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(1S,2R,5S)-(+)-MENTHYL (R)-P-TOLUENESULFINATE

CAS No.
91796-57-5
Chemical Name:
(1S,2R,5S)-(+)-MENTHYL (R)-P-TOLUENESULFINATE
Synonyms
(+)-Menthyl (R)-p-toluenesulfinate;(R)-(+)-MENTHYL P-TOLUENESULFINATE;(+)-(1S)-Menthyl (R)-p-toluenesulfinate;(+)-(1S)-MENTHYL (R)-TOLUENE-4-SULFINATE;(1S,2R,5S)-MENTHYL (R)-P-TOLUENESULFINATE;(1S,2R,5S)-(+)-MENTHYL (R)-P-TOLUENESULFINATE;(R)-(+)-P-TOLUENESULFINIC ACID D-MENTHYL ESTER;(1S,2R,5S)-(+)-Menthyl(R)-p-Toluenesulfinate>(R)-(5S)-2-Isopropyl-5-methylcyclohexyl 4-methylbenzenesulfinate;(R)-(1S,2R,5S)-2-Isopropyl-5-methylcyclohexyl 4-Methylbenzenesulfinate
CBNumber:
CB5112980
Molecular Formula:
C17H26O2S
Molecular Weight:
294.45
MDL Number:
MFCD00064472
MOL File:
91796-57-5.mol
MSDS File:
SDS
Last updated:2023-06-08 17:06:38

(1S,2R,5S)-(+)-MENTHYL (R)-P-TOLUENESULFINATE Properties

Melting point 104-106 °C(lit.)
Boiling point 402.3±38.0 °C(Predicted)
Density 1.08±0.1 g/cm3(Predicted)
refractive index 200 ° (C=2, Acetone)
storage temp. 2-8°C
form powder to crystal
color White to Almost white
optical activity [α]20/D +200°, c = 2 in acetone
BRN 4907352
CAS DataBase Reference 91796-57-5(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Safety Statements  22-24/25
WGK Germany  3
HS Code  2930.90.2900
NFPA 704
0
1 0

(1S,2R,5S)-(+)-MENTHYL (R)-P-TOLUENESULFINATE price More Price(17)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 278742 (1S,2R,5S)-(+)-Menthyl (R)-p-toluenesulfinate 98% 91796-57-5 10g $297 2023-06-20 Buy
Sigma-Aldrich 89714 (+)-(1S)-Menthyl (R)-p-toluenesulfinate ≥98.0% (sum of enantiomers, HPLC) 91796-57-5 5g $130 2023-01-07 Buy
TCI Chemical M1066 (1S,2R,5S)-(+)-Menthyl (R)-p-Toluenesulfinate >97.0%(HPLC) 91796-57-5 1g $41 2024-03-01 Buy
TCI Chemical M1066 (1S,2R,5S)-(+)-Menthyl (R)-p-Toluenesulfinate >97.0%(HPLC) 91796-57-5 5g $121 2024-03-01 Buy
TRC M220403 (1S,2R,5S)-(+)-Menthyl (R)-p-Toluenesulfinate 91796-57-5 50mg $45 2021-12-16 Buy
Product number Packaging Price Buy
278742 10g $297 Buy
89714 5g $130 Buy
M1066 1g $41 Buy
M1066 5g $121 Buy
M220403 50mg $45 Buy

(1S,2R,5S)-(+)-MENTHYL (R)-P-TOLUENESULFINATE Chemical Properties,Uses,Production

Chemical Properties

white to light yellow crystal powde

Uses

(1S,2R,5S)-(+)-Menthyl (R)-p-toluenesulfinate can be used:

  • As a chiral electrophile in the synthesis of fluorescent triazolopyridine ligands.
  • To prepare various sulfinimines, which are further used in the synthesis of α-aminophosphonic acids by reacting with borane complexes.
  • In one of the key synthetic steps for the synthesis of (S)-(+)-ethyl β-amino-3-pyridinepropanoate, a component of an antiplatelet agent.

Uses

(1S,2R,5S)-(+)-Menthyl (R)-p-Toluenesulfinate is used as a reactant in the stereoselective synthesis of pyrazole derivatives using tert-butansulfonamide as a chiral auxiliary.

(1S,2R,5S)-(+)-MENTHYL (R)-P-TOLUENESULFINATE Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 68)Suppliers
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Capot Chemical Co.,Ltd.
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career henan chemical co
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PT CHEM GROUP LIMITED
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Aladdin Scientific
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Meryer (Shanghai) Chemical Technology Co., Ltd. 021-61259108 18621169109 market03@meryer.com China 40240 62
TCI (Shanghai) Development Co., Ltd. 021-67121386 Sales-CN@TCIchemicals.com China 24539 81

View Lastest Price from (1S,2R,5S)-(+)-MENTHYL (R)-P-TOLUENESULFINATE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
(1S,2R,5S)-(+)-MENTHYL (R)-P-TOLUENESULFINATE pictures 2020-01-03 (1S,2R,5S)-(+)-MENTHYL (R)-P-TOLUENESULFINATE
91796-57-5
US $6.60 / KG 1KG 97%-99% 1kg -1000kg Career Henan Chemical Co
(1S,2R,5S)-(+)-MENTHYL (R)-P-TOLUENESULFINATE (1S,2R,5S)-MENTHYL (R)-P-TOLUENESULFINATE (+)-(1S)-MENTHYL (R)-TOLUENE-4-SULFINATE (+)-(1S)-Menthyl (R)-p-toluenesulfinate (R)-(5S)-2-Isopropyl-5-methylcyclohexyl 4-methylbenzenesulfinate (R)-(+)-MENTHYL P-TOLUENESULFINATE (R)-(+)-P-TOLUENESULFINIC ACID D-MENTHYL ESTER p-Toluenesulfinic acid (1R)-5β-methyl-2β-isopropylcyclohexan-1β-yl ester Benzenesulfinic acid, 4-Methyl-,(1S,2R,5S)-5-Methyl-2-(1-Methylethyl)cyclohexylester, [S(R)]- (+)-Menthyl (R)-p-toluenesulfinate (1S,2R,5S)-(+)-Menthyl(R)-p-Toluenesulfinate> (R)-(1S,2R,5S)-2-Isopropyl-5-methylcyclohexyl 4-Methylbenzenesulfinate 91796-57-5 C17H26O2S Organic Building Blocks Sulfonates/Sulfinates Terpenes Asymmetric Synthesis Monocyclic Monoterpenes Chiral Building Blocks chiral Asymmetric Synthesis Biochemistry Monocyclic Monoterpenes Synthetic Organic Chemistry Terpenes