ChemicalBook >> CAS DataBase List >>(R)-(-)-2,2'-Bis[di(3,5-di-i-propyl-4-dimethylaminophenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97%
(R)-(-)-2,2'-Bis[di(3,5-di-i-propyl-4-dimethylaminophenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97%
- CAS No.
- 352655-40-4
- Chemical Name:
- (R)-(-)-2,2'-Bis[di(3,5-di-i-propyl-4-dimethylaminophenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97%
- Synonyms
- SL-A107-1;(R)-3,5-iPr-4-NMe2-MeOBIPHEP;(R)-2,2’-Bis[di(3,5-di-i-propyl-4-dimethylaminophenyl)phosphino]-6,6’-dimethoxy-1,1’-biphenyl;(R)-2,2’-Bis[bis(3,5-diisopropyl-4-dimethylaminophenyl) phosphino]-6,6’-dimethoxy-1,1’-biphenyl;(S)-(6,6μ-Dimethoxybiphenyl-2,2μ-diyl)bis{bis[3,5-diisopropyl-4-(dimethylamino)phenyl]phosphine};(R)-(6,6μ-Dimethoxybiphenyl-2,2μ-diyl)bis{bis[3,5-diisopropyl-4-(dimethylamino)phenyl]phosphine};(R)-(-)-2,2''-Bis[di(3,5-di-i-propyl-4-dimethylaminophenyl)phosphino]-6,6''-dimethoxy-1,1''-biphenyl;(R)-(+)-2,2'-Bis[di-(3,5-di-isopropyl-4-dimethyl-aminophenyl)-phosphino]-6,6'-dimethoxy-1,1'-biphenyl;(R)-(+)-2,2'-Bis[di-(3,5-di-i-propyl-4-dimethyl- aminophenyl)-phosphino]-6,6'-dimethoxy-1,1'- biphenyl;(R)-(-)-2,2'-Bis[di(3,5-di-i-propyl-4-dimethylaminophenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97%
- CBNumber:
- CB61180974
- Molecular Formula:
- C70H100N4O2P2
- Molecular Weight:
- 1091.54
- MDL Number:
- MFCD09753010
- MOL File:
- 352655-40-4.mol
Last updated:2023-04-23 13:52:06
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS07 |
---|---|
Signal word | Warning |
Hazard statements | H302-H315-H319-H335 |
Precautionary statements | P261-P280-P301+P312-P302+P352-P305+P351+P338 |
WGK Germany | 3 |
HS Code | 29319090 |
(R)-(-)-2,2'-Bis[di(3,5-di-i-propyl-4-dimethylaminophenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97% price More Price(16)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Strem Chemicals | 15-0652 | (R)-(-)-2,2'-Bis[di(3,5-di-i-propyl-4-dimethylaminophenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl, min. 97% | 352655-40-4 | 100mg | $96 | 2024-03-01 | Buy |
Strem Chemicals | 15-0652 | (R)-(-)-2,2'-Bis[di(3,5-di-i-propyl-4-dimethylaminophenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl, min. 97% | 352655-40-4 | 500mg | $355 | 2024-03-01 | Buy |
Strem Chemicals | 15-0652 | (R)-(-)-2,2'-Bis[di(3,5-di-i-propyl-4-dimethylaminophenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl, min. 97% | 352655-40-4 | 2g | $1207 | 2024-03-01 | Buy |
Strem Chemicals | 15-0652 | (R)-(-)-2,2'-Bis[di(3,5-di-i-propyl-4-dimethylaminophenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl, min. 97% | 352655-40-4 | 10g | $4824 | 2024-03-01 | Buy |
American Custom Chemicals Corporation | ING0001276 | (R)-(-)-2,2'-BIS[DI(3,5-DI-I-PROPYL-4-DIMETHYLAMINOPHENYL)PHOSPHINO]-6,6'-DIMETHOXY-1,1'-BIPHENYL 95.00% | 352655-40-4 | 1G | $1269.75 | 2021-12-16 | Buy |
(R)-(-)-2,2'-Bis[di(3,5-di-i-propyl-4-dimethylaminophenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97% Chemical Properties,Uses,Production
Reaction
In many respects the catalytic profile of the MeOBIPHEP ligands is similar to that of other atropisomeric diphosphines such as binap and its many analogs. The nature of the PR2 group strongly influences the catalytic performance of the metal complexes. The rhodium and ruthenium MeO-BIPHEP catalysts are highly effective for the hydrogenation of various C=O, C=C and C=N bonds and several synthetically useful C-C coupling reactions.
- Ru and Ir catalyzed dynamic kinetic resolution for the synthesis of hydroxy, amino acid derivatives.
- Ru-catalyzed asymmetric hydrogenation of ketones and alkenes.
- Ir catalyzed enantioselective hydrogenation of heteroaromatic compounds.
- Conjugate addition using 2-heteroaryl titanates and zinc reagents.
- Conjugate addition of terminal alkynes to α,β-unsaturated thioamides.
Chemical Properties
Off-white powder
(R)-(-)-2,2'-Bis[di(3,5-di-i-propyl-4-dimethylaminophenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97% Preparation Products And Raw materials
Raw materials
Preparation Products
(R)-(-)-2,2'-Bis[di(3,5-di-i-propyl-4-dimethylaminophenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97% Suppliers
Global( 22)Suppliers
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Hangzhou MolCore BioPharmatech Co.,Ltd. | +86-057181025280; +8617767106207 | sales@molcore.com | China | 49739 | 58 |
Aladdin Scientific | +1-+1(833)-552-7181 | sales@aladdinsci.com | United States | 52927 | 58 |
J & K SCIENTIFIC LTD. | 010-82848833 400-666-7788 | jkinfo@jkchemical.com | China | 96815 | 76 |
Energy Chemical | 021-021-58432009 400-005-6266 | sales8178@energy-chemical.com | China | 44700 | 61 |
Bide Pharmatech Ltd. | 400-164-7117 13681763483 | product02@bidepharm.com | China | 41463 | 60 |
Zhengzhou Kingorgchem Chemical Technology Co., Ltd.gy Co., Ltd. | 0371-65511006 18625597674 | sales@kingorgchem.com | China | 953 | 55 |
LaaJoo | 021-60702684 18516024827 | huang.jiayi@sinocompound.com | China | 2654 | 58 |
Shanghai Anyinuo Biomedical Technology Co., Ltd. | 021-34625901 | 420970979@qq.com | China | 5836 | 58 |
Jiangsu aikang biomedical research and development co., LTD | 025-66110311 13155353615 | qzhang@aikonchem.com | China | 15527 | 58 |
Henan Weituxi Chemical Technology Co., Ltd. | 0371-63284658 18135795563 | 2885349392@qq.com | China | 10025 | 58 |
352655-40-4((R)-(-)-2,2'-Bis[di(3,5-di-i-propyl-4-dimethylaminophenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97%)Related Search:
SL-A107-1
(R)-(+)-2,2'-Bis[di-(3,5-di-i-propyl-4-dimethyl- aminophenyl)-phosphino]-6,6'-dimethoxy-1,1'- biphenyl
(R)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis{bis[3,5-diisopropyl-4-(dimethylamino)phenyl]phosphine}>=97%, optical purity ee: >=99%
(R)-(-)-2,2'-Bis[di(3,5-di-i-propyl-4-dimethylaminophenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97%
(R)-(6,6μ-Dimethoxybiphenyl-2,2μ-diyl)bis{bis[3,5-diisopropyl-4-(dimethylamino)phenyl]phosphine}
(R)-3,5-iPr-4-NMe2-MeOBIPHEP, SL-A107-1, (R)-2,2μ-Bis[bis(3,5-diisopropyl-4-dimethylaminophenyl)phosphino]-6,6μ-dimethoxy-1,1μ-biphenyl
(S)-(6,6μ-Dimethoxybiphenyl-2,2μ-diyl)bis{bis[3,5-diisopropyl-4-(dimethylamino)phenyl]phosphine}
(S)-3,5-iPr-4-NMe2-MeOBIPHEP, SL-A107-2, (S)-2,2μ-Bis[bis(3,5-diisopropyl-4-dimethylaminophenyl)phosphino]-6,6μ-dimethoxy-1,1μ-biphenyl
(R)-(-)-2,2'-Bis[di(3,5-di-i-propyl-4-dimethylaminophenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl, min. 97%
(R)-(+)-2,2'-Bis[di-(3,5-di-isopropyl-4-dimethyl-aminophenyl)-phosphino]-6,6'-dimethoxy-1,1'-biphenyl
(R)-3,5-iPr-4-NMe2-MeOBIPHEP
4-[[2-[2-bis[4-(dimethylamino)-3,5-di(propan-2-yl)phenyl]phosphanyl-6-methoxyphenyl]-3-methoxyphenyl]-[4-(dimethylamino)-3,5-di(propan-2-yl)phenyl]phosphanyl]-N,N-dimethyl-2,6-di(propan-2-yl)aniline
Benzenamine, 4,4',4'',4'''-[[(1R)-6,6'-dimethoxy[1,1'-biphenyl]-2,2'-diyl]diphosphinidyne]tetrakis[N,N-dimethyl-2,6-bis(1-methylethyl)- (9CI)
(R)-2,2’-Bis[bis(3,5-diisopropyl-4-dimethylaminophenyl) phosphino]-6,6’-dimethoxy-1,1’-biphenyl
(R)-(-)-2,2''-Bis[di(3,5-di-i-propyl-4-dimethylaminophenyl)phosphino]-6,6''-dimethoxy-1,1''-biphenyl
(R)-2,2’-Bis[di(3,5-di-i-propyl-4-dimethylaminophenyl)phosphino]-6,6’-dimethoxy-1,1’-biphenyl
352655-40-4
C70H100N4O2P2
Chiral Phosphine
MeOBIPHEP Series