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ChemicalBook >> CAS DataBase List >>Acetic anhydride

Acetic anhydride suppliers

Acetic anhydride

CAS:
108-24-7
MF:
C4 H6 O3
MW:
102.09

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Company Type

Properties

Melting point:
-73.1 °C
Boiling point:
140 °C
Density 
1.087
vapor density 
3.5 (vs air)
vapor pressure 
10 mm Hg ( 36 °C)
refractive index 
n20/D 1.390(lit.)
Flash point:
130 °F
storage temp. 
Store at RT.
solubility 
Miscible with ether, chloroform and benzene.
form 
Liquid
Specific Gravity
1.082
color 
Colorless
Odor
Very strong; pungent; vinegar-like characteristic odor.
PH
3 (10g/l, H2O, 20°C)
explosive limit
2.0-10.2%(V)
Odor Type
acidic
Water Solubility 
REACTS
Sensitive 
Moisture Sensitive
Merck 
14,56
BRN 
385737
Exposure limits
NIOSH REL: ceiling 5 ppm (20 mg/m3), IDLH 200 ppm; OSHA PEL: 5 ppm; ACGIH TLV: ceiling 5 ppm.
Dielectric constant
20.0
Stability:
Stability Flammable. Incompatible with strong oxidizing agents, water, strong bases, alcohols.
LogP
-0.58 at 20℃

Safety Information

Symbol(GHS) 
GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS02,GHS05,GHS06
Signal word 
Danger
Hazard statements 
H226-H302-H314-H330
Precautionary statements 
P210-P280-P301+P312-P303+P361+P353-P304+P340+P310-P305+P351+P338
Hazard Codes 
C,Xn,F,Xi
Risk Statements 
11-20/21/22-37/38-41-34-20/21-10-20/22-19-40
Safety Statements 
26-39-45-36/37/39-33-16
RIDADR 
UN 2924 3/PG 2
WGK Germany 
3
RTECS 
AK1925000
21
Autoignition Temperature
629 °F
TSCA 
Yes
HazardClass 
8
PackingGroup 
II
HS Code 
29152400
Toxicity
LD50 orally in rats: 1.78 g/kg (Smyth)
IDLA
200 ppm

Use

Acetic anhydride is a colourless liquid and appreciably soluble in water. It is of ethanoic acid smell. Acetic acid anhydride is flammable, moisture sensitive, and incompatible with strong oxidising agents, water, strong bases, alcohols, metals, reducing agents, amines, ammonia, nitrates, nitric acid, permanganates, phenols, sodium hydroxide, hydrogen peroxide, chromium trioxide, potassium hydroxide, perchloric acid, and ethanol. Acetic anhydride is mainly used for the acetylation of cellulose to cellulose acetate for photographic film and other applications. Upon burning, acetic anhydride decomposes and produces toxic gases and toxic fumes including acetic acid fumes. It attacks many metals with or without the presence of water.

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