Poly-TPD , Poly[N,N'-bis(4-butylphenyl)-N,N'-bis(phenyl)-benzi

Poly-TPD , Poly[N,N'-bis(4-butylphenyl)-N,N'-bis(phenyl)-benzi 구조식 이미지
카스 번호:
472960-35-3
상품명:
Poly-TPD , Poly[N,N'-bis(4-butylphenyl)-N,N'-bis(phenyl)-benzi
동의어(영문):
POLY-TPD;4-Butyl-N,N-diphenylaniline;Poly(4-butylphenyl-diphenylamine);Poly(4-butyl-N,N-diphenylaniline);Poly-TPD, average MW: 20,000 - 35,000;Poly[bis(4-phenyl)(4-butylphenyl)aMine];4-Butyl-N,N-diphenylaniline homopolymer;Benzenamine, 4-butyl-N,N-diphenyl-, homopolymer;Poly[N,N'-bis(4-butylphenyl)-N,N'-bis(phenyl)-benzi;Poly-TPD , Poly[N,N'-bis(4-butylphenyl)-N,N'-bis(phenyl)-benzi
CBNumber:
CB92548172
분자식:
C22H23N
포뮬러 무게:
301.43
MOL 파일:
472960-35-3.mol
MSDS 파일:
SDS

Poly-TPD , Poly[N,N'-bis(4-butylphenyl)-N,N'-bis(phenyl)-benzi 속성

저장 조건
15-25°C
InChI
InChI=1S/C22H23N/c1-2-3-10-19-15-17-22(18-16-19)23(20-11-6-4-7-12-20)21-13-8-5-9-14-21/h4-9,11-18H,2-3,10H2,1H3
InChIKey
LGDCSNDMFFFSHY-UHFFFAOYSA-N
SMILES
N(C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC(CCCC)=CC=1

안전

HS 번호 29211990

Poly-TPD , Poly[N,N'-bis(4-butylphenyl)-N,N'-bis(phenyl)-benzi C화학적 특성, 용도, 생산

개요

Poly(N,N'-bis-4-butylphenyl-N,N'-bisphenyl)benzidine, also known as polyTPD, is an excellent hole transport layer material used in photovoltaics such as perovskite solar cells. It has also proven polyTPD is a promising candidate HTL in multilayer WPLEDs because its HOMO level 5.2 eV is very close to the work function of the indium tin oxide ITO/PEDOT:PSS anode.

용도

In a recent study of a double-junction Quantum-Dot Light-Emitting Diodes (QD-LEDs), an impressive high quantum efficiency of 42.2% and a high current efficiency of 183.3 cd/A were achieved, which are comparable to those of the best vacuum-deposited tandem organic LEDs. Such high-efficiency devices are achieved by interface engineering of fully optimized single light-emitting units, which improves carriers′ transport/injection balance and suppresses exciton quenching induced by ZnO, and design of an effective interconnecting layer consisting of Poly-TPD mixed poly(9-vinylcarbazole) (PVK)/poly(3,4-ethylenedioxythiophene):polystyrene sulfonate/polyethylenimine ethoxylated-modified ZnO.

Indoor photovoltaics is one of the best sustainable and reliable energy source for low power consumption electronics such as the rapidly growing Internet of Things.
In another recent study, Perovskite photovoltaic (PPV) cells with a mesoporous PPV (mPPV) structure using typical Spiro-OMeTAD as the hole transport layer (HTL) shows the highest maximum power density (Pmax) of 19.9 μW/cm2 under 200 lux and 115.6 μWcm-2 under 1000 lux (without masking), which is among the best of the indoor PV. When PEDOT:PSS is replaced by Poly-TPD as HTL in the inverted PPV (iPPV) cell, the Pmax under indoor light improves significantly and is comparable to that of the best mesoporous mPPV cell.


Device performance:
iPPV-Poly-TPD
1. under one sun [Pin=100 mW/cm2]
Jsc=21.8 mA/cm2
Voc=1.07 V
FF=73.7%
PCE=17.2%

2. under 1000 lux [200 lux]
Jsc=172.3 mA/cm2
Voc=0.851 V
FF=75.9%
Pmax=111.3 mW/cm

Poly-TPD , Poly[N,N'-bis(4-butylphenyl)-N,N'-bis(phenyl)-benzi 준비 용품 및 원자재

원자재

준비 용품


Poly-TPD , Poly[N,N'-bis(4-butylphenyl)-N,N'-bis(phenyl)-benzi 공급 업체

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