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TERT-BUTYL 3-BROMO-1H-PYRROLO[2,3-B]PYRIDINE-1-CARBOXYLATE

TERT-BUTYL 3-BROMO-1H-PYRROLO[2,3-B]PYRIDINE-1-CARBOXYLATE structure

CAS No.: 226085-17-2

Chemical Name:: TERT-BUTYL 3-BROMO-1H-PYRROLO[2,3-B]PYRIDINE-1-CARBOXYLATE

Synonyms: 1-Boc-3-bromo-7-azaindole;3-Bromo-1H-pyrrolo[2,3-b]pyridine, N-BOC protected;3-Bromo-1H-pyrrolo[2,3-b]pyridine, N1-BOC protected;tert-Butyl 3-broMopyrrolo[2,3-b]pyridine-1-carboxylate;TERT-BUTYL 3-BROMO-1H-PYRROLO[2,3-B]PYRIDINE-1-CARBOXYLAT;TERT-BUTYL 3-BROMO-1H-PYRROLO[2,3-B]PYRIDINE-1-CARBOXYLATE;1H-Pyrrolo[2,3-b]pyridine-1-carboxylic acid,3-bromo-, 1,1-dimethylethyl ester;tert-Butyl 3-bromo-1H-pyrrolo[2,3-b]pyridine-1-carboxylate, 3-Bromo-1-(tert-butoxycarbonyl)-1H-pyrrolo[2,3-b]pyridine

CBNumber:: CB7808562

Molecular Formula:: C12H13BrN2O2

Molecular Weight:: 297.15

MDL Number:: MFCD08689737

MOL File:: 226085-17-2.mol

MSDS File:: SDS

Last updated:2025-07-24 18:13:46

Product description	Number	Pack Size	Price
tert-Butyl3-Bromo-1H-pyrrolo[2,3-b]pyridine-1-carboxylate	T135578	500mg	$200
tert-Butyl 3-bromopyrrolo[2,3-b]pyridine-1-carboxylate	FB154069	500mg	$75
tert-Butyl 3-bromo-1H-pyrrolo[2,3-b]pyridine-1-carboxylate >95%	047090	500mg	$80
tert-Butyl 3-bromo-1H-pyrrolo[2,3-b]pyridine-1-carboxylate >95%	047090	1g	$107
tert-Butyl 3-bromopyrrolo[2,3-b]pyridine-1-carboxylate	FB154069	1g	$131
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TERT-BUTYL 3-BROMO-1H-PYRROLO[2,3-B]PYRIDINE-1-CARBOXYLATE Properties

Boiling point	376.7±45.0 °C(Predicted)
Density	1.46±0.1 g/cm3(Predicted)
storage temp.	under inert gas (nitrogen or Argon) at 2-8°C
pka	1.65±0.30(Predicted)
Appearance	Light yellow to yellow Liquid

SAFETY

Risk and Safety Statements

Symbol(GHS)	GHS07
Signal word	Warning
Hazard statements	H302-H315-H319-H332-H335
Precautionary statements	P280-P305+P351+P338-P310
Hazard Codes	Xi
HazardClass	IRRITANT
HS Code	2933399990

TERT-BUTYL 3-BROMO-1H-PYRROLO[2,3-B]PYRIDINE-1-CARBOXYLATE price More Price(21)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
TRC	T135578	tert-Butyl3-Bromo-1H-pyrrolo[2,3-b]pyridine-1-carboxylate	226085-17-2	500mg	$200	2021-12-16	Buy
Biosynth Carbosynth	FB154069	tert-Butyl 3-bromopyrrolo[2,3-b]pyridine-1-carboxylate	226085-17-2	500mg	$75	2021-12-16	Buy
Matrix Scientific	047090	tert-Butyl 3-bromo-1H-pyrrolo[2,3-b]pyridine-1-carboxylate >95%	226085-17-2	500mg	$80	2021-12-16	Buy
Matrix Scientific	047090	tert-Butyl 3-bromo-1H-pyrrolo[2,3-b]pyridine-1-carboxylate >95%	226085-17-2	1g	$107	2021-12-16	Buy
Biosynth Carbosynth	FB154069	tert-Butyl 3-bromopyrrolo[2,3-b]pyridine-1-carboxylate	226085-17-2	1g	$131	2021-12-16	Buy

Product number	Packaging	Price	Buy
T135578	500mg	$200	Buy
FB154069	500mg	$75	Buy
047090	500mg	$80	Buy
047090	1g	$107	Buy
FB154069	1g	$131	Buy

TERT-BUTYL 3-BROMO-1H-PYRROLO[2,3-B]PYRIDINE-1-CARBOXYLATE Chemical Properties,Uses,Production

Synthesis

74420-15-8

24424-99-5

TERT-BUTYL 3-BROMO-1H-PYRROLO[2,3-B]PYRIDINE-1-CARBOXYLATE

226085-17-2

Under nitrogen atmosphere, 3-bromo-1H-pyrrolo[2,3-b]pyridine (0.10 g, 0.50 mmol) was dissolved in tetrahydrofuran (THF, 4.0 mL) followed by the addition of 4-dimethylaminopyridine (DMAP, 0.006 g, 0.06 mmol). The reaction mixture was cooled to -20 °C and di-tert-butyl dicarbonate (Boc anhydride, 122 μL, 0.56 mmol) was slowly added. The reaction mixture was gradually warmed to room temperature and stirred continuously for 2 hours. The reaction progress was monitored by thin layer chromatography (TLC). Upon completion of the reaction, water (20 mL) was added to the mixture and extracted with ethyl acetate (EtOAc, 3 × 50 mL). The organic phases were combined, dried with anhydrous sodium sulfate (Na2SO4), filtered and concentrated. The crude product was purified by silica gel column chromatography (60-120 mesh, 5% ethyl acetate-hexane as eluent) to afford the target product 1-BOC-3-bromo-7-azaindole as an oil (0.12 g, 79% yield).

References

[1] Synthesis, 1999, # 4, p. 615 - 620
[2] Patent: WO2009/74812, 2009, A1. Location in patent: Page/Page column 59

TERT-BUTYL 3-BROMO-1H-PYRROLO[2,3-B]PYRIDINE-1-CARBOXYLATE Preparation Products And Raw materials

Raw materials

3-Bromo-7-azaindole Di-tert-butyl dicarbonate

Preparation Products

TERT-BUTYL 3-BROMO-1H-PYRROLO[2,3-B]PYRIDINE-1-CARBOXYLATE Suppliers

Global( 85)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Capot Chemical Co.,Ltd.	+86-（0）57185586718; +8613336195806	sales@capot.com	China	29640	60
Shanghai Daken Advanced Materials Co.,Ltd	+86-2158073036	info@dakenam.com	China	13843	58
Alchem Pharmtech,Inc.	8485655694	sales@alchempharmtech.com	United States	63687	58
career henan chemical co	+86-0371-86658258 +8613203830695	factory@coreychem.com	China	29794	58
Guangzhou Yuheng Pharmaceutical Technology Co., Ltd	+8613580539051	joe@yuhengpharm.com	CHINA	21142	58
Neostar United (Changzhou) Industrial Co., Ltd.	+86-0519-85551759 +8613506123987	marketing1@neostarunited.com	China	8828	58
Dayang Chem (Hangzhou) Co.,Ltd.	+86-0571-88938639 +8617705817739	info@dycnchem.com	China	52705	58
PT CHEM GROUP LIMITED	+86-85511178;	peter68@ptchemgroup.com	China	35425	58
GIHI CHEMICALS CO.,LIMITED	+86-571-86217390; +8618058761490	info@gihichemicals.com	China	49968	58
Zhengzhou Lingzhiyue Technology Co., Ltd	+86-0371-55074660 +86-13523716970	Lingzhiyue@aliyun.com	China	3145	58

Supplier	Advantage
Capot Chemical Co.,Ltd.	60
Shanghai Daken Advanced Materials Co.,Ltd	58
Alchem Pharmtech,Inc.	58
career henan chemical co	58
Guangzhou Yuheng Pharmaceutical Technology Co., Ltd	58
Neostar United (Changzhou) Industrial Co., Ltd.	58
Dayang Chem (Hangzhou) Co.,Ltd.	58
PT CHEM GROUP LIMITED	58
GIHI CHEMICALS CO.,LIMITED	58
Zhengzhou Lingzhiyue Technology Co., Ltd	58

View Lastest Price from TERT-BUTYL 3-BROMO-1H-PYRROLO[2,3-B]PYRIDINE-1-CARBOXYLATE manufacturers

Image	Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
	2020-01-10	tert-butyl 3-bromopyrrolo[2,3-b]pyridine-1-carboxylate 226085-17-2	US $1.00 / KG	1KG	99%	200kg	Career Henan Chemical Co

tert-butyl 3-bromopyrrolo[2,3-b]pyridine-1-carboxylate
226085-17-2
US $1.00 / KG
99%
Career Henan Chemical Co

TERT-BUTYL 3-BROMO-1H-PYRROLO[2,3-B]PYRIDINE-1-CARBOXYLATE Spectrum

TERT-BUTYL 3-BROMO-1H-PYRROLO[2,3-B]PYRIDINE-1-CARBOXYLATE(226085-17-2)¹HNMR

226085-17-2(TERT-BUTYL 3-BROMO-1H-PYRROLO[2,3-B]PYRIDINE-1-CARBOXYLATE)Related Search:

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TERT-BUTYL 3-BROMO-1H-PYRROLO[2,3-B]PYRIDINE-1-CARBOXYLATE 3-Bromo-1H-pyrrolo[2,3-b]pyridine, N-BOC protected 1H-Pyrrolo[2,3-b]pyridine-1-carboxylic acid,3-bromo-, 1,1-dimethylethyl ester 1-Boc-3-bromo-7-azaindole 3-Bromo-1H-pyrrolo[2,3-b]pyridine, N1-BOC protected tert-Butyl 3-bromo-1H-pyrrolo[2,3-b]pyridine-1-carboxylate, 3-Bromo-1-(tert-butoxycarbonyl)-1H-pyrrolo[2,3-b]pyridine tert-Butyl 3-broMopyrrolo[2,3-b]pyridine-1-carboxylate TERT-BUTYL 3-BROMO-1H-PYRROLO[2,3-B]PYRIDINE-1-CARBOXYLAT 226085-17-2 138343-77-9 Heterocycle-Pyridine series