ChemicalBook >> CAS DataBase List >>(s,s)-2-ALLYL-2-CHLORO-3,4-DIMETHYL-5-PHENYL-[1,3,2]-OXAZASILOLIDINE
(s,s)-2-ALLYL-2-CHLORO-3,4-DIMETHYL-5-PHENYL-[1,3,2]-OXAZASILOLIDINE
![(s,s)-2-ALLYL-2-CHLORO-3,4-DIMETHYL-5-PHENYL-[1,3,2]-OXAZASILOLIDINE Structure](CAS/GIF/447440-43-9.gif)
- CAS No.
- 447440-43-9
- Chemical Name:
- (s,s)-2-ALLYL-2-CHLORO-3,4-DIMETHYL-5-PHENYL-[1,3,2]-OXAZASILOLIDINE
- Synonyms
- 1-Oxa-3-aza-2-silacyclopentane,2-chloro-3,4-dimethyl-5-pheny...;(s,s)-2-ALLYL-2-CHLORO-3,4-DIMETHYL-5-PHENYL-[1,3,2]-OXAZASILOLIDINE;(4S,5S)-2-Allyl-2-chloro-3,4-dimethyl-5-phenyl-1,3,2-oxazasilolidine;(4S,5S)-2-chloro-3,4-dimethyl-5-phenyl-2-prop-2-enyl-1,3,2-oxazasilolidine;(4S,5S)-2-Allyl-2-chloro-3,4-dimethyl-5-phenyl-1-oxa-3-aza-2-silacyclopentane ;1-Oxa-3-aza-2-silacyclopentane, 2-chloro-3,4-dimethyl-5-phenyl-2-(2-propen-1-yl)-, (4S,5S)-
- CBNumber:
- CB72134999
- Molecular Formula:
- C13H18ClNOSi
- Molecular Weight:
- 267.83
- MDL Number:
- MFCD09953823
- MOL File:
- 447440-43-9.mol
- MSDS File:
- SDS
| Density | 1.095 g/mL at 25 °C |
|---|---|
| refractive index | n20/D1.517 |
| Flash point | 38℃ |
| pka | 4.43±0.60(Predicted) |
| Specific Gravity | 1.01 |
| optical activity | [α]20/D 72.5°, c = 0.6 in ethanol (200 proof) |
| Hydrolytic Sensitivity | 8: reacts rapidly with moisture, water, protic solvents |
| Sensitive | moisture sensitive, store cold |
| Boiling point | 120°C/5 mmHg |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS02,GHS07 |
|---|---|
| Signal word | Danger |
| Hazard statements | H226-H261-H315-H319-H335 |
| Precautionary statements | P231+P232-P261-P305+P351+P338-P422 |
| Hazard Codes | F,Xi |
| Risk Statements | 10-15-36/37/38 |
| Safety Statements | 26 |
| RIDADR | UN 3132 / PGII |
| WGK Germany | 3 |
(s,s)-2-ALLYL-2-CHLORO-3,4-DIMETHYL-5-PHENYL-[1,3,2]-OXAZASILOLIDINE price More Price(2)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Strem Chemicals | 14-1815 | (4S,5S)-2-Allyl-2-chloro-3,4-dimethyl-5-phenyl-1-oxa-3-aza-2-silacyclopentane, min. 98% (~2:1 mixture of diastereomers) | 447440-43-9 | 1g | $99 | 2024-03-01 | Buy |
| Strem Chemicals | 14-1815 | (4S,5S)-2-Allyl-2-chloro-3,4-dimethyl-5-phenyl-1-oxa-3-aza-2-silacyclopentane, min. 98% (~2:1 mixture of diastereomers) | 447440-43-9 | 5g | $395 | 2024-03-01 | Buy |
(s,s)-2-ALLYL-2-CHLORO-3,4-DIMETHYL-5-PHENYL-[1,3,2]-OXAZASILOLIDINE Chemical Properties,Uses,Production
Reaction
Versatile reagent for the enantioselective allylation of aldehydes and hydrazones.
Uses
Leighton′s Strained Silacycles: Powerful Enantioselective Allylation Reagents
- Practical, enantioselective allylation of acylhydrazones
- Enantioselective allylation of ketimines: synthesis of tertiary carbinamines
General Description
This product is a mixture of diastereomers.
(s,s)-2-ALLYL-2-CHLORO-3,4-DIMETHYL-5-PHENYL-[1,3,2]-OXAZASILOLIDINE Preparation Products And Raw materials
Raw materials
Preparation Products
Global( 15)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 15954 | 58 |
| Chongqing Chemdad Co., Ltd | +86-023-6139-8061 +86-86-13650506873 | sales@chemdad.com | China | 39916 | 58 |
| Henan Alfa Chemical Co., Ltd | +8618339805032 | alfa4@alfachem.cn | China | 13039 | 58 |
| Hefei TNJ Chemical Industry Co.,Ltd. | 0551-65418684 +8618949823763 | sales@tnjchem.com | China | 25363 | 58 |
| Aladdin Scientific | +1-+1(833)-552-7181 | sales@aladdinsci.com | United States | 52927 | 58 |
| J & K SCIENTIFIC LTD. | 010-82848833 400-666-7788 | jkinfo@jkchemical.com | China | 96815 | 76 |
| Meryer (Shanghai) Chemical Technology Co., Ltd. | 021-61259108 18621169109 | market03@meryer.com | China | 40240 | 62 |
| Sigma-Aldrich | 021-61415566 800-8193336 | orderCN@merckgroup.com | China | 51471 | 80 |
| Aikon International Limited | 025-58851090 13611564524 | lwan@aikonchem.com | China | 15952 | 58 |
| Suzhou Siso new material Co.,Ltd. | 0512-65402974 18550909935; | siso03@126.com | China | 1892 | 58 |
447440-43-9((s,s)-2-ALLYL-2-CHLORO-3,4-DIMETHYL-5-PHENYL-[1,3,2]-OXAZASILOLIDINE)Related Search:
(s,s)-2-ALLYL-2-CHLORO-3,4-DIMETHYL-5-PHENYL-[1,3,2]-OXAZASILOLIDINE
(4S,5S)-2-Allyl-2-chloro-3,4-dimethyl-5-phenyl-1-oxa-3-aza-2-silacyclopentane
1-Oxa-3-aza-2-silacyclopentane,2-chloro-3,4-dimethyl-5-pheny...
(4S,5S)-2-chloro-3,4-dimethyl-5-phenyl-2-prop-2-enyl-1,3,2-oxazasilolidine
(4S,5S)-2-Allyl-2-chloro-3,4-dimethyl-5-phenyl-1,3,2-oxazasilolidine
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447440-43-9
C13H18ClNOSi
organosilicon compound