CHLOZOLINATE
- CAS No.
- 84332-86-5
- Chemical Name:
- CHLOZOLINATE
- Synonyms
- SERINAL;Manderol;SDS 65311;Clozolinate;CHLOZOLINATE;Chlozolinate 1;Einecs 282-714-4;Chlozolinate [iso];Chlozolinate Standard;chlozolinate (bsi,iso)
- CBNumber:
- CB4358743
- Molecular Formula:
- C13H11Cl2NO5
- Molecular Weight:
- 332.14
- MDL Number:
- MFCD00143964
- MOL File:
- 84332-86-5.mol
| Melting point | 110-114 °C |
|---|---|
| Boiling point | 420.8±55.0 °C(Predicted) |
| Density | 1.479 |
| vapor pressure | 1.3 x 10-5 Pa (25 °C) |
| Flash point | 100 °C |
| storage temp. | 0-6°C |
| Water Solubility | 2 mg l-1 (25 °C) |
| pka | -4.24±0.40(Predicted) |
| EWG's Food Scores | 2 |
| FDA UNII | 6YW05QFN1Y |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |     GHS02,GHS07,GHS08,GHS09 |
|---|---|
| Signal word | Danger |
| Hazard statements | H225-H304-H315-H336-H410 |
| Precautionary statements | P210-P261-P273-P301+P310-P331-P501 |
| Hazard Codes | Xn,N,F |
| Risk Statements | 40-51/53-67-65-50/53-38-11-20 |
| Safety Statements | 36/37-61-62-60-33-25-16-9 |
| RIDADR | UN3077 9/PG 3 |
| WGK Germany | 2 |
| HS Code | 29251900 |
CHLOZOLINATE price More Price(8)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 33743 | Chlozolinate solution 100μg/mL in cyclohexane, PESTANAL | 84332-86-5 | 2ml | $74.5 | 2022-05-15 | Buy |
| TRC | C989138 | Chlozolinate | 84332-86-5 | 25mg | $880 | 2021-12-16 | Buy |
| TRC | C989138 | Chlozolinate | 84332-86-5 | 50mg | $1680 | 2021-12-16 | Buy |
| American Custom Chemicals Corporation | PST0000442 | CHLOZOLINATE 98.00% | 84332-86-5 | 10MG | $924 | 2021-12-16 | Buy |
| Crysdot | CD11048026 | Ethyl3-(3,5-dichlorophenyl)-5-methyl-2,4-dioxooxazolidine-5-carboxylate 95+% | 84332-86-5 | 1g | $972 | 2021-12-16 | Buy |
CHLOZOLINATE Chemical Properties,Uses,Production
Uses
Chlozolinate is a dicarboximide fungicide which is used primarily on grapes.
Uses
Chlozolinate controls fruit rot, downy mildew and brown rot in pome and stone fruits, vines, vegetables, strawberries and ornamentals caused by Botrytis, Monilia and Sclerotinia, efc.
Definition
ChEBI: Ethyl 3-(3,5-dichlorophenyl)-5-methyl-2,4-dioxo-1,3-oxazolidine-5-carboxylate is the ethyl ester of 3-(3,5-dichlorophenyl)-5-methyl-2,4-dioxo-1,3-oxazolidine-5-carboxylic acid. It is a dichlorobenzene, an oxazolidinone, a dicarboximide and an ethyl ester.
General Description
Chlozolinate is a systemic fungicide, used for the control of downy mildew, brown rot, and fruit rot in agricultural commodities.
Metabolic pathway
The fungicides, chlozolinate, vinclozolin, and procymidone, are added to wine after fermentation and the degradation products are isolated and identified. Chlozolinate undergoes a rapid hydrolytic loss of the ethoxycarbonyl substituent to give an oxazolidine that further undergoes hydrolytic cleavage to give 3' ,5' -dichloro-2-hydroxypropanilide. The oxazolidine ring of vinclozolin undergoes a similar hydrolysis reaction to give the corresponding anilide, 3' ,5'-dichloro-2-hydroxy-2-methylbut-3-eneanilide. Both of these anilides are stable in wine for 150 days. A different degradation behavior is observed with procymidone and leads to the formation of 3,5- dichloroaniline, which, in turn, breaks down in wine.
Degradation
Chlozolinate (1) hydrolysed rapidly at 25 °C in alkaline solution with DTm
values of 6 hours (pH 6.8) and 16 min (pH 8.3). Three hydrolytic degradation
reactions were observed. The first reaction involved the cleavage of
the ethyl ester to yield the corresponding carboxylic acid (2). Compound
2 underwent decarboxylation to yield 3-(3,5-dichlorophenyl)-5-methyloxazolidine-
2,4-dione (3). The third reaction involved the opening of the
oxazolidinedione ring to yield 3',5'-dichloro-2-hydroxypropanilide(4)
(Villedieu et al., 1994,1995).
Chlozolinate degraded rapidly in wine during the vinification process
(DT50 0.35 and 0.14 day at pH 3 and 4, respectively). Decarboxylation
resulted in the formation of compound 3 as the major product (Cabras et
al., 1984; Pirisi et al., 1986; Gennari et al., 1992).
CHLOZOLINATE Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Hubei Jusheng Technology Co.,Ltd. | 18871490254 | linda@hubeijusheng.com | CHINA | 28180 | 58 |
| Finetech Industry Limited | +86-27-87465837 +8618971612321 | info@finetechnology-ind.com | China | 9571 | 58 |
| Hangzhou MolCore BioPharmatech Co.,Ltd. | +86-057181025280; +8617767106207 | sales@molcore.com | China | 49739 | 58 |
| Aceschem Inc. | +1-817863-6948 +1-（817）863-6948 | sales@aceschem.com | United States | 19639 | 58 |
| Amadis Chemical Company Limited | 571-89925085 | sales@amadischem.com | China | 131981 | 58 |
| J & K SCIENTIFIC LTD. | 010-82848833 400-666-7788 | jkinfo@jkchemical.com | China | 96815 | 76 |
| BEST-REAGENT | 400-1166-196 18981987031 | cdhxsj@163.com | China | 11726 | 57 |
| Chengdu Ai Keda Chemical Technology Co., Ltd. | 4008-755-333 18080918076 | 800078821@qq.com | China | 9725 | 55 |
| The future of Shanghai Industrial Co., Ltd. | 021-61552785 | sales@shshiji.com | China | 9552 | 55 |
| Nanjing Sunlida Biological Technology Co., Ltd. | 025-57798810 | sales@sunlidabio.com | China | 3750 | 55 |