cis-4-Hydroxycyclohexanecarboxylic acid
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cis-4-Hydroxycyclohexanecarboxylic acid 속성
- 녹는점
- 150°C
- 끓는 점
- 115 °C(Press: 8 Torr)
- 밀도
- 1.246
- 저장 조건
- 2-8°C
- 용해도
- almost transparency in Methanol
- 물리적 상태
- powder to crystal
- 산도 계수 (pKa)
- pK1:4.836 (25°C)
- 색상
- 흰색에서 거의 흰색
- InChI
- InChI=1S/C7H12O3/c8-6-3-1-5(2-4-6)7(9)10/h5-6,8H,1-4H2,(H,9,10)/t5-,6+
- InChIKey
- HCFRWBBJISAZNK-OLQVQODUSA-N
- SMILES
- [C@@H]1(C(O)=O)CC[C@H](O)CC1
- CAS 데이터베이스
- 3685-22-1
안전
- 위험 및 안전 성명
- 위험 및 사전주의 사항 (GHS)
| 위험품 표기 | T | ||
|---|---|---|---|
| 위험 카페고리 넘버 | 36/37/38-25 | ||
| 안전지침서 | 26-36/37/39-45 | ||
| 유엔번호(UN No.) | UN 2811 6.1 / PGIII | ||
| HS 번호 | 2918199890 |
cis-4-Hydroxycyclohexanecarboxylic acid C화학적 특성, 용도, 생산
화학적 성질
White to Almost white powder to crystal. Melting point: 148.0 to 152.0 °C.Synthesis
cis-4-Hydroxycyclohexanecarboxylic acid can be synthesized through the following steps:1. In an argon glove box, dissolve ligands L1-(S,R)-f-ambinol (7.5mg, 0.0105mmol) and [Ir(COD)Cl]2 (3.4mg, 0.005mmol) in 1 mL of iPrOH in a 2mL vial and stir at room temperature for 2 h.
2. Put 1 mmol of raw material 4-substituted cyclohexanone into a 4 mL hydrogenation flask.
3. Add 0.1 mL of the in-situ complexed catalyst solution and 1.6 mg of tBuOLi solid powder to the hydrogenation flask.
4. Add 1 mL of EtOH to dissolve the reactants in the hydrogenation flask.
5. Put the reaction flask into the hydrogenation kettle and replace the kettle body with hydrogen three times.
6. Fill the kettle with 5bar H2 and react at room temperature for 12h.
7. After the reaction is completed, carefully release the hydrogen and spin-dry the solvent under reduced pressure.
8. Purify the hydrogenated product cis-4-substituted cyclohexanol by silica gel column.
9. Obtain the final product cis-4-Hydroxycyclohexanecarboxylic acid.
cis-4-Hydroxycyclohexanecarboxylic acid 준비 용품 및 원자재
원자재
준비 용품
cis-4-Hydroxycyclohexanecarboxylic acid 공급 업체
글로벌( 111)공급 업체
| 공급자 | 전화 | 이메일 | 국가 | 제품 수 | 이점 |
|---|---|---|---|---|---|
| Frapp's ChemicalNFTZ Co., Ltd. | +86 (576) 8169-6106 |
sales@frappschem.com | China | 885 | 50 |
| Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 |
sales@capotchem.com | China | 29797 | 60 |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 |
info@dakenam.com | China | 15928 | 58 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 |
ivan@atkchemical.com | China | 32480 | 60 |
| Jinan Carbotang Biotech Co.,Ltd. | +8615866703830 |
figo.gao@foxmail.com | China | 6992 | 58 |
| Accela ChemBio Inc. | (+1)-858-699-3322 |
info@accelachem.com | United States | 19965 | 58 |
| Chongqing Chemdad Co., Ltd | +86-023-61398051 +8613650506873 |
sales@chemdad.com | China | 39916 | 58 |
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 |
sales@conier.com | China | 49390 | 58 |
| career henan chemical co | +86-0371-86658258 15093356674; |
factory@coreychem.com | China | 29826 | 58 |
| Antai Fine Chemical Technology Co.,Limited | 18503026267 |
info@antaichem.com | CHINA | 9641 | 58 |
cis-4-Hydroxycyclohexanecarboxylic acid 관련 검색:
CIS-4-CYCLOHEXENE-1,2-DICARBOXYLIC ACID
H-CIS-HYP-OME HCL
cis-4-Hydroxy-D-proline
cis-4-Hydroxy-L-proline
Cyclohexanecarboxylic acid, 4-hydroxy-, Methyl ester, cis-
CIS-3-AMINOCYCLOHEXANECARBOXYLICACID
Bicyclo[1.1.1]pentane-1,3-dicarboxylic acid, MonoMethyl ester
Tetrahydro-5-oxo-2- furancarboxyli
4-Hydroxycyclohexanecarboxylic acid
ETHYL 4-HYDROXYCYCLOHEXANECARBOXYLATE
1-AMINO-4-OXOCYCLOHEXANECARBOXYLIC ACID ETHYLENE KETAL
METHYL 4-HYDROXYCYCLOHEXANECARBOXYLATE
4-METHOXYCYCLOHEXANECARBOXYLIC ACID
cis-4-Hydroxycyclohexanecarboxylic acid
PICROTIN
ethyl 1,4-dioxaspiro[4.5]decane-8-carboxylate
TRANS-4-HYDROXYCYCLOHEXANECARBOXYLIC ACID
8-(9H-FLUOREN-9-YLMETHOXYCARBONYLAMINO)-1,4-DIOXA-SPIRO[4.5]DECANE-8-CARBOXYLIC ACID