ChemicalBook >> CAS DataBase List >>lithium chloroacetylide

lithium chloroacetylide

CAS No.
6180-21-8
Chemical Name:
lithium chloroacetylide
Synonyms
lithium chloroacetylide
CBNumber:
CB94648050
Molecular Formula:
C2ClLi
Molecular Weight:
66.41
MDL Number:
MOL File:
6180-21-8.mol
Last updated:2025-01-13 16:57:10

lithium chloroacetylide Properties

Boiling point 101°C

lithium chloroacetylide Chemical Properties,Uses,Production

Uses

Lithium chloroacetylide is a nucleophilic organolithium reagent that reacts with a variety of electrophiles.

Preparation

Lithium chloroacetylide is prepared in ether solution under anhyd conditions by treatment of cis- or trans-1,2- dichloroethylene with 2 equiv Methyllithium at 0 °C under N2.

storage

Dry lithium chloroacetylide is explosive (as are the other metal  haloacetylides), but may be safely handled and kept in the solution in which it is prepared under N2.

lithium chloroacetylide Preparation Products And Raw materials

Raw materials

Preparation Products

lithium chloroacetylide 6180-21-8