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바륨 티타네이트(IV)

바륨 티타네이트(IV)
바륨 티타네이트(IV) 구조식 이미지
카스 번호:
12047-27-7
한글명:
바륨 티타네이트(IV)
동의어(한글):
바륨티타네이트(IV);산화바륨티탄;산화바륨티탄;티탄산바륨 (IV);테트라타이타늄산 바륨;메타타이타늄산 바륨;메타타이타늄산 바륨 (BaTiO3);바륨 타이타네이트 (BaTiO3);산화 바륨 타이타늄;산화 타이타늄 바륨 (TiBaO3);삼산화 바륨 타이타늄;타이타늄산(IV) 바륨 (BaTiO3);타이타늄산 (TiO32-) 바륨 (1:1);타이타늄산 바륨
상품명:
Barium titanate
동의어(영문):
vk4;hbt3;bt303;bt204;bt201;hpbt1;yv100an;kyorixbt-s;vk4(oxide);BARIUM TITANATE
CBNumber:
CB0265773
분자식:
BaO3Ti
포뮬러 무게:
233.19
MOL 파일:
12047-27-7.mol

바륨 티타네이트(IV) 속성

녹는점
1625 °C
밀도
6.08 g/mL at 25 °C(lit.)
저장 조건
Storage temperature: no restrictions.
용해도
Soluble in alcohols
물리적 상태
powder
색상
White to gray
Specific Gravity
6.08
수소이온지수(pH)
9.6 (20g/l, H2O, 25℃)(slurry)
수용성
INSOLUBLE
Merck
14,1000
InChIKey
WNKMTAQXMLAYHX-UHFFFAOYSA-N
CAS 데이터베이스
12047-27-7(CAS DataBase Reference)
EPA
Barium titanium oxide (BaTiO3) (12047-27-7)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 Xn
위험 카페고리 넘버 20/22
안전지침서 28-28A
유엔번호(UN No.) UN 1564 6.1/PG 3
WGK 독일 1
RTECS 번호 XR1437333
TSCA Yes
위험 등급 3
포장분류 III
HS 번호 28419085
그림문자(GHS):
신호 어: Warning
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H226 인화성 액체 및 증기 인화성 액체 구분 3 경고
H302 삼키면 유해함 급성 독성 물질 - 경구 구분 4 경고 P264, P270, P301+P312, P330, P501
H332 흡입하면 유해함 급성 독성 물질 흡입 구분 4 경고 P261, P271, P304+P340, P312
예방조치문구:
P210 열·스파크·화염·고열로부터 멀리하시오 - 금연 하시오.
P261 분진·흄·가스·미스트·증기·...·스프레이의 흡입을 피하시오.
P264 취급 후에는 손을 철저히 씻으시오.
P264 취급 후에는 손을 철저히 씻으시오.
P270 이 제품을 사용할 때에는 먹거나, 마시거나 흡연하지 마시오.
P303+P361+P353 피부(또는 머리카락)에 묻으면 오염된 모든 의복은 벗거나 제거하시오 피부를 물로 씻으시오/샤워하시오.
P304+P340 흡입하면 신선한 공기가 있는 곳으로 옮기고 호흡하기 쉬운 자세로 안정을 취하시오.

바륨 티타네이트(IV) C화학적 특성, 용도, 생산

개요

Attributing to its ferroelectricity, barium titanate is applied as a semiconductor with positive temperature coefficient of resistivity. It is one of the most important electroceramic materials among all the ferroelectric materials. Barium titanate has also dielectric properties, which can be used in the manufacture of ceramic capacitors. Furthermore, barium titanate has piezoelectric property and can be used in electrical devices such as actuators, accelerators, ultrasonic generators, piezoelectric transducers, filters, and sensors.

화학적 성질

White crystalline solid; exists in five crystal modifications; the common tetragonal form has a Curie point of 120°C; exhibits ferroelectric and piezoelectric properties; density 6.02 g/cm3; melts at 1,625°C; insoluble in water and alkalies; slightly soluble in dilute mineral acids; dissolves in concentrated sulfuric acid and hydrofluoric acid.

물리적 성질

White crystalline solid; exists in five crystal modifications; the common 94 BARIUM TITANATE tetragonal form has a Curie point of 120°C; exhibits ferroelectric and piezoelectric properties; density 6.02 g/cm3; melts at 1,625°C; insoluble in water and alkalies; slightly soluble in dilute mineral acids; dissolves in concentrated sulfuric acid and hydrofluoric acid.

용도

Barium titanate has many important commercial applications. It has both ferroelectric and piezoelectric properties. Also, it has a very high dielectric constant (about 1,000 times that of water). The compound has five crystalline modifications, each of which is stable over a particular temperature range. Ceramic bodies of barium titanate find wide applications in dielectric amplifiers, magnetic amplifiers, and capacitors. These storage devices are used in digital calculators, radio and television sets, ultrasonic apparatus, crystal microphone and telephone, sonar equipment, and many other electronic devices.

용도

In electronic devices, e.g., as voltage-sensitive dielectric in so-called dielectric amplifiers, in computer elements, magnetic amplifiers, memory devices.

용도

Barium titanate (BaTiO3, BT) is one of the widely used materials in electronic ceramics. Because of its very high permittivity, it could be used in capacitors with outstanding properties by doping. Because barium titanate is used in large quantities as a material in electronic devices, considerable energy savings could be achieved if barium titanate could be sintered at a reduced temperature. It is reported that for LTCC (Low Temperature Cc-fired Ceramics) application, barium titanate is sintering at 1000℃ for 24 hours with the incorporation of silicate glass system. In addition, there is a report saying that a sintered body of relative density around 90% was achieved by 900℃ for 8 hours by adding boron oxide or lead borate to a barium titanate.

제조 방법

Barium titanate is made by sintering a finely powdered mixture of barium carbonate and titanium dioxide in a furnace at 1,350°C. The calcined mass is finely ground and mixed with a binder (plastic). The mixture is subjected to extrusion, pressing or film casting to obtain ceramic bodies of desired shapes. Plastic is burnt off by heating and the shaped body is sintered by firing and then polished.
Barium titanate also may be prepared by other methods. These include ignition of barium and titanium alcoholates in an organic solvent; treatment of tetraethyl titanate or other alkyl ester of titanium with an aqueous solution of barium hydroxide; and ignition of barium titanyloxalate.

참고 문헌

[1] Burcu Ertu?, The Overview of The Electrical Properties of Barium Titanate, American Journal of Engineering Research, 2013, vol. 02, 01-07
[2] G. Arlt, D. Hennings and G. de With, Dielectric properties of fine‐grained barium titanate ceramics, Journal of Applied Physics, 1985, vol. 58, 1619
[3] Tomoaki Karaki, Kang Yan and Masatoshi Adachi, Barium Titanate Piezoelectric Ceramics Manufactured by Two-Step Sintering, Japanese Journal of Applied Physics, 2007, vol. 46, 7035-7038

바륨 티타네이트(IV) 준비 용품 및 원자재

원자재

준비 용품


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