1,3-ジクロロ-5,5-ジメチルヒダントイン 化学特性,用途語,生産方法
外観
白色～微褐色、結晶性粉末～粉末
用途
酸化剤。
用途
ポリ塩化ビニルの安定剤、アミノ酸、医薬、農薬の中間体
化学的特性
DCDMH is a combustible, white powder.
Chlorine-like odor.
物理的性質
White powder or four-sided crystals from chloroform with a chlorine-like odor. Aqueous solutions
are acidic.
使用
Dantoin(R) DCDMH is an industrial bleaching agent based on dimethyl hydantoin. This product finds application wherever solid bleach is desired.
定義
Methionine hydroxy analog c. 90%.
一般的な説明
White powder with a weak chlorine odor. Conflagrates at 414°F (turns brown). Chlorine gas evolves > 410°F.
空気と水の反応
Sensitive to exposure to light, air, and moisture. Reacts with water or steam to produce toxic and corrosive fumes.
反応プロフィール
1,3-Dichloro-5,5-dimethylhydantoin reacts violently with xylene. 1,3-Dichloro-5,5-dimethylhydantoin is incompatible with strong acids, easily oxidized materials, ammonia salts and sulfides. 1,3-Dichloro-5,5-dimethylhydantoin will react with water or steam to produce toxic and corrosive fumes. At a pH of 9, 1,3-Dichloro-5,5-dimethylhydantoin decomposes completely.
健康ハザード
1,3-Dichloro-5,5-dimethylhydantoin
powder in contact with water yields
hypochlorous acid, which is an irritant of the
eyes and mucous membranes.
火災危険
Flash point data for 1,3-Dichloro-5,5-dimethylhydantoin are not available. 1,3-Dichloro-5,5-dimethylhydantoin is probably combustible.
安全性プロファイル
Moderately toxic by
ingestion. Mildly toxic by inhalation. A
severe slun irritant. Mutation data reported.
Avoid excessive contact because of effects
of active chlorine on skin. Some of the
hydantoins are central nervous system
depressants. Mixtures with xylene may
explode. Wdl react with water or steam to
produce toxic and corrosive fumes. When
heated to decomposition it emits toxic
fumes of Cl and NOx. See also
CHLORIDES.
職業ばく露
It is used as a chlorinating agent,
disinfectant, biocide, and laundry bleach. It is also used as
a polymerization catalyst in making vinyl chloride; and
in drug and pesticide synthesis.
環境運命予測
Chemical/Physical. Reacts with water (pH 7.0) releasing hypochlorous acid. At pH 9, nitrogen
chloride is formed (Windholz et al., 1983).
輸送方法
UN1479 Oxidizing solid, n.o.s., Hazard Class:
5.1; Labels: 5.1-Oxidizer, Technical Name Required
純化方法
Purify it by dissolving in conc H2SO4 and diluting with ice H2O, collect the solid, dry it in a vacuum and recrystallise it from CHCl3. It sublimes at 100o in a vacuum. It exhibits time-dependent hydrolysis at pH 9. [Petterson & Grzeskowiak J Org Chem 24 1414 1959, Beilstein 24 III/IV 1100.]
不和合性
A strong oxidizer. Contact with water
forms poisonous and corrosive gases. Mixtures with xylene
may explode. Not compatible with moisture (especially hot
water, steam), strong acids; easily oxidized materials (such
as ammonia salts; sulfides, etc.); reducing agents; strong
bases; ammonium salts; sulfides. Compounds of the
carboxyl group react with all bases, both inorganic and
organic (i.e., amines) releasing substantial heat, water and
a salt that may be harmful. Incompatible with arsenic compounds (releases hydrogen cyanide gas), diazo compounds,
dithiocarbamates, isocyanates, mercaptans, nitrides, and
sulfides (releasing heat, toxic and possibly flammable
gases), thiosulfates and dithionites (releasing hydrogen
sulfate and oxides of sulfur)
廃棄物の処理
Incineration (815.5C/816C,
0.5 second for primary combustion; 104.4C/220F, 1.0 second for secondary combustion). The formation of elemental
chlorine can be prevented by injection of steam or methane
into the combustion process. Any nitrogen oxides may be
abated by the use of thermal or catalytic devices
1,3-ジクロロ-5,5-ジメチルヒダントイン 上流と下流の製品情報
原材料
準備製品