2-Bromo-6-fluorobenzonitrile
- CAS No.
- 79544-27-7
- Chemical Name:
- 2-Bromo-6-fluorobenzonitrile
- Synonyms
- 2-FLUORO-6-BROMOBENZONITRILE;6-BROMO-2-FLUOROBENZONITRILE;2-BROM;2-Bromo-6-fluorobenzon;2- fluoro-6-bromoxynil;2-Bromo-6-fluorobenzotrile;2-BROMO-6-FLUOROBENZONITRILE;3-bromo-2-cyanofluorobenzene;2-Cyano-3-Fluoro-1-broMobenzene;Benzonitrile, 2-bromo-6-fluoro-
- CBNumber:
- CB6216595
- Molecular Formula:
- C7H3BrFN
- Molecular Weight:
- 200.01
- MDL Number:
- MFCD06797753
- MOL File:
- 79544-27-7.mol
- MSDS File:
- SDS
Melting point | 60-61 |
---|---|
Boiling point | 254.6±25.0 °C(Predicted) |
Density | 1.69±0.1 g/cm3(Predicted) |
storage temp. | Inert atmosphere,Room Temperature |
form | Solid |
color | White to brown |
InChIKey | IELGUZKHALDFOO-UHFFFAOYSA-N |
CAS DataBase Reference | 79544-27-7(CAS DataBase Reference) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS07 |
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Signal word | Warning | |||||||||
Hazard statements | H302+H312+H332-H302-H315-H319-H335-H312-H332 | |||||||||
Precautionary statements | P264-P270-P271-P280-P301+P312+P330-P302+P352+P312+P362+P364-P304+P340+P312-P305+P351+P338+P337+P313-P501-P261-P305+P351+P338-P304+P340-P405-P501a | |||||||||
Hazard Codes | T,Xi,Xn | |||||||||
Risk Statements | 22-36/37/38 | |||||||||
Safety Statements | 26 | |||||||||
WGK Germany | 3 | |||||||||
Hazard Note | Toxic | |||||||||
HazardClass | IRRITANT-HARMFUL | |||||||||
HazardClass | 6.1 | |||||||||
HS Code | 2926907090 | |||||||||
NFPA 704 |
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2-Bromo-6-fluorobenzonitrile price More Price(32)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
TCI Chemical | B3183 | 2-Bromo-6-fluorobenzonitrile >97.0%(GC) | 79544-27-7 | 5g | $66 | 2024-03-01 | Buy |
Alfa Aesar | H61498 | 2-Bromo-6-fluorobenzonitrile, 97% | 79544-27-7 | 5g | $36.7 | 2021-12-16 | Buy |
Alfa Aesar | H61498 | 2-Bromo-6-fluorobenzonitrile, 97% | 79544-27-7 | 25g | $147 | 2021-12-16 | Buy |
TRC | B692023 | 2-Bromo-6-fluorobenzonitrile | 79544-27-7 | 500mg | $45 | 2021-12-16 | Buy |
Matrix Scientific | 018273 | 2-Bromo-6-fluorobenzonitrile 98% | 79544-27-7 | 25g | $49 | 2021-12-16 | Buy |
2-Bromo-6-fluorobenzonitrile Chemical Properties,Uses,Production
Chemical Properties
Off-white crystalline
Uses
2-Bromo-6-fluorobenzonitrile is used as an initial raw material in the synthesis of 2-bromo-6-fluorobenzoic acid.
Synthesis
2-Amino-6-fluorobenzonitrile (18.0 g, 132 mmol) was dissolved in hot 1,4-dioxane (20 ml), 48% hydrobromic acid (200 ml) was added and the mixture cooled to 0°C before dropwise addition of sodium nitrite (10.5 g, 152 mmol) in water (20 ml) over 1.5 h. The resulting mixture was stirred at 0°C for 1.5 h then poured onto a cooled (0°C) solution of copper(I) bromide (56.8 g, 396 mmol) in 48% hydrobromic acid (50 ml). The solution was stirred at 0°C for 15 min then heated at 50°C for 20 min. The mixture was cooled to ambient temperature, diluted with water (1200 ml) and extracted with ethyl acetate (2 x 400 ml). The combined organics were washed with 10% aqueous ammonia solution (400 ml), water (400 ml) and brine (500 ml), dried over anhydrous magnesium sulfate, filtered and evaporated to give an orange oil. Purification by chromatography on silica 5 gel eluting with isohexane on a gradient of ethyl acetate (2-4%) gave 2-bromo-6-fluorobenzonitrile. White solid, yield (18.5 g, 70%). δH (400 MHz, CDCl3) 7.17-7.23 (1H, ddd, J 8, 8 and 1), 7.44-7.52 (2H, m).
2-Bromo-6-fluorobenzonitrile Preparation Products And Raw materials
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Changzhou Anxuan Chemical Co., Ltd | +86-0519-89882563 +86-18961279162 | andy@anxuanchem.com | China | 4328 | 58 |
Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | sales@capotchem.com | China | 29798 | 60 |
Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 18628 | 58 |
career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29888 | 58 |
Win-Win Chemical CO., Limited | 0086-577-64498589 | sales@win-winchemical.com | CHINA | 998 | 58 |
Changzhou Ansciep Chemical Co., Ltd. | +86 519 86305871 | sales@ansciepchem.com | CHINA | 4242 | 58 |
Shenzhen Nexconn Pharmatechs Ltd | +86-755-89396905 +86-15013857715 | admin@nexconn.com | China | 10311 | 58 |
Accela ChemBio Inc. | +1-858-6993322 | info@accelachem.com | United States | 19536 | 58 |
Hubei xin bonus chemical co. LTD | 86-13657291602 | linda@hubeijusheng.com | CHINA | 22968 | 58 |
Chongqing Chemdad Co., Ltd | +86-023-6139-8061 +86-86-13650506873 | sales@chemdad.com | China | 39916 | 58 |
View Lastest Price from 2-Bromo-6-fluorobenzonitrile manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
---|---|---|---|---|---|---|---|---|
2024-08-21 | 2-BROMO-6-FLUOROBENZONITRILE
79544-27-7
|
US $0.00 / KG | 1KG | 98% | 1MT | Changzhou Anxuan Chemical Co., Ltd | ||
2019-07-06 | 2-BROMO-6-FLUOROBENZONITRILE
79544-27-7
|
US $1.00 / KG | 1KG | 99% | Customized | Career Henan Chemical Co |
- 2-BROMO-6-FLUOROBENZONITRILE
79544-27-7
- US $0.00 / KG
- 98%
- Changzhou Anxuan Chemical Co., Ltd
- 2-BROMO-6-FLUOROBENZONITRILE
79544-27-7
- US $1.00 / KG
- 99%
- Career Henan Chemical Co
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