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DIENOCHLOR

CAS No.
2227-17-0
Chemical Name:
DIENOCHLOR
Synonyms
PENTAC;HRS 16;hrs-16;hrs16a;HRS 16A;hrs1654;HRS 1654;pentacsp;pentacwp;NSC 26106
CBNumber:
CB8760739
Molecular Formula:
C10Cl10
Molecular Weight:
474.64
MDL Number:
MFCD00019272
MOL File:
2227-17-0.mol
Last updated:2023-05-04 17:34:35

DIENOCHLOR Properties

Melting point 122-123℃
Boiling point 547.24°C (rough estimate)
Density 1.8769 (rough estimate)
vapor pressure 2.9 x 10-4 Pa (25 °C)
refractive index 1.6000 (estimate)
Water Solubility 0.025 mg l-1
Merck 13,3131
BRN 2064747
EWG's Food Scores 1
FDA UNII 243Z2SVZ40
Pesticides Freedom of Information Act (FOIA) Pentac
EPA Substance Registry System Dienochlor (2227-17-0)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS07,GHS09
Signal word  Warning
Hazard statements  H302-H410
Precautionary statements  P273-P301+P312+P330
Hazard Codes  Xn
Risk Statements  22
Safety Statements  22-24
RIDADR  2761
WGK Germany  3
RTECS  DT8225000
HazardClass  6.1(a)
PackingGroup  I
Toxicity Acute oral LD50 for male albino rats >3.16 g/kg, bobwhite quail 705 mg/kg (Worthing and Hance, 1991).

DIENOCHLOR price More Price(8)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 45443 Dienochlor PESTANAL 2227-17-0 250mg $61.4 2022-05-15 Buy
TRC D441878 Dienochlor 2227-17-0 500mg $70 2021-12-16 Buy
TRC D441878 Dienochlor 2227-17-0 250mg $45 2021-12-16 Buy
American Custom Chemicals Corporation HCH0107607 1,2,3,4,5-PENTACHLORO-5-(1,2,3,4,5-PENTACHLOROCYCLOPENTA-2,4-DIEN-1-YL)CYCLOPENTA-1,3-DIENE 95.00% 2227-17-0 1G $699.01 2021-12-16 Buy
American Custom Chemicals Corporation HCH0107607 1,2,3,4,5-PENTACHLORO-5-(1,2,3,4,5-PENTACHLOROCYCLOPENTA-2,4-DIEN-1-YL)CYCLOPENTA-1,3-DIENE 95.00% 2227-17-0 100MG $750.75 2021-12-16 Buy
Product number Packaging Price Buy
45443 250mg $61.4 Buy
D441878 500mg $70 Buy
D441878 250mg $45 Buy
HCH0107607 1G $699.01 Buy
HCH0107607 100MG $750.75 Buy

DIENOCHLOR Chemical Properties,Uses,Production

Uses

Acaricide used for control of mites on ornamentals.

Uses

Dienochlor is used for the control of mites (Tetrunychus spp., Panonychus ulmi and Polyphagotarsonemus latus) on roses, Chrysanthemums and other ornamentals.

Uses

Miticide.

Definition

ChEBI: Dienochlor is an organochlorine compound.

Environmental Fate

Plant. On plants, dienochlor was converted by sunlight to form perchloro ketones (Quistad and Mulholland, 1983).
Chemical/Physical. Dienochlor is unstable when exposed to sunlight. When dienochlor applied as a thin ?lm on glass plates was exposed to sunlight, nonpolar products, a tricyclic chlorocarbon and 3 isomeric perchloro ketones were formed at yields
Dienochlor begins to decompose at 130°C (Worthing and Hance, 1991).

Metabolic pathway

Dienochlor is readily degraded in sunlight to many products, only a few of which have been identified. It is also metabolised in animals but to unknown products. In vitro studies have shown that it interacts with thiols (glutathione, cysteine, efc.) and proteins.

Metabolism

Dienochlor decomposes in simulated sunlight (DT50 1.6 min). Degradation is mainly environmental rather than metabolic, and photochemical breakdown is rapid. It decomposes in soils, DT50 3.1 days and DT50 2–3 days on plants exposed to sunlight.The major degradation products of dienochlor in plants are perchloroketones. It is rapidly degraded in rats.

Degradation

Dienochlor is stable in storage at 54°C for 14 days and at 42°C over 2 years. It undergoes hydrolysis with DT50 values at pH 5,7 and 9 of 184, 93 and 30.5 days, respectively, at 25 °C. It decomposes in simulated sunlight with a DT50 of 1.6 minutes (PM).
A thin film of dienochlor on glass was readily degraded with a half-life of <1 hour on exposure to sunlight. Four photoproducts were isolated from a plethora of products and identified by 13C NMR spectroscopy (Quistad and Mulholland, 1983). The photocatalysed addition of two chlorine atoms (from donor dienochlor) afforded the tricyclic photochlorination product 2 (up to 10% yield). Three isomeric perchloroketones (3,4 and 5), each resulting from the net addition of one oxygen atom, were major products, both on glass (up to 14% combined isomers) and on cucumber and strawberry plants (up to 11% yield). Generally products 2, 3 and 4 were found in similar yields and 5 was the minor of the identified metabolites. The photochlorination product 2, however, was not detected on the plants. These products are illustrated in Scheme 1.

DIENOCHLOR Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 55)Suppliers
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1,1',2,2',3,3',4,4',5,5'-DECACHLOROBI-2,4-CYCLOPENTADIEN-1-YL 1,1’,2,2’,3,3’,4,4’,5,5’-decachlorobi-2,4-cyclopentadien-1-yl 1,1’,2,2’,3,3’,4,4’,5,5’-decachloro-bi-4-cyclopentadien-1-yl 1,1’2,2’,3,3’4,4’,5,5’-Decachlorodi-2,4-cy-clo-pentadien-1-yl PENTAC PENTAC (TM) DECACHLOROBIS(2,4-CYCLOPENTADIENE-1-YL) DIENOCHLOR BIS(PENTACHLORO-2,4-CYCLOPENTADIEN-1-YL) dienochlor (bsi,iso) BIS-(2,4-CYCLOPENTADIEN-1-YL),DECACHLORO- decachlorobicyclopenta-2,4-dienyl DIENOCHLOR PESTANAL, 250 MG Decachlorobis(2,4-cyclopentadiene-yl) 1,2,3,4,5-pentachloro-5-(1,2,3,4,5-pentachlorocyclopenta-2,4-dien-1-yl)cyclopenta-1,3-diene NSC 26106 NSC 41880 Dienochlor 0.2 1,1’2,2’3,3’4,4’5,5’-decachlorobi-2,4-cyclopentadien-1-yl Bi-2,4-cyclopentadien-1-yl, 1,1',2,2',3,3',4,4',5,5'-decachloro- Bi-2,4-cyclopentadien-1-yl, decachloro- Bi-2,4-cyclopentadien-1-yl,1,1’,2,2’,3,3’,4,4’,5,5’-decachloro- Bis(pentachlor-2,4-cyclopentadien-1-yl) Bis(pentachlorocyclopentadienyl) Decachlor Decachlorobi-2,4-cyclopentadien-1-yl Decachlorobi-2,4-cyclopentadiene-1-yl decachloro-bi-4-cyclopentadien-1-yl decachlorobis(2,4-cyclopentadien-1-yl) Dienochlore ENT 25,718 ent25,718 Hooker HRS 1654 Hooker HRS-16 hookerhrs-16 hookerhrs1654 HRS 16 HRS 1654 HRS 16A hrs-16 hrs1654 hrs16a Pentac aquaflow Pentac SP Pentac WP pentac(50wp) pentacsp pentacwp perchloro-1,1’-bicyclopenta-2,4-diene perchloro-1,1’-bicyclopenta-2,4-dienyl Perchlorobi(2,4-cyclopentadienyl) Cycloartenol Impurity 1 2227-17-0 227-17-0 C10Cl10 AcaricidesPesticides&Metabolites Alpha sort D