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ZIRCONIUM IODIDE

CAS No.
13986-26-0
Chemical Name:
ZIRCONIUM IODIDE
Synonyms
ZrI4;Einecs 237-780-9;ZIRCONIUM IODIDE;ZIRCONIUM(IV) IODIDE;ZIRCONIUM TETRAIODIDE;zirconiumiodide(zri4);Zirconium iodide (ZrI4);Zirconium(IV) tetraiodide;zirconium(4+),tetraiodide;ZIRCONIUM(IV) IODIDE: 99.5%
CBNumber:
CB5134410
Molecular Formula:
I4Zr
Molecular Weight:
598.84
MDL Number:
MFCD00049641
MOL File:
13986-26-0.mol
Last updated:2024-05-30 15:33:58

ZIRCONIUM IODIDE Properties

Melting point 499°C
Boiling point 431°C (estimate)
Density 4.85
storage temp. under inert gas (nitrogen or Argon) at 2–8 °C
solubility very soluble in H2O
form powder
color Yellow
Specific Gravity 4.914
Water Solubility Insoluble in water.
Hydrolytic Sensitivity 7: reacts slowly with moisture/water
Sensitive Air & Moisture Sensitive
Merck 14,10178
Exposure limits ACGIH: TWA 5 mg/m3; STEL 10 mg/m3
NIOSH: IDLH 25 mg/m3; TWA 5 mg/m3; STEL 10 mg/m3
CAS DataBase Reference 13986-26-0(CAS DataBase Reference)
FDA UNII H6NZC1810V
EPA Substance Registry System Zirconium iodide (ZrI4) (13986-26-0)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS05
Signal word  Danger
Hazard statements  H314
Precautionary statements  P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363
Hazard Codes  C
Risk Statements  34
Safety Statements  22-26-27-36/37/39-45
RIDADR  UN 3260 8/PG 2
WGK Germany  3
TSCA  No
HazardClass  8
PackingGroup  III
NFPA 704
0
3 0

ZIRCONIUM IODIDE price More Price(5)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Alfa Aesar 017400 Zirconium(IV) iodide 99% 13986-26-0 25g $615 2023-06-20 Buy
Strem Chemicals 93-4025 Zirconium(IV) iodide (99.5%-Zr) 13986-26-0 1g $68 2024-03-01 Buy
Strem Chemicals 93-4025 Zirconium(IV) iodide (99.5%-Zr) 13986-26-0 5g $178 2024-03-01 Buy
American Custom Chemicals Corporation ING0007364 ZIRCONIUM(IV) IODIDE 95.00% 13986-26-0 1G $673.68 2021-12-16 Buy
American Custom Chemicals Corporation ING0007364 ZIRCONIUM(IV) IODIDE 95.00% 13986-26-0 5G $957.46 2021-12-16 Buy
Product number Packaging Price Buy
017400 25g $615 Buy
93-4025 1g $68 Buy
93-4025 5g $178 Buy
ING0007364 1G $673.68 Buy
ING0007364 5G $957.46 Buy

ZIRCONIUM IODIDE Chemical Properties,Uses,Production

Description

Zirconium(IV) iodide, ZrI4, is the most readily available iodide of zirconium. It is an orange-colored solid that degrades in the presence of water. The compound was once renowned as an intermediate in the purification of zirconium metal. This compound is volatile, subliming as intact tetrahedral ZrI4 molecules.

Chemical Properties

orange crystal(s); fumes heavily in air; cub, a=1.179nm [KIR84] [MER06]

Uses

Used in the van Arkel-de Boer refining process.

Preparation

It is prepared by the direct reaction of powdered zirconium metal and iodine. Pyrolysis of zirconium(IV) iodide gas by contact of hot wire was the first industrial process for the commercial production of pure ductile metallic zirconium.

Structure and conformation

Like most binary metal halides, it has a polymeric structure. The compound exists as a polymer consisting of octahedral Zr(IV) centers, each with a pair of terminal iodide ligands and four doubly bridging iodide ligands. The Zr-I distances are 2.692 (terminal) and 3.030 A? .

ZIRCONIUM IODIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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Zirconium(IV)iodide(99.5%-Zr) ZIRCONIUM(IV) IODIDE: 99.5% Zirconium iodide (ZrI4) zirconiumiodide(zri4) ZrI4 ZIRCONIUM IODIDE ZIRCONIUM(IV) IODIDE ZIRCONIUM TETRAIODIDE Zirconiumiodidereddishbrownpowder Zirconium(IV) tetraiodide Einecs 237-780-9 Zirconium(IV) iodide anhydrous ZirconiuM (IV) Iodide, Powder Zirconium(IV) iodide anhydrous, powder, 99.9% trace metals basis zirconium(4+),tetraiodide ZIRCONIUM IODIDE ISO 9001:2015 REACH 13986-26-0 13985-26-0 Zrl4 Zirconium Catalysis and Inorganic Chemistry ZirconiumMetal and Ceramic Science Catalysis and Inorganic Chemistry Chemical Synthesis Crystal Grade Inorganics Salts Zirconium Salts metal halide