Tricyclohexyl phosphine
- CAS No.
- 2622-14-2
- Chemical Name:
- Tricyclohexyl phosphine
- Synonyms
- PCY3;TRICYCLOHEXYLPHOSPHINE;Cy3P;TCHP;TricycL;Phosphine, tricyclohexyl-;NSC 158657;Protein TCHP;Tricyclohexyl phosph;tricyclohexylphospine
- CBNumber:
- CB9251553
- Molecular Formula:
- C18H33P
- Molecular Weight:
- 280.43
- MOL File:
- 2622-14-2.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/1/4 16:53:01
| Melting point | 81-83 °C (lit.) |
|---|---|
| Boiling point | 383.4±9.0 °C | Condition: Press: 760 Torr |
| Density | 0.909 g/mL at 25 °C |
| Flash point | 48 °F |
| storage temp. | Inert atmosphere,2-8°C |
| solubility | Chloroform (Slightly), DMSO (Slightly, Heated, Sonicaetd), Ethyl Acetate (Slightly) |
| form | Solution |
| Specific Gravity | 0.9 |
| color | White to off-white |
| Water Solubility | Soluble in most organic solvents. Insoluble in water. |
| Sensitive | Air Sensitive |
| Hydrolytic Sensitivity | 8: reacts rapidly with moisture, water, protic solvents |
| BRN | 957171 |
| Stability | Air Sensitive, Moisture Sensitive |
| InChIKey | WLPUWLXVBWGYMZ-UHFFFAOYSA-N |
| CAS DataBase Reference | 2622-14-2(CAS DataBase Reference) |
| NIST Chemistry Reference | Phosphine, tricyclohexyl-(2622-14-2) |
| EPA Substance Registry System | Phosphine, tricyclohexyl- (2622-14-2) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |    GHS02,GHS07,GHS08 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H225-H304-H315-H319-H335-H336-H361d-H373-H412 | |||||||||
| Precautionary statements | P210-P273-P301+P310-P303+P361+P353-P305+P351+P338-P331 | |||||||||
| Hazard Codes | Xi,Xn,F | |||||||||
| Risk Statements | 36/37/38-22-37/38-36-19-11-67-65-63-48/20-40 | |||||||||
| Safety Statements | 26-36/37-62-37/39-36-33-29-16 | |||||||||
| RIDADR | UN 2056 3/PG 2 | |||||||||
| WGK Germany | 3 | |||||||||
| TSCA | Yes | |||||||||
| HazardClass | 3 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 29319090 | |||||||||
| NFPA 704 |
|
Tricyclohexyl phosphine price More Price(20)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | SAB1302957 | ANTI-TCHP (CENTER) antibody produced in rabbit IgG fraction of antiserum, buffered aqueous solution | 2622-14-2 | 400μL | ₹47796.6 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 592285 | Tricyclohexylphosphine solution 1?M in toluene | 2622-14-2 | 100ML | ₹31840.2 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 455164 | Tricyclohexylphosphine solution 20?wt. % in toluene | 2622-14-2 | 100G | ₹10480.4 | 2022-06-14 | Buy |
| Sigma-Aldrich | 261971 | Tricyclohexylphosphine | 2622-14-2 | 1G | ₹2478.93 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 261971 | Tricyclohexylphosphine | 2622-14-2 | 1G | ₹2478.93 | 2022-06-14 | Buy |
Tricyclohexyl phosphine Chemical Properties,Uses,Production
Chemical Properties
clear colorless to pale yellow solution
Uses
- Tricyclohexyl Phosphine is a ligand catalyst used primarily in organometallic chemistry.
- Ligand used in the Pd-catalyzed coupling of malononitrile with aryl halides.
- suzuki reaction: Bulky phosphine ligand used with a Pd(0)-triolefinic macrocycle catalyst for Suzuki coupling of aryl bromides and chlorides.
- This ligand is applied with Ni as a key intermediate in the formation of cylcopentane compounds.
- As a reagent, Tricyclohexylphosphine is used for a range of metal-catalyzed organic transformations.
- Crabtree's catalyst is an organoiridium compound containing tricyclohexyl phosphine used for hydrogenation of mono-, di-, tri-, and tetra- substituted substrates and hydrogen transfer reactions.
- Grubbs' catalysts consists of transition metal ruthenium and tricylohexyl phosphine utilized in olefin metathesis in synthetic organic chemistry.
Purification Methods
It recrystallises from EtOH [Boert et al. J Am Chem Soc 109 7781 1987]. [Beilstein 16 IV 947.]
Tricyclohexyl phosphine Preparation Products And Raw materials
Raw materials
chevron_left
1of3
chevron_rightPreparation Products
chevron_left
1of2
chevron_right
Global( 456)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| DAVY CHEM LABS | +91-9603460845 +91-9493444489 | Hyderabad, India | 109 | 58 | Inquiry |
| JIVICHEM SYNTHESIS PVT LTD | +91-7028392790 +91-7028392790 | Maharashtra, India | 342 | 58 | Inquiry |
| AMINO ORGANICS | +919866989891 | Hyderabad, India | 278 | 58 | Inquiry |
| JSK Chemicals | +919879767970 | Gujarat, India | 3758 | 58 | Inquiry |
| AKASH PHARMA EXPORTS | +91-9388123451 +91-9846039283 | Kerela, India | 470 | 58 | Inquiry |
| Triveni chemicals | 08048762458 | New Delhi, India | 6093 | 58 | Inquiry |
| ALTAIR ALCHEMY Laboratories | 91--9014276848 | Hyderabad, India | 324 | 58 | Inquiry |
| Spectrochem Pvt., Ltd. | 91-22-22016968 | Maharashtra, India | 183 | 58 | Inquiry |
| HiMedia Laboratories | 91-22-61471919 | Maharashtra, India | 1843 | 58 | Inquiry |
| VASIN BIO LIFE SCIENCES PVT LTD | 9491644688 | Hyderabad, India | 2096 | 58 | Inquiry |
| Supplier | Advantage |
|---|---|
| DAVY CHEM LABS | 58 |
| JIVICHEM SYNTHESIS PVT LTD | 58 |
| AMINO ORGANICS | 58 |
| JSK Chemicals | 58 |
| AKASH PHARMA EXPORTS | 58 |
| Triveni chemicals | 58 |
| ALTAIR ALCHEMY Laboratories | 58 |
| Spectrochem Pvt., Ltd. | 58 |
| HiMedia Laboratories | 58 |
| VASIN BIO LIFE SCIENCES PVT LTD | 58 |
Related articles
- Synthesis method of tricyclohexyl phosphine
- Tricyclohexyl phosphine is the tertiary phosphine.
- Aug 18，2022
2622-14-2(Tricyclohexyl phosphine)Related Search:
DICYCLOHEXYLPHOSPHINE
TRICYCLOHEXYLPHOSPHINE OXIDE
TRICYCLOHEXYLPHOSPHONIUM TETRAFLUOROBORATE
TRICYCLOPENTYLPHOSPHINE
TRIHEXYLPHOSPHINE
O-(2,2,2-Trifluoroethyl)hydroxylamine hydrochloride
Trimethylsilyl 2-(fluorosulfonyl)difluoroacetate
BIS(TRICYCLOHEXYLPHOSPHINE)[(PHENYLTHIO)METHYLENE]RUTHENIUM (IV) DICHLORIDE
Benzylidene-bis(tricyclohexylphosphine)dichlororuthenium
(3-Phenyl-1H-inden-1-ylidene)bis(tricyclohexylphosphine)rutheniuM(IV) Dichloride
chevron_left
1of4
chevron_right
PHOSPHORUS TRICYCLOHEXYL
TRICYCLOHEXYL-PHOSPHANE
NSC 158657
ANTI-TCHP (CENTER) antibody produced in rabbit
Protein TCHP
Trichoplein keratin filament-binding protein
Tumor suppressor protein
Tricyclohexylphosphine, min. 98%
TRICYCLOHEXYLPHOSPHINE: (20% IN TOLUENE)
Tricyclohexylphosphine, technical grade
Tricyclohexylphosphine (contains Tricyclohexylphosphine Oxide) (ca. 18% in Toluene, ca. 0.60mol/L)
TRICYCLOHEXYLPHOSPHINE, DISSOLVED IN TOLUENE (20% CONCENTRATION)
TRICYCLOHEXYL PHOSPHINE (TCHP)
Tricyclohexylphosphine (20% in toluene), min. 88%
Tris(cyclohexyl)phosphine
Triscyclohexylphosphine
Tricyclohexylphosphine (ca. 18% in Toluene, ca. 0.60mol/L)(contains Tricyclohexylphosphine Oxide)
Tricyclohexylphosphine,1M solution in THF
Tricyclohexylphosphine,1M solution in toluene
tricyclohexyl-phosphin
TRICYCLOHEXYLPHOSPHINE, 20 WT. % SOLUTI&
TRICYCLOHEXYLPHOSPHINE, 1M IN TOLUENE
TRICYCLOHEXYLPHOSPHINE, 1M IN TETRAHYDR&
Tricyclohexylphosphine, 20% Toluene Solution
Tricyclohexylphosphine,97%
Tricyclohexylphosphine(20%intoluene),min.88%
tricyclohexylphosphine solution
tricyclohexylphospine
Tricyclohexylphosphine,Cy3P
Tricyclohexyl Phosphine (90%)
Tricyclohexylphosphine solution 20 wt. % in toluene
Tricyclohexyphosphine
Tricyclohexylphosphine, 1.0 M solution in THF, SpcSeal
Tricyclohexylphosphine,97% Cy3P
Tricyclohexylphosphine,96%
Tricyclohexyl phosph
Tricyclohexylphosphine, 1M solution in toluene, AcroSeal
Tricyclohexylphosphine, 1M solution in THF, AcroSeal
Tricyclohexylphosphene
Tricyclohexylphosphine, 97% 5GR
Tricyclohexylphosphine, 97% 1mol toluene
TRICYCLOHEXYLPHOSPHINE, 20-22% in toluene
Tricyclohexylphosphine, 97% 1mol THF
Tricyclohexylphosphine (Cy3P) extrapure, 97%
Tricyclohexylphosphine, 1M solution in toluene, AcroSeal&trade
TCHP
TRICYCLOHEXYLPHOSPHINE
PCY3
TricycL
Cy3P
Phosphine, tricyclohexyl-
2-Propenoicacid,2-methyl-,2-(6-hydroxyethoxy)ethylester
ricyclohexylphosphane
Tricyclohexylphosphine(TCP)
Tricyclohexylphosphine,95%
2622-14-2
3622-14-2
622-14-2