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ChemicalBook >> CAS DataBase List >>Formic acid

Formic acid suppliers

Formic acid

CAS:
64-18-6
MF:
CH2O2
MW:
46.03

Properties

Melting point:
8.2-8.4 °C (lit.)
Boiling point:
100-101 °C (lit.)
Density 
1.22 g/mL at 25 °C (lit.)
vapor density 
1.03 (vs air)
vapor pressure 
52 mm Hg ( 37 °C)
FEMA 
2487 | FORMIC ACID
refractive index 
n20/D 1.377
Flash point:
133 °F
storage temp. 
2-8°C
solubility 
H2O: soluble1g/10 mL, clear, colorless
pka
3.75(at 20℃)
form 
Liquid
Specific Gravity
1.216 (20℃/20℃)
color 
APHA: ≤15
PH
3.47(1 mM solution);2.91(10 mM solution);2.38(100 mM solution);
Odor
at 0.10 % in water. pungent vinegar formyl
Odor Type
acetic
biological source
synthetic
explosive limit
12-38%(V)
Water Solubility 
MISCIBLE
Thermal Conductivity
0.265 W/(m·K) at 25 ℃
Sensitive 
Hygroscopic
λmax
λ: 260 nm Amax: 0.03
λ: 280 nm Amax: 0.01
Merck 
14,4241
JECFA Number
79
BRN 
1209246
Henry's Law Constant
At 25 °C: 95.2, 75.1, 39.3, 10.7, and 3.17 at pH values of 1.35, 3.09, 4.05, 4.99, and 6.21, respectively (Hakuta et al., 1977)
Exposure limits
TLV-TWA 5 ppm (~9 mg/m3) (ACGIH, MSHA, OSHA, and NIOSH); IDLH 100 ppm (180 mg/m3) (NIOSH).
Dielectric constant
58.0(16℃)
Stability:
Stable. Substances to be avoided include strong bases, strong oxidizing agents and powdered metals, furfuryl alcohol. Combustible. Hygroscopic. Pressure may build up in tightly closed bottles, so bottles should be opened carefully and vented periodically.
Major Application
sample preparation
Cosmetics Ingredients Functions
PRESERVATIVE
pH ADJUSTERS
FRAGRANCE
Cosmetic Ingredient Review (CIR)
Formic acid (64-18-6)
InChI
1S/CH2O2/c2-1-3/h1H,(H,2,3)
InChIKey
BDAGIHXWWSANSR-UHFFFAOYSA-N
SMILES
OC=O
LogP
-0.540
CAS DataBase Reference
64-18-6(CAS DataBase Reference)
NIST Chemistry Reference
Formic acid(64-18-6)
EPA Substance Registry System
Formic acid (64-18-6)

Safety Information

Symbol(GHS) 
GHS hazard pictogramsGHS hazard pictograms
GHS05,GHS06
Signal word 
Danger
Hazard statements 
H302-H314-H331
Precautionary statements 
P261-P280-P301+P312-P303+P361+P353-P304+P340+P310-P305+P351+P338
Hazard Codes 
T,C,Xi
Risk Statements 
23/24/25-34-40-43-35-36/38-10
Safety Statements 
36/37-45-26-23-36/37/39
OEB
B
OEL
TWA: 5 ppm (9 mg/m3)
RIDADR 
UN 1779 8/PG II (FORMIC ACID with more than 85 % acid by mass)
RIDADR 
UN 3412 8/PG II (FORMIC ACID with not less than 10 % but not more than 85 % acid by mass)
WGK Germany 
2
RTECS 
LP8925000
10
Autoignition Temperature
1004 °F
TSCA 
TSCA listed
HazardClass 
8
PackingGroup 
II
HS Code 
29151100
Storage Class
3 - Flammable liquids
Hazard Classifications
Acute Tox. 3 Inhalation
Acute Tox. 4 Oral
Eye Dam. 1
Flam. Liq. 3
Skin Corr. 1A
Hazardous Substances Data
64-18-6(Hazardous Substances Data)
Toxicity
LD50 in mice (mg/kg): 1100 orally; 145 i.v. (Malorny)
IDLA
30 ppm
Limited Quantities
1.0 L (0.3 gallons) (liquid) or 1 Kg (2.2 lbs) (solid)
Excepted Quantities
Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)

Use

Formic acid has a number of commercial uses. It is used in the leather industry to degreaseand remove hair from hides and as an ingredient in tanning formulations. It is used as alatex coagulant in natural rubber production. Formic acid and its formulations are used aspreservatives of silage. It is especially valued in Europe where laws require the use of naturalantibacterial agents rather than synthetic antibiotics. Silage is fermented grass and crops thatare stored in silos and used for winter feed. Silage is produced during anaerobic fermentationwhen bacteria produce acids that lower the pH, preventing further bacterial action. Acetic acidand lactic acid are the desired acids during silage fermentation. Formic acid is used in silageprocessing to reduce undesirable bacteria and mold growth. Formic acid reduces Clostridiabacteria that would produce butyric acid causing spoilage. In addition to preventing silagespoilage, formic acid helps preserve protein content, improves compaction, and preservessugar content. Formic acid is used as a miticide by beekeepers.

1007 supplier list of "Formic acid"

  • Product Name:Formate
  • Products Intro:Purity: ULC-MS,99% | Package: $670.9/50ml;Bulk package | CustNote: ULC-MS,99%
  • Company Type: Trader
  • Country/Region: UNITED STATES
  • Main Products: Chemicals and BioChemicals,Materials Science,ligands acting on targets,Proteins,Antibodies
  • Product Name:Formic acid
  • Products Intro:Purity: 99.0% Min | Package: 1g
  • Company Type: Trader
  • Country/Region: CHINA
Formic acid Formic acid 2Photos

$10.00-500.00 / 25kg

  • Product Name:Formic acid
  • Products Intro:Purity: 0.98|Package: 25kg;10.00;USD|50kg;20.00;USD|1000kg;500.00;USD
  • Company Type: Trader
  • Country/Region: CHINA
  • Main Products: Monochloroacetic Acid,Paradichlorobenzene,Rongalite,Thiourea,Zinc Oxide
Formic acid
  • Product Name:Formic acid
  • Products Intro:Purity: 99% | Package: 25KG;
  • Company Type: Trader
  • Country/Region: CHINA
  • Main Products: Ammonium thiocyanate,Sodium thiocyanate,D-SERINE,Rhamnolipid,Glycine
  • Product Name:Formic acid
  • Products Intro:Purity: 99.99% | Package: 1Tons;806USD|10Tons;800USD|100Tons;790USD
  • Company Type: Trader
  • Country/Region: CHINA
  • Main Products: Rutile,PVA,Titanium dioxide,Pharmaceutical intermediates,Cobalt oxide
  • Product Name:Natural Formic acid
  • Products Intro:Purity: 95% | Package: 25L,200L,1000L/drum
  • Company Type: Trader
  • Country/Region: CHINA
  • Main Products: alcohols,acids,esters,aldehydes,ketones
Formic acid;Methanoic acid
  • Product Name:Formic acid;Methanoic acid
  • Products Intro:Purity: 99.99% | Package: According to customer requirements | CustNote: Organic chemical raw material
  • Company Type: Trader
  • Country/Region: CHINA
  • Main Products: alcohols,lipid,acids,ethers
Formic acid Formic acid 2Photos
  • Product Name:Formic acid
  • Products Intro:Purity: 99%|Package: 25KG
  • Company Type: Trader
  • Country/Region: CHINA
  • Main Products: 1-Octadecanol,AMP 95,Polyisobutylene,tetramisole hcl,Ivermectin
Formic acid Formic acid 2Photos

$15.50/ 1KG

  • Product Name:Formic acid
  • Products Intro:Purity: 99%|Package: 1KG;15.50;USD
  • Company Type: Trader
  • Country/Region: CHINA
  • Main Products: acetic acid,Ethyl oleate,Hypophosphorous acid,tetramisole,OPP
  • Product Name:Formic acid
  • Products Intro:Purity: 99% | Package: 1KG;50USD|1000KG
  • Company Type: Trader
  • Country/Region: CHINA
  • Main Products: Electronic material intermediates,OLED,ppb grade Monomer,Pharmaceutical intermediates,KrF/ArF Monomer
You can find Formic acid suppliers, manufacturers, and distributors from countries such as China, India and the United States here. Browse to the tetrahydrofuran product information displayed by the supplier, as well as the supplier's contact and capability information.

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