사이클로테트라메틸렌테트라니트라민

사이클로테트라메틸렌테트라니트라민
사이클로테트라메틸렌테트라니트라민 구조식 이미지
카스 번호:
2691-41-0
한글명:
사이클로테트라메틸렌테트라니트라민
동의어(한글):
사이클로테트라메틸렌테트라나니트라민;사이클로테트라메틸렌테트라니트라민;사이클로테트라메틸렌테트라니트라민(CYCLOTETRAMETHYLENETETRANITRAMINE)
상품명:
HMX
동의어(영문):
hw4;HMX;HW 4;lx14-0;OCTOGEN;LX 14-0;Oktogen;beta-hmy;beta-HMX;beta Hmy
CBNumber:
CB1453029
분자식:
C4H8N8O8
포뮬러 무게:
296.16
MOL 파일:
2691-41-0.mol
MSDS 파일:
SDS

사이클로테트라메틸렌테트라니트라민 속성

녹는점
281°
끓는 점
437.77°C (rough estimate)
밀도
Density (g/cm3): b=1.903; a=1.87; g=1.82; d=1.78
증기압
0Pa at 25℃
굴절률
1.6910 (estimate)
인화점
2℃
저장 조건
2-8°C
산도 계수 (pKa)
-16.32±0.20(Predicted)
물리적 상태
무색 고체
수용성
4.46mg/L at 25℃
LogP
0.165 at 21℃
CAS 데이터베이스
2691-41-0
EPA
Cyclotetramethylenetetranitramine (2691-41-0)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 F,T,Xn,E
위험 카페고리 넘버 11-23/24/25-36/37/38-36-20/21/22-3
안전지침서 16-27-45-36/37-35-26
유엔번호(UN No.) 0226
WGK 독일 2
위험 등급 1.1D
HS 번호 29339900
유해 물질 데이터 2691-41-0(Hazardous Substances Data)
독성 LD50 oral in rabbit: 50mg/kg
그림문자(GHS): GHS hazard pictogramsGHS hazard pictograms
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H225 고인화성 액체 및 증기 인화성 액체 구분 2 위험 GHS hazard pictograms P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H319 눈에 심한 자극을 일으킴 심한 눈 손상 또는 자극성 물질 구분 2A 경고 GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
예방조치문구:
P210 열·스파크·화염·고열로부터 멀리하시오 - 금연 하시오.
P261 분진·흄·가스·미스트·증기·...·스프레이의 흡입을 피하시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
P337+P313 눈에 대한 자극이 지속되면 의학적인 조치· 조언를 구하시오.
P403+P235 환기가 잘 되는 곳에 보관하고 저온으로 유지하시오.

사이클로테트라메틸렌테트라니트라민 C화학적 특성, 용도, 생산

화학적 성질

HMX (high-melting explosive) is a completely N-nitrated, eight-membered heterocyclic ring compound analogous to RDX. HMX has a molecular weight of 296.16 and a melting point of 204°C. Virtually none of the toxicity information on HMX was published, but it was reviewed by the EPA.

용도

HMX has uses similar to RDX, that is, as a base charge for detonators and as an ingredient of bursting-charge and plastic explosives by the military.

정의

ChEBI: A tetrazocane that is 1,3,5,7-tetrazocane in which the hydrogen atom attached to each of the nitrogens is replaced by a nitro group.

일반 설명

A white crystalline solid. Melting point 281°C. Practically insoluble in water. Water slurry mitigates explosion hazard. Used in solid propellants and explosives. The primary hazard is the blast effect and not flying projectiles and fragments.

공기와 물의 반응

Insoluble in water.

반응 프로필

HMX is a high explosive. May begin a vigorous reaction that culminates in a detonation if mixed with reducing agents, including hydrides, sulfides and nitrides. May explode in the presence of a base such as sodium hydroxide or potassium hydroxide even in the presence of water. Presence of metal oxides increases thermal sensitivity. Wetting reduces sensitivity toward detonation.

건강위험

Fire may produce irritating, corrosive and/or toxic gases.

화재위험

MAY EXPLODE AND THROW FRAGMENTS 1600 meters (1 MILE) OR MORE IF FIRE REACHES CARGO.

Safety Profile

A poison by ingestion and intravenous routes. An explosive. Decomposes violently at 279OC. When heated to decomposition it emits toxicfumes of NOx. See also EXPLOSIVES, HIGH.

잠재적 노출

A potential danger to those involved in the manufacture of this material and its handling in munitions and solid-propellant manufacture. It is also used as a rat poison; a powerful military explosive; a base charge for detonators; and in plastic explosives.

운송 방법

UN0483 Cyclotrimethylenetrinitramine, desensi- tized or Cyclonite, desensitized or Hexogen, desensitized or RDX, desensitized, Hazard Class: 1D; Labels: 1D- Explosive (with a mass explosion hazard); D-Substances or articles which may mass detonate (with blast and/or frag- ment hazard) when exposed to fire. UN0072 Cyclotrimethylenetrinitramine, wetted or Cyclonite, wetted or Hexogen, wetted or RDX, wetted with not ,15% water by mass, Hazard Class: 1D; Labels: 1D-Explosive (with a mass explosion hazard); D-Substances or articles which may mass detonate (with blast and/or fragment hazard) when exposed to fire.

비 호환성

Heat, physical damage, shock, and deto- nators. Detonates on contact with mercury fulminate. Keep away from other explosives, combustibles, oxidizers (such as chlorates, nitrates, perchlorates, permanganates, perox- ides; bromine, chlorine, and fluorine); reducing agents; and aqueous alkaline solutions.

폐기물 처리

Pour over soda ash, neutralize and flush to sewer with water. Also HMX may be recov- ered from solid propellant waste.

사이클로테트라메틸렌테트라니트라민 준비 용품 및 원자재

원자재

준비 용품


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