3-PHENYLPROPIONITRILE

3-PHENYLPROPIONITRILE 구조식 이미지
카스 번호:
645-59-0
상품명:
3-PHENYLPROPIONITRILE
동의어(영문):
NSC 16936;phenethylcyanide;Phenethyl cyanide;Benzylacetonitrile;Phenylpropionitrile;HYDROCINNAMONITRILE;Benzenepropionitrile;2-Phenylethylcyanide;benzenepropanenitrile;(2-Cyanoethyl)benzene
CBNumber:
CB1733015
분자식:
C9H9N
포뮬러 무게:
131.17
MOL 파일:
645-59-0.mol
MSDS 파일:
SDS

3-PHENYLPROPIONITRILE 속성

녹는점
−2-−1 °C(lit.)
끓는 점
113 °C9 mm Hg(lit.)
밀도
1.001 g/mL at 25 °C(lit.)
굴절률
n20/D 1.521(lit.)
인화점
>230 °F
저장 조건
Sealed in dry,Room Temperature
용해도
1.68g/l(계산)
물리적 상태
액체
Specific Gravity
1
색상
무색투명~연황색
냄새
강력한 한련
BRN
636348
노출 한도
NIOSH: IDLH 25 mg/m3
CAS 데이터베이스
645-59-0(CAS DataBase Reference)
EPA
Benzenepropanenitrile (645-59-0)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 T,C
위험 카페고리 넘버 23/24/25-36-34
안전지침서 36/37/39-45-27-26
유엔번호(UN No.) UN 3276 6.1/PG 3
WGK 독일 3
RTECS 번호 MW5604750
TSCA Yes
위험 등급 6.1
포장분류 II
HS 번호 29269095
그림문자(GHS): GHS hazard pictograms
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H301 삼키면 유독함 급성 독성 물질 - 경구 구분 3 위험 GHS hazard pictograms P264, P270, P301+P310, P321, P330,P405, P501
예방조치문구:
P264 취급 후에는 손을 철저히 씻으시오.
P264 취급 후에는 손을 철저히 씻으시오.
P270 이 제품을 사용할 때에는 먹거나, 마시거나 흡연하지 마시오.
P301+P310 삼켰다면 즉시 의료기관(의사)의 진찰을 받으시오.
P405 밀봉하여 저장하시오.
P501 ...에 내용물 / 용기를 폐기 하시오.
NFPA 704
1
3 0

3-PHENYLPROPIONITRILE C화학적 특성, 용도, 생산

화학적 성질

clear colorless to light yellow liquid

용도

3-Phenylpropionitrile was used to study the free enzyme activity of nitrilase AtNIT1.

제조 방법

To a stirred solution of 3-phenylpropanamide (50 mg, 0.34 mmol) in acetonitrile (0.8 mL) at room temperature were successively added formic acid (0.2 mL) and paraformaldehyde (50 mg, 1.67 mmol). The reaction mixture was then refluxed for 12 h, and the solution obtained was cooled to room temperature.
Work-up A: The crude mixture was concentrated under reduced pressure, and the residue was subjected to flash chromatography on silica gel (230–240 mesh) eluting with hexane/ethyl acetate (7:3) to yield 3-phenylpropanonitrile (37 mg, 85%).
Work-up B: The reaction mixture was diluted with ethyl acetate (10 mL) and washed successively with saturated sodium hydrogen carbonate solution (5 mL) and water (5 mL). The combined aqueous layers were extracted with ethyl acetate (2 × 10 mL). The combined organic layers were dried over Na2SO4, filtered, and concentrated. The crude 3-phenylpropanonitrile was purified as described above (Work-up A).

정의

ChEBI: A nitrile that is propionitrile in which one of the methyl hydrogens has been replaced by a phenyl group.

일반 설명

The effect of 3-Phenylpropionitrile on the growth and survival of woodlouse Porcellio scaber has been studied.

3-PHENYLPROPIONITRILE 준비 용품 및 원자재

원자재

준비 용품


3-PHENYLPROPIONITRILE 공급 업체

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