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(+)-(18-CROWN-6)-2,3,11,12-TETRACARBOXYLIC ACID

CAS No.
61696-54-6
Chemical Name:
(+)-(18-CROWN-6)-2,3,11,12-TETRACARBOXYLIC ACID
Synonyms
C90001;Bis(L-tartaric Acid) 18-Crown-6;(+)-18-Crown-6 tetracarboxylic Acid;(+)-(CROWN-6)-2,3,11,12-TETRACARBOXYLIC ACID;(+)-(18-CROWN-6)-2,3,11,12-TETRACARBOXYLIC ACID;(+)-(18-Crown-6)-2,3,11,12-tetracarboxylic acid 97%;(2R,3R,11R,12R)-1,4,7,10,13,16-HEXAOXACYCLOOCTADECANE-2,3,11,12-TETRACARBOXYLIC ACID;(2R,3R,11S,12R)-1,4,7,10,13,16-Hexaoxacyclooctadecane-2,3,11,12-tetracarboxylic acid;1,4,7,10,13,16-Hexaoxacyclooctadecane-2,3,11,12-tetracarboxylic acid, (2R,3R,11R,12R)-;(+)-(18-Crown-6)-2,3,11,12-tetracarboxylic acid,(2R,3R,11R,12R)-1,4,7,10,13,16-Hexaoxacyclooctadecane-2,3,11,12-tetracarboxylic acid
CBNumber:
CB4685263
Molecular Formula:
C16H24O14
Molecular Weight:
440.35
MDL Number:
MFCD00040514
MOL File:
61696-54-6.mol
Last updated:2023-04-23 13:52:06

(+)-(18-CROWN-6)-2,3,11,12-TETRACARBOXYLIC ACID Properties

Melting point 210-212 °C (lit.)
Boiling point 798.9±60.0 °C(Predicted)
Density 1.399±0.06 g/cm3(Predicted)
storage temp. -20°C Freezer, Under Inert Atmosphere
solubility Methanol (Slightly), Water (Slightly)
form Solid
pka 1.95±0.70(Predicted)
color Off-White to Pale Yellow
optical activity [α]20/D +62°, c = 1 in methanol
BRN 4240375
Stability Hygroscopic

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36
WGK Germany  3
HS Code  2932990090

(+)-(18-CROWN-6)-2,3,11,12-TETRACARBOXYLIC ACID price More Price(11)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TRC C825000 (+)-(18-Crown-6)-2,3,11,12-tetracarboxylic acid 61696-54-6 250mg $1155 2021-12-16 Buy
American Custom Chemicals Corporation CHM0015038 (+)-(18-CROWN-6)-2,3,11,12-TETRACARBOXYLIC ACID 95.00% 61696-54-6 250MG $1963.5 2021-12-16 Buy
Medical Isotopes, Inc. 8604 (+)-(18-Crown-6)-2,3,11,12-tetracarboxylic acid 97% 61696-54-6 125mg $2200 2021-12-16 Buy
Biosynth Carbosynth FC20591 (+)-(18-Crown-6)-2,3,11,12-tetracarboxylic acid 61696-54-6 2mg $65 2021-12-16 Buy
Biosynth Carbosynth FC20591 (+)-(18-Crown-6)-2,3,11,12-tetracarboxylic acid 61696-54-6 5mg $100 2021-12-16 Buy
Product number Packaging Price Buy
C825000 250mg $1155 Buy
CHM0015038 250MG $1963.5 Buy
8604 125mg $2200 Buy
FC20591 2mg $65 Buy
FC20591 5mg $100 Buy

(+)-(18-CROWN-6)-2,3,11,12-TETRACARBOXYLIC ACID Chemical Properties,Uses,Production

Chemical Properties

(+)-(18-CROWN-6)-2,3,11,12-TETRACARBOXYLIC ACID is White Solid

Uses

(+)-(18-CROWN-6)-2,3,11,12-TETRACARBOXYLIC ACID is a calcium and barium chelator. A useful chiral NMR discriminating agent for underivatized amino acids

Uses

Derived tetracarboxylic acid chloride of this crown ether reacts with meta- and para-xylylene diamines to form chiral captands in high yields. Used as a chiral selector in capillary zone electrophoresis for the separation of a variety of optically active amines. Synthesis of monoamides.

(+)-(18-CROWN-6)-2,3,11,12-TETRACARBOXYLIC ACID Preparation Products And Raw materials

Raw materials

Preparation Products

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(+)-(18-CROWN-6)-2,3,11,12-TETRACARBOXYLIC ACID (2R,3R,11R,12R)-1,4,7,10,13,16-HEXAOXACYCLOOCTADECANE-2,3,11,12-TETRACARBOXYLIC ACID (+)-(CROWN-6)-2,3,11,12-TETRACARBOXYLIC ACID C90001 (+)-(18-Crown-6)-2,3,11,12-tetracarboxylic acid,(2R,3R,11R,12R)-1,4,7,10,13,16-Hexaoxacyclooctadecane-2,3,11,12-tetracarboxylic acid (+)-18-Crown-6 tetracarboxylic Acid Bis(L-tartaric Acid) 18-Crown-6 (+)-(18-Crown-6)-2,3,11,12-tetracarboxylic acid 97% (2R,3R,11S,12R)-1,4,7,10,13,16-Hexaoxacyclooctadecane-2,3,11,12-tetracarboxylic acid 1,4,7,10,13,16-Hexaoxacyclooctadecane-2,3,11,12-tetracarboxylic acid, (2R,3R,11R,12R)- 61696-54-6 C16H24O14 Chelation/Complexation Compounds Chiral Crown Ethers Synthetic Reagents Chelating Agents, Ligands Chelating Agents & Ligands