H410
Precautionary statements  P210-P261-P273-P301+P310-P331-P501
Hazard Codes  Xn,N,F
Risk Statements  40-51/53-67-65-50/53-38-11-20
Safety Statements  36/37-61-62-60-33-25-16-9
RIDADR  UN3077 9/PG 3
WGK Germany  2
HS Code  29251900

CHLOZOLINATE price More Price(8)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 33743 Chlozolinate solution 100μg/mL in cyclohexane, PESTANAL 84332-86-5 2ml $74.5 2022-05-15 Buy
TRC C989138 Chlozolinate 84332-86-5 25mg $880 2021-12-16 Buy
TRC C989138 Chlozolinate 84332-86-5 50mg $1680 2021-12-16 Buy
American Custom Chemicals Corporation PST0000442 CHLOZOLINATE 98.00% 84332-86-5 10MG $924 2021-12-16 Buy
Crysdot CD11048026 Ethyl3-(3,5-dichlorophenyl)-5-methyl-2,4-dioxooxazolidine-5-carboxylate 95+% 84332-86-5 1g $972 2021-12-16 Buy
Product number Packaging Price Buy
33743 2ml $74.5 Buy
C989138 25mg $880 Buy
C989138 50mg $1680 Buy
PST0000442 10MG $924 Buy
CD11048026 1g $972 Buy

CHLOZOLINATE Chemical Properties,Uses,Production

Uses

Chlozolinate is a dicarboximide fungicide which is used primarily on grapes.

Uses

Chlozolinate controls fruit rot, downy mildew and brown rot in pome and stone fruits, vines, vegetables, strawberries and ornamentals caused by Botrytis, Monilia and Sclerotinia, efc.

Definition

ChEBI: Ethyl 3-(3,5-dichlorophenyl)-5-methyl-2,4-dioxo-1,3-oxazolidine-5-carboxylate is the ethyl ester of 3-(3,5-dichlorophenyl)-5-methyl-2,4-dioxo-1,3-oxazolidine-5-carboxylic acid. It is a dichlorobenzene, an oxazolidinone, a dicarboximide and an ethyl ester.

General Description

Chlozolinate is a systemic fungicide, used for the control of downy mildew, brown rot, and fruit rot in agricultural commodities.

Metabolic pathway

The fungicides, chlozolinate, vinclozolin, and procymidone, are added to wine after fermentation and the degradation products are isolated and identified. Chlozolinate undergoes a rapid hydrolytic loss of the ethoxycarbonyl substituent to give an oxazolidine that further undergoes hydrolytic cleavage to give 3' ,5' -dichloro-2-hydroxypropanilide. The oxazolidine ring of vinclozolin undergoes a similar hydrolysis reaction to give the corresponding anilide, 3' ,5'-dichloro-2-hydroxy-2-methylbut-3-eneanilide. Both of these anilides are stable in wine for 150 days. A different degradation behavior is observed with procymidone and leads to the formation of 3,5- dichloroaniline, which, in turn, breaks down in wine.

Degradation

Chlozolinate (1) hydrolysed rapidly at 25 °C in alkaline solution with DTm values of 6 hours (pH 6.8) and 16 min (pH 8.3). Three hydrolytic degradation reactions were observed. The first reaction involved the cleavage of the ethyl ester to yield the corresponding carboxylic acid (2). Compound 2 underwent decarboxylation to yield 3-(3,5-dichlorophenyl)-5-methyloxazolidine- 2,4-dione (3). The third reaction involved the opening of the oxazolidinedione ring to yield 3',5'-dichloro-2-hydroxypropanilide(4) (Villedieu et al., 1994,1995).
Chlozolinate degraded rapidly in wine during the vinification process (DT50 0.35 and 0.14 day at pH 3 and 4, respectively). Decarboxylation resulted in the formation of compound 3 as the major product (Cabras et al., 1984; Pirisi et al., 1986; Gennari et al., 1992).

CHLOZOLINATE Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 53)Suppliers
Supplier Tel Email Country ProdList Advantage
Hubei Jusheng Technology Co.,Ltd.
18871490254 linda@hubeijusheng.com CHINA 28180 58
Finetech Industry Limited
+86-27-87465837 +8618971612321 info@finetechnology-ind.com China 9634 58
Hangzhou MolCore BioPharmatech Co.,Ltd.
+86-057181025280; +8617767106207 sales@molcore.com China 49739 58
Aceschem Inc.
+1-817863-6948 +1-(817)863-6948 sales@aceschem.com United States 19639 58
Amadis Chemical Company Limited
571-89925085 sales@amadischem.com China 131981 58
J & K SCIENTIFIC LTD. 010-82848833 400-666-7788 jkinfo@jkchemical.com China 96815 76
BEST-REAGENT 400-1166-196 18981987031 cdhxsj@163.com China 11726 57
Chengdu Ai Keda Chemical Technology Co., Ltd. 4008-755-333 18080918076 800078821@qq.com China 9725 55
The future of Shanghai Industrial Co., Ltd. 021-61552785 sales@shshiji.com China 9552 55
Nanjing Sunlida Biological Technology Co., Ltd. 025-57798810 sales@sunlidabio.com China 3750 55

84332-86-5(CHLOZOLINATE)Related Search:

CHLOZOLINATE SERINAL ethyl (RS)-3-(3,5-dichlorophenyl)-5-methyl-2,4-dioxooxazolidine-5-carboxylate chlozolinate (bsi,iso) ethyl 3-(3,5-dichlorophenyl)-5- methyl-2,4-dioxo-5-oxazolidinecarboxyate chlozolinate (ISO) ethyl (RS)-3-(3,5-dichlorophenyl)-5-methyl-2,4-dioxo-oxazolidine-5-carboxylate Chlozolinate solution 5-Oxazolidinecarboxylic acid, 3-(3,5-dichlorophenyl)-5-methyl-2,4-dioxo-, ethyl ester, (+-)- Chlozolinate [iso] Einecs 282-714-4 Clozolinate 3-(3,5-Dichlorophenyl)-5-methyl-2,4-dioxo-5-oxazolidinecarboxylic acid ethyl ester SDS 65311 ethyl(±) 3-(3,5-dichlorophenyl)-5-methyl-2,4-dioxo-1,3-oxazolidine-5-carboxylate Manderol CHLORPICRIN PESTANAL (TRICHLORO- NITROME CHLOZOLINATE PESTANAL. (±)ethyl 3-(3,5-dichlorophenyl)-5-methyl-2,4-dioxo-5-oxazolidinecarboxylate Chlozolinate 1 Chlozolinate solution,100ppm Chlozolinate Standard Chlozolinate@1000 μg/mL in Acetonitrile Chlozolinate@100 μg/mL in Acetonitrile ClozolinateSolution,10mg/L,1ml 84332-86-5 C13H11Cl2NO5