ChemicalBook >> CAS DataBase List >>(-)-1,2-BIS((2S,5S)-2,5-DIETHYLPHOSPHOLANO)ETHANE

(-)-1,2-BIS((2S,5S)-2,5-DIETHYLPHOSPHOLANO)ETHANE

(-)-1,2-BIS((2S,5S)-2,5-DIETHYLPHOSPHOLANO)ETHANE structure

CAS No.: 136779-27-6

Chemical Name:: (-)-1,2-BIS((2S,5S)-2,5-DIETHYLPHOSPHOLANO)ETHANE

Synonyms: (S,S)-ET-BPE;(-)-1,2-BIS((2S,5S)-2,5-DIETHYLPHOSPHOLANO)ETHANE;(-)-1,2-bis-((2S,5S)-2,5-Diethylphospholano)ethane;(-)-1,2-Bis[(2S,5S)-2,5-diethyl-1-phospholanyl]ethane;(-)-1,2-Bis[(2S,5S)-2,5-diethyl-1-phospholanyl]ethane;(-)-1,2-Bis[(2S,5S)-2,5-diethyl-1-phospholanyl]ethane, 97+%;(-)-1,2-Bis((2S,5S)-2,5-diethylphospholano)ethane (S,S)-Et-BPE;(-)-1,2-Bis[(2S,5S)-2,5-diethylphospholano]ethane, Kanata purity;(-)-1,2-Bis((2S,5S)-2,5-diethylphospholano)ethane,98+%(S,S)-Et-BPE;(-)-1,2-Bis[(2S,5S)-2,5-diethylphospholano]ethane, 97% (S,S-Et-BPE)

CBNumber:: CB6271770

Molecular Formula:: C18H36P2

Molecular Weight:: 314.43

MDL Number:: MFCD01073769

MOL File:: 136779-27-6.mol

Last updated:2023-04-23 13:52:06

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(-)-1,2-BIS((2S,5S)-2,5-DIETHYLPHOSPHOLANO)ETHANE Properties

alpha	-320° ±4° (c 1, hexane)
Boiling point	104-106°C 0,5mm
refractive index	n 20/D 1.5243
form	liquid
color	colorless to pale-yellow
Sensitive	air sensitive
FDA UNII	OGD5P7X3R9

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS02

Signal word

Danger

Hazard statements

H250

Precautionary statements

P222-P231-P422

Hazard Codes

Risk Statements

36/37/38-17

Safety Statements

26-36/37/39-6

RIDADR

UN 2845 4.2/PG 1

WGK Germany

NFPA 704

	4
2		0

(-)-1,2-BIS((2S,5S)-2,5-DIETHYLPHOSPHOLANO)ETHANE price More Price(7)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Strem Chemicals	15-0102	(-)-1,2-Bis((2S,5S)-2,5-diethylphospholano)ethane, 98+% (S,S)-Et-BPE	136779-27-6	100mg	$79	2024-03-01	Buy
Strem Chemicals	15-0102	(-)-1,2-Bis((2S,5S)-2,5-diethylphospholano)ethane, 98+% (S,S)-Et-BPE	136779-27-6	500mg	$278	2024-03-01	Buy
Strem Chemicals	15-0102	(-)-1,2-Bis((2S,5S)-2,5-diethylphospholano)ethane, 98+% (S,S)-Et-BPE	136779-27-6	2g	$874	2024-03-01	Buy
American Custom Chemicals Corporation	ING0001091	(-)-1,2-BIS((2S,5S)-2,5-DIETHYLPHOSPHOLANO)ETHANE 95.00%	136779-27-6	2G	$1238	2021-12-16	Buy
American Custom Chemicals Corporation	ING0001091	(-)-1,2-BIS((2S,5S)-2,5-DIETHYLPHOSPHOLANO)ETHANE 95.00%	136779-27-6	100MG	$474.3	2021-12-16	Buy

Product number	Packaging	Price	Buy
15-0102	100mg	$79	Buy
15-0102	500mg	$278	Buy
15-0102	2g	$874	Buy
ING0001091	2G	$1238	Buy
ING0001091	100MG	$474.3	Buy

(-)-1,2-BIS((2S,5S)-2,5-DIETHYLPHOSPHOLANO)ETHANE Chemical Properties,Uses,Production

Reaction

The DUPHOS family of catalysts is highly efficient for the asymmetric hydrogenation of various substituted acetamidoacrylates and enol acetates yielding products of high enantiomeric excesses. Efficient ligand for the asymmetric hydrogenation of tetrasubstituted enamides.
Forms superior catalysts for asymmetric reductive aminations.
Catalyst used for the asymmetric hydrogenation of enol phosphonates.
A novel enantioselective synthesis of β-amino alcohols and 1,2-diamines.
Ligand for the catalytic asymmetric [4+1] cycloaddition of vinylallenes with CO.
Ligand for the Rh-catalyzed asymmetric enyne cycloisomerization.
Catalytic enantioselective addition of dialkylzinc to N-Diphenylphosphinoylimines.
Palladium catalyzed asymmetric phosphination.

Uses

DuPhos and BPE Ligands: Highly Efficient Privileged Ligands

(-)-1,2-BIS((2S,5S)-2,5-DIETHYLPHOSPHOLANO)ETHANE Preparation Products And Raw materials

Raw materials

Preparation Products

(-)-1,2-BIS((2S,5S)-2,5-DIETHYLPHOSPHOLANO)ETHANE Suppliers

Global( 29)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Career Henan Chemica Co	+86-0371-86658258 +8613203830695	laboratory@coreychem.com	China	30250	58
Dayang Chem (Hangzhou) Co.,Ltd.	571-88938639 +8617705817739	info@dycnchem.com	China	52861	58
PT CHEM GROUP LIMITED		peter68@ptchemgroup.com	China	35426	58
GIHI CHEMICALS CO.,LIMITED	+8618058761490	info@gihichemicals.com	China	50003	58
Aladdin Scientific	+1-+1(833)-552-7181	sales@aladdinsci.com	United States	52927	58
J & K SCIENTIFIC LTD.	010-82848833 400-666-7788	jkinfo@jkchemical.com	China	96815	76
Meryer (Shanghai) Chemical Technology Co., Ltd.	021-61259108 18621169109	market03@meryer.com	China	40240	62
Alfa Aesar	400-6106006	saleschina@alfa-asia.com	China	30132	84
Energy Chemical	021-021-58432009 400-005-6266	sales8178@energy-chemical.com	China	44700	61
Sigma-Aldrich	021-61415566 800-8193336	orderCN@merckgroup.com	China	51471	80

Supplier	Advantage
Career Henan Chemica Co	58
Dayang Chem (Hangzhou) Co.,Ltd.	58
PT CHEM GROUP LIMITED	58
GIHI CHEMICALS CO.,LIMITED	58
Aladdin Scientific	58
J & K SCIENTIFIC LTD.	76
Meryer (Shanghai) Chemical Technology Co., Ltd.	62
Alfa Aesar	84
Energy Chemical	61
Sigma-Aldrich	80

136779-27-6((-)-1,2-BIS((2S,5S)-2,5-DIETHYLPHOSPHOLANO)ETHANE)Related Search:

(+)-1,2-BIS((2R,5R)-2,5-DIETHYLPHOSPHOLANO)ETHANE (-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE 1,2-BIS((2R,5R)-2,5-DIISOPROPYLPHOSPHOLANO)ETHANE 1,2-BIS(DIETHYLPHOSPHINO)ETHANE (-)-1,2-BIS((2S,5S)-2,5-DIETHYLPHOSPHOLANO)ETHANE

(S,S)-ET-BPE (-)-1,2-BIS((2S,5S)-2,5-DIETHYLPHOSPHOLANO)ETHANE (-)-1,2-Bis[(2S,5S)-2,5-diethylphospholano]ethane, Kanata purity (-)-1,2-Bis((2S,5S)-2,5-diethylphospholano)ethane,98+%(S,S)-Et-BPE (-)-1,2-Bis[(2S,5S)-2,5-diethyl-1-phospholanyl]ethane, 97+% (-)-1,2-Bis((2S,5S)-2,5-diethylphospholano)ethane (S,S)-Et-BPE (-)-1,2-Bis[(2S,5S)-2,5-diethylphospholano]ethane, 97% (S,S-Et-BPE) (2S,5S)-1-[2-[(2S,5S)-2,5-diethylphospholan-1-yl]ethyl]-2,5-diethylphospholane (-)-1,2-Bis[(2S,5S)-2,5-diethyl-1-phospholanyl]ethane Phospholane, 1,1'-(1,2-ethanediyl)bis[2,5-diethyl-, (2S,2'S,5S,5'S)- (-)-1,2-Bis[(2S,5S)-2,5-diethyl-1-phospholanyl]ethane (-)-1,2-bis-((2S,5S)-2,5-Diethylphospholano)ethane 136779-27-6 Asymmetric Synthesis Chiral Catalysts, Ligands, and Reagents DuPhos/BPE Privileged Ligands organophosphine ligand