4-Bromobenzylamine hydrochloride
- CAS No.
- 26177-44-6
- Chemical Name:
- 4-Bromobenzylamine hydrochloride
- Synonyms
- 4-BBA X HCL;4-BROMOBENZYLAMINE HCL;p-Bromo Benzylamine Hcl;4-BROMOBENZYLAMINE HYDROCHLORIDE;P-BROMOBENZYLAMINE HYDROCHLORIDE;4-Bromobenzylamine Hydrochloride >4-Bromobenzylamine hydrochloride,98%;4-BROMOBENZYLAMINE HYDROCHLORIDE 98%;4-Bromobenzylamine hydrochloride 99+%;(4-Bromophenyl)methamine hydrochloride
- CBNumber:
- CB6136325
- Molecular Formula:
- C7H9BrClN
- Molecular Weight:
- 222.51
- MDL Number:
- MFCD00012860
- MOL File:
- 26177-44-6.mol
- MSDS File:
- SDS
| Melting point | 274-276 °C(lit.) |
|---|---|
| refractive index | 1,5855-1,5875 |
| storage temp. | Inert atmosphere,Room Temperature |
| form | powder to crystal |
| color | White to Almost white |
| Water Solubility | Soluble in water. |
| Sensitive | Hygroscopic |
| BRN | 3693458 |
| InChI | InChI=1S/C7H8BrN.ClH/c8-7-3-1-6(5-9)2-4-7;/h1-4H,5,9H2;1H |
| InChIKey | BVYUYDBWQMSOKM-UHFFFAOYSA-N |
| SMILES | C1(CN)=CC=C(Br)C=C1.Cl |
| CAS DataBase Reference | 26177-44-6(CAS DataBase Reference) |
| UNSPSC Code | 12352100 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319-H335 | |||||||||
| Precautionary statements | P261-P264-P271-P280-P302+P352-P305+P351+P338 | |||||||||
| target organs | Respiratory system | |||||||||
| PPE | dust mask type N95 (US), Eyeshields, Gloves | |||||||||
| Hazard Codes | Xi,Xn | |||||||||
| Risk Statements | 36/37/38-21/22 | |||||||||
| Safety Statements | 26-37/39-36/37/39-36 | |||||||||
| WGK Germany | 3 | |||||||||
| Hazard Note | Irritant | |||||||||
| HS Code | 29214900 | |||||||||
| Storage Class | 11 - Combustible Solids | |||||||||
| Hazard Classifications | Eye Irrit. 2 Skin Irrit. 2 STOT SE 3 |
|||||||||
| NFPA 704 |
|
4-Bromobenzylamine hydrochloride price More Price(40)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 205214 | 4-Bromobenzylamine hydrochloride 98% | 26177-44-6 | 5g | $163 | 2026-04-30 | Buy |
| TCI Chemical | B1841 | 4-Bromobenzylamine Hydrochloride >97.0%(N)(T) | 26177-44-6 | 5g | $93 | 2026-04-30 | Buy |
| TCI Chemical | B1841 | 4-Bromobenzylamine Hydrochloride >97.0%(N)(T) | 26177-44-6 | 25g | $429 | 2026-04-30 | Buy |
| Apolloscientific | OR8654 | 4-Bromobenzylamine hydrochloride 98% | 26177-44-6 | 25g | $75 | 2026-06-04 | Buy |
| Apolloscientific | OR8654 | 4-Bromobenzylamine hydrochloride 98% | 26177-44-6 | 100g | $224 | 2026-06-04 | Buy |
4-Bromobenzylamine hydrochloride Chemical Properties, Uses, Production
Chemical Properties
OFF-WHITE TO BEIGE CRYSTALLINE POWDER
Uses
4-Bromobenzylamine hydrochloride is used to study the characteristics of C-terminal polyamine modification in the presence of protease and amine. Further, it is used to prepare 1-(4-Brombenzyl)-pyrrole by reacting with 2,5-dimethoxy-tetrahydro-furan.
Synthesis
623-00-7
26177-44-6
General procedure: in a glove box, to a flame-dried GLC vial fitted with a magnetic stirring bar was added [3a] + [BArF4] (1.0 mol%) and Me2PhSiH(2a) (2.1 or 5.0 equivalents). The specified 4-bromobenzonitrile was added to the glove box (in case of solid material) or via a microsyringe outside the glove box. The resulting reaction mixture was kept at room temperature for the indicated time. Upon completion of the reaction, a mixture of cyclohexane and tert-butyl methyl ether (90:10) containing 4% Et3N (0.5 mL) was added to quench the reaction. The resulting solution was filtered through a diatomaceous earth pad coated with a small amount of silica gel, and a solution of cyclohexane and tert-butyl methyl ether (90:10) containing 4% Et3N (3-4 mL) was used as the eluent. The solvent was removed under reduced pressure and the residue was dissolved in Et2O (1 mL), followed by the addition of HCl (2M in Et2O, 1.0 mL, 2.0 mmol, 10 equiv). The resulting suspension was stirred for 1 h and filtered to give 4-bromobenzylamine hydrochloride as a white to yellow solid.
References
[1] Synlett, 2017, vol. 28, # 18, p. 2411 - 2414
[2] Tetrahedron, 2014, vol. 70, # 4, p. 975 - 983
[3] Tetrahedron Letters, 2009, vol. 50, # 50, p. 7005 - 7007
[4] Journal of the American Chemical Society, 2016, vol. 138, # 28, p. 8809 - 8814
[5] ACS Catalysis, 2018, vol. 8, # 10, p. 9125 - 9130
4-Bromobenzylamine hydrochloride Preparation Products And Raw materials
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Nanjing Jubai Biomedical Technology Co., Ltd. | 13585203734 | info@jbzml.com | China | 200 | 58 |
| Suzhou Lakestar Pharmatech Co., Ltd. | 0512-63970158-603 18018108880 | info@lakestarpharma.com | China | 399 | 59 |
| J & K SCIENTIFIC LTD. | 18210857532 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
| Meryer (Shanghai) Chemical Technology Co., Ltd. | 4006356688 18621169109 | market03@meryer.com | China | 40202 | 62 |
| Alfa Aesar | 400-6106006 | saleschina@alfa-asia.com | China | 30103 | 84 |
| TCI (Shanghai) Development Co., Ltd. | 021-67121386 | Sales-CN@TCIchemicals.com | China | 24512 | 81 |
| ShangHai DEMO Chemical Co.,Ltd | 400-021-7337 2355568890 | sales@demochem.com | China | 2569 | 57 |
| Energy Chemical | 400-0056266 | sales8178@energy-chemical.com | China | 45000 | 61 |
| Capot Chemical Co., Ltd | +86 (0) 571 85 58 67 18 | China | 18187 | 66 | |
| Beijing Ouhe Technology Co., Ltd | 13552068683 13522913783 | 2355560935@qq.com | China | 11775 | 60 |
View Latest Price from 4-Bromobenzylamine hydrochloride manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2026-08-20 | 4-Bromobenzylamine hydrochloride
26177-44-6
|
$1.10 | 1g | 99.00% | 100 Tons Min | Dideu Industries Group Limited | |
 |
2019-07-06 | 4-Bromobenzylamine hydrochloride
26177-44-6
|
$3.00 | 1KG | 99% | 100kg | Career Henan Chemical Co |
-
- 4-Bromobenzylamine hydrochloride
26177-44-6
- $1.10
- 99.00%
- Dideu Industries Group Limited
-
- 4-Bromobenzylamine hydrochloride
26177-44-6
- $3.00
- 99%
- Career Henan Chemical Co
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