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diethyl methylidenemalonate

CAS No.
3377-20-6
Chemical Name:
diethyl methylidenemalonate
Synonyms
Diethyl 2-methylenemalonate;Diethyl methylenemalonate;SKL217;diethyl methylidenemalonate;diethyl methylidenepropanedioate;diethyl 2-methylidenepropanedioate;Diethyl ethylene-1,1-dicarboxylate;Methylenemalonic acid diethyl ester;Methylenepropanedioic acid diethyl ester;Propanedioic acid,2-Methylene-, 1,3-diethyl este
CBNumber:
CB81361760
Molecular Formula:
C8H12O4
Molecular Weight:
172.18
MDL Number:
MFCD01756915
MOL File:
3377-20-6.mol
MSDS File:
SDS
Last updated:2023-04-23 13:52:06

diethyl methylidenemalonate Properties

Melting point 135.5-136.5 °C(Solv: ethanol (64-17-5))
Boiling point 210 °C
Density 1.052 g/cm3(Temp: 25 °C)
storage temp. Inert atmosphere,Store in freezer, under -20°C
solubility Chloroform (Slightly), Dichloromethane (Slightly)
form Oil
color Light Yellow
Stability Light Sensitive

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319
Precautionary statements  P264-P280-P302+P352-P337+P313-P305+P351+P338-P362+P364-P332+P313
Toxicity mouse,LD,intraperitoneal,> 500mg/kg (500mg/kg),"Summary Tables of Biological Tests," National Research Council Chemical-Biological Coordination Center. Vol. 6, Pg. 147, 1954.

diethyl methylidenemalonate price More Price(12)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TRC D495945 Diethyl2-Methylenemalonate(StabilizedwithTBC,>85%) 3377-20-6 50mg $75 2021-12-16 Buy
Biosynth Carbosynth FD164901 Diethyl 2-methylenemalonate 3377-20-6 100mg $120 2021-12-16 Buy
Biosynth Carbosynth FD164901 Diethyl 2-methylenemalonate 3377-20-6 250mg $235 2021-12-16 Buy
Biosynth Carbosynth FD164901 Diethyl 2-methylenemalonate 3377-20-6 500mg $360 2021-12-16 Buy
Biosynth Carbosynth FD164901 Diethyl 2-methylenemalonate 3377-20-6 1g $550 2021-12-16 Buy
Product number Packaging Price Buy
D495945 50mg $75 Buy
FD164901 100mg $120 Buy
FD164901 250mg $235 Buy
FD164901 500mg $360 Buy
FD164901 1g $550 Buy

diethyl methylidenemalonate Chemical Properties,Uses,Production

Uses

Diethyl 2-methylenemalonate could be a used reagent for synthesizing donor-acceptor cyclobutanes via copper acetate or iron trichloride catalyzed [2+2] cycloaddition.g

diethyl methylidenemalonate Preparation Products And Raw materials

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diethyl methylidenemalonate Diethyl ethylene-1,1-dicarboxylate Methylenemalonic acid diethyl ester Methylenepropanedioic acid diethyl ester Propanedioic acid, 2-Methylene-, 1,3-diethyl ester Propanedioic acid,2-Methylene-, 1,3-diethyl este diethyl 2-methylidenepropanedioate Diethyl 2-Methylenemalonate (Stabilized with TBC, >85%) SKL217 Diethyl methylenemalonate Diethyl 2-methylenemalonate diethyl methylidenepropanedioate 3377-20-6