6-FORMYL-2-PYRIDINE CARBOXYLIC ACID METHYL ESTER
- CAS No.
- 69950-65-8
- Chemical Name:
- 6-FORMYL-2-PYRIDINE CARBOXYLIC ACID METHYL ESTER
- Synonyms
- Methyl 6-formylpicolinate;6-formyl-2-pyridinecarboxylate;Methyl 6-formylpyridine-2-carboxylate;Methyl 6-formyl-2-pyridinecarboxylate;Methyl 6-formylpyridine-2-carboxylate 96%;6-FORMYL-2-PYRIDINE CARBOXYLIC ACID METHYL ESTER;2-Pyridinecarboxylic acid, 6-formyl-, methyl ester;methyl 6-formyl-2-pyridinecarboxylate(SALTDATA: FREE);2-Formyl-6-(methoxycarbonyl)pyridine, Methyl 6-formylpicolinate
- CBNumber:
- CB6205313
- Molecular Formula:
- C8H7NO3
- Molecular Weight:
- 165.15
- MDL Number:
- MFCD07367925
- MOL File:
- 69950-65-8.mol
| Product description | Number | Pack Size | Price |
| Methyl6-formylpicolinate | M305503 | 25mg | $45 |
| Methyl6-formylpicolinate | M305503 | 250mg | $75 |
| Methyl 6-formyl-2-pyridinecarboxylate 95+% | 119184 | 250mg | $144 |
| Methyl6-formylpyridine-2-carboxylate | Y9861 | 1g | $66 |
| Methyl6-formylpyridine-2-carboxylate 96% | OR16637 | 1g | $66 |
| Melting point | 94-98 °C |
|---|---|
| Boiling point | 296.6±25.0 °C(Predicted) |
| Density | 1.249±0.06 g/cm3(Predicted) |
| storage temp. | Inert atmosphere,Store in freezer, under -20°C |
| pka | 1.57±0.10(Predicted) |
| Appearance | White to light yellow Solid |
| InChI | InChI=1S/C8H7NO3/c1-12-8(11)7-4-2-3-6(5-10)9-7/h2-5H,1H3 |
| InChIKey | CERBENZCBVYKEF-UHFFFAOYSA-N |
| SMILES | C1(C(OC)=O)=NC(C=O)=CC=C1 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|---|---|
| Signal word | Warning |
| Hazard statements | H302-H315-H319-H332-H335 |
| Precautionary statements | P261-P280-P305+P351+P338 |
| HS Code | 2933399990 |
6-FORMYL-2-PYRIDINE CARBOXYLIC ACID METHYL ESTER price More Price(20)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| TRC | M305503 | Methyl6-formylpicolinate | 69950-65-8 | 25mg | $45 | 2021-12-16 | Buy |
| TRC | M305503 | Methyl6-formylpicolinate | 69950-65-8 | 250mg | $75 | 2021-12-16 | Buy |
| Matrix Scientific | 119184 | Methyl 6-formyl-2-pyridinecarboxylate 95+% | 69950-65-8 | 250mg | $144 | 2021-12-16 | Buy |
| AK Scientific | Y9861 | Methyl6-formylpyridine-2-carboxylate | 69950-65-8 | 1g | $66 | 2021-12-16 | Buy |
| Apolloscientific | OR16637 | Methyl6-formylpyridine-2-carboxylate 96% | 69950-65-8 | 1g | $66 | 2021-12-16 | Buy |
6-FORMYL-2-PYRIDINE CARBOXYLIC ACID METHYL ESTER Chemical Properties,Uses,Production
Synthesis
39977-44-1
69950-65-8
General procedure for the synthesis of methyl 6-formyl-2-pyridinecarboxylate from methyl 6-hydroxymethyl-2-pyridinecarboxylate: the product of Example 17A (8 g, 48 mmol) was dissolved in dichloromethane (200 mL) and electrolytic manganese dioxide (41.67 g, 0.48 mol) was added. The reaction mixture was stirred at 25 °C for 4 days and filtered through diatomaceous earth after completion of the reaction. The filtrate was concentrated under reduced pressure and the residue was purified by silica gel column chromatography to afford methyl 6-formyl-2-pyridinecarboxylate as a white solid (6.9 g, 87% yield) using a 5% dichloromethane solution of methanol as eluent.
References
[1] Patent: US2005/131017, 2005, A1. Location in patent: Page/Page column 106
[2] Patent: US6020345, 2000, A
[3] Bioorganic and Medicinal Chemistry Letters, 2003, vol. 13, # 4, p. 609 - 612
[4] Patent: WO2004/37808, 2004, A1. Location in patent: Page 9-10
[5] Chemistry of Heterocyclic Compounds, 2009, vol. 45, # 2, p. 161 - 168
6-FORMYL-2-PYRIDINE CARBOXYLIC ACID METHYL ESTER Preparation Products And Raw materials
Raw materials
Preparation Products
6-FORMYL-2-PYRIDINE CARBOXYLIC ACID METHYL ESTER Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29847 | 58 |
| Alchem Pharmtech,Inc. | 8485655694 | sales@alchempharmtech.com | United States | 63687 | 58 |
| Wuhan Chemwish Technology Co., Ltd | 027-67849912 | sales@chemwish.com | CHINA | 10821 | 58 |
| Dayang Chem (Hangzhou) Co.,Ltd. | +86-0571-88938639 +8617705817739 | info@dycnchem.com | China | 52846 | 58 |
| Hunan Jibang Biological Technology Co., LTD | +8613776644403 | sales02@kingboomtech.com | China | 1804 | 58 |
| Nanjing Doge Biomedical Technology Co., Ltd | +86-25-58227606 +86-15305155328 | sales@dogechemical.com | China | 4128 | 58 |
| HANGZHOU LEAP CHEM CO., LTD. | +86-571-87711850 | market18@leapchem.com | China | 24727 | 58 |
| GIHI CHEMICALS CO.,LIMITED | +8618058761490 | info@gihichemicals.com | China | 49944 | 58 |
| HANGZHOU LEAP CHEM CO., LTD. | +86-571-87711850 | market18@leapchem.com | China | 43339 | 58 |
| Aladdin Scientific | tp@aladdinsci.com | United States | 57505 | 58 |
View Lastest Price from 6-FORMYL-2-PYRIDINE CARBOXYLIC ACID METHYL ESTER manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
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2019-12-19 | 6-FORMYL-2-PYRIDINE CARBOXYLIC ACID METHYL ESTER
69950-65-8
|
US $1.00 / KG | 1KG | 98 | 10t | Career Henan Chemical Co |
-
- 6-FORMYL-2-PYRIDINE CARBOXYLIC ACID METHYL ESTER
69950-65-8
- US $1.00 / KG
- 98
- Career Henan Chemical Co
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