Phosphorus trioxide

Phosphorus trioxide 구조식 이미지
카스 번호:
1314-24-5
상품명:
Phosphorus trioxide
동의어(영문):
Phosphorus trioxide;phosphorous anhydride;Diphosphorus trioxide;Phosphorus trioxide ISO 9001:2015 REACH
CBNumber:
CB2852146
분자식:
H4O5P2
포뮬러 무게:
145.976282
MOL 파일:
1314-24-5.mol

Phosphorus trioxide 속성

녹는점
23.8°
끓는 점
bp 173.1° in nitrogen atm
밀도
d421 2.135
용해도
reacts with H2O
물리적 상태
무색의 단사정계 결정 또는 액체
색상
colorless monoclinic crystals, crystalline or liquid
수용성
차가운 H2O에서 천천히 H3PO3를 형성합니다. 뜨거운 H2O에서 격렬하게 반응하여 빨간색 P, PH3 및 H3PO4를 형성합니다. [MER06]
EPA
Phosphorus trioxide (1314-24-5)

안전

유엔번호(UN No.) 2578
위험 등급 8
포장분류 III

Phosphorus trioxide C화학적 특성, 용도, 생산

화학적 성질

transparent crystal(s); monoclinic or colorless liquid; disproportionates to red P and P2O4if heated above 210°C [MER06]

일반 설명

White crystalline solid or a liquid (melting point 24°C). Density 2.14 g / cm3. Toxic and corrosive. May severely irritate skin and eyes. Used to make other chemicals.

공기와 물의 반응

Fumes in air. Reacts slowly with cold water to give phosphorous acid. Reacts vigorously with hot water to generate red phosphorus, phosphine (highly toxic and flammable) and phosphoric acid [Merck 11th ed. 1989].

반응 프로필

Phosphorus trioxide reacts exothermically with bases. Melted Phosphorus trioxide readily ignites in air. Instantly ignites with a flame of almost blinding brilliance when thrown into oxygen at 50-60°C [J. Am. Chem. Soc. 125:347. 1924]. Incompatible with ammonia, disulfur dichloride, halogens, oxygen, phosphorus pentachloride, sulfur, sulfuric acid, water [Bretherick, 5th ed., 1995, p. 1778].

건강위험

TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death. Reaction with water or moist air will release toxic, corrosive or flammable gases. Reaction with water may generate much heat that will increase the concentration of fumes in the air. Fire will produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.

화재위험

Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Vapors may accumulate in confined areas (basement, tanks, hopper/tank cars etc.). Substance will react with water (some violently), releasing corrosive and/or toxic gases and runoff. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated or if contaminated with water.

Phosphorus trioxide 준비 용품 및 원자재

원자재

준비 용품


Phosphorus trioxide 공급 업체

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