Phenyl trifluoromethanesulfonate
|
|
Phenyl trifluoromethanesulfonate 속성
- 끓는 점
- 99-100 °C/60 mmHg (lit.)
- 밀도
- 1.396 g/mL at 25 °C (lit.)
- 굴절률
- n
20/D 1.435(lit.)
- 인화점
- 160 °F
- 저장 조건
- Inert atmosphere,Room Temperature
- 물리적 상태
- 투명한 액체
- 색상
- 무색 내지 거의 무색
안전
- 위험 및 안전 성명
- 위험 및 사전주의 사항 (GHS)
위험품 표기 | T | ||
---|---|---|---|
위험 카페고리 넘버 | 36/37/38-34-24/25 | ||
안전지침서 | 26-36-45-36/37/39 | ||
유엔번호(UN No.) | UN 2927 6.1/PG 2 | ||
WGK 독일 | 3 | ||
HS 번호 | 29049090 |
Phenyl trifluoromethanesulfonate C화학적 특성, 용도, 생산
화학적 성질
Colorless Liquid.용도
Phenyl trifluoromethanesulfonate (phenyl triflate) may be used in the following studies:As an arylating agent for the asymmetric α-arylation of ketones catalyzed by Pd(dba)2 and difluorphos.
As a reactant in the one pot synthesis of carbazoles by palladium-catalyzed N-arylation of anilines with phenyl triflate followed by oxidative coupling.
Synthesis of N-(2,6-diarylbenzoyl)anilines by diarylation of benzanilides with phenyl triflate in the presence of palladium-based catalyst.
As an arylating agent in the synthesis of (R)-2-phenyl-2,3-dihydrofuran by the arylation of 2,3-dihydrofuran.
제조 방법
Synthesis of Phenyl trifluoromethanesulfonate: The reaction of phenol (1.00 g, 10.6 mmol) with triflic anhydride as outlined in the general procedure provided phenyl trifluoromethanesulfonate as colorless oil (0.73 g, 30%).1H NMR (400 MHz, CDCl3) δ 7.50 – 7.42 (m, 2H), 7.41 – 7.36 (m, 1H), 7.32 – 7.24 (m, 2H).
일반 설명
Phenyl trifluoromethanesulfonate (phenyl triflate) is an aryl fluorosulphonate. It has been synthesized by the reaction of phenol with fluorosulphonic anhydride.Phenyl trifluoromethanesulfonate 준비 용품 및 원자재
원자재
준비 용품
Phenyl trifluoromethanesulfonate 공급 업체
글로벌( 94)공급 업체
공급자 | 전화 | 이메일 | 국가 | 제품 수 | 이점 |
---|---|---|---|---|---|
Changzhou Ansciep Chemical Co., Ltd. | +86 519 86305871 |
sales@ansciepchem.com | CHINA | 4242 | 58 |
career henan chemical co | +86-0371-86658258 +8613203830695 |
factory@coreychem.com | China | 29822 | 58 |
Zhengzhou Alfa Chemical Co.,Ltd | +8618530059196 |
sale04@alfachem.cn | China | 13363 | 58 |
Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418671 +8618949823763 |
sales@tnjchem.com | China | 34571 | 58 |
Dayang Chem (Hangzhou) Co.,Ltd. | 571-88938639 +8617705817739 |
info@dycnchem.com | China | 52861 | 58 |
Aromsyn Co., Ltd. | +86-0571-85585865 +8613336024896 |
CB@aromsyn.com | China | 19185 | 58 |
Hebei Guanlang Biotechnology Co., Ltd. | +8619930503259 |
cherry@crovellbio.com | China | 18419 | 58 |
PT CHEM GROUP LIMITED | |
peter68@ptchemgroup.com | China | 35426 | 58 |
GIHI CHEMICALS CO.,LIMITED | +8618058761490 |
info@gihichemicals.com | China | 50003 | 58 |
Aceschem Inc. | +1-817863-6948 +1-(817)863-6948 |
sales@aceschem.com | United States | 19639 | 58 |
Phenyl trifluoromethanesulfonate 관련 검색:
8-퀴노리닐 트리플루오로메탄설포네이트
4-BROMOPHENYL TRIFLUOROMETHANESULFONATE
Trimethylsilyl trifluoromethanesulfonate
TRIFLUOROMETHYL SULFINYL CHLORIDE
SILVER TRIFLUOROMETHANESULFONATE
Trifluoromethanesulfonyl chloride
Ethyl trifluoromethanesulfonate
Trifluoromethanesulfonic anhydride
Sodium trifluoromethanesulfonate
Trifluoromethanesulfonic acid
Lithium trifluoromethanesulfonate
Methyl trifluoromethanesulfonate
4-METHYL-2-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFONATE,98.0+%(GC),4-METHYL-2-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFONATE
P-TOLYL TRIFLATE
1-NAPHTHYL TRIFLATE
4-NITROPHENYL TRIFLUOROMETHANESULFONATE
2-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFONATE
METHYL 2-TRIFLUOROMETHANESULFONYLOXY-1-NAPHTHOATE