Allyl chloride manufacturers and suppliers

Allyl chloride suppliers

Properties

Melting point:: -136 °C

Boiling point:: 44-46 °C(lit.)

Density: 0.939 g/mL at 25 °C(lit.)

vapor density: 2.6 (vs air)

vapor pressure: 20.58 psi ( 55 °C)

refractive index: n20/D 1.414(lit.)

Flash point:: −20 °F

storage temp.: Store at +2°C to +8°C.

solubility: alcohol: miscible(lit.)

form: Powder/Solid

color: White

Specific Gravity: 0.939

Odor: pungent odor

explosive limit: 3.3-11.2%(V)

Water Solubility: 3.6 G/L (20 ºC)

FreezingPoint: -134.5℃

Merck: 14,289

BRN: 635704

Henry's Law Constant: 2.69 at 25 °C (static headspace-GC, Welke et al., 1998)

Exposure limits: NIOSH REL: TWA 1 ppm (3 mg/m³), STEL 2 ppm (6 mg/m³), IDLH 250 ppm; OSHA PEL: TWA 1 ppm; ACGIH TLV: STEL 2 ppm.

Dielectric constant: 8.2（20℃）

Stability:: Stable, but reacts vigorously or violently with a wide variety of materials. Highly flammable. Incompatible with strong oxidizing agents, acids, amines, peroxides, chlorides of iron and aluminium, BF3, aromatic hydrocarbons, Lewis acids, metals, caustics, ammonia, ferric chloride, ethylene imine, ethylenediamine. Heat and light sensitive

LogP: 2.1 at 25℃

Safety Information

Symbol(GHS): GHS02,GHS07,GHS08,GHS09

Signal word: Danger

Hazard statements: H225-H302+H312+H332-H315-H319-H341-H351-H371-H372-H400

Precautionary statements: P210-P273-P280-P303+P361+P353-P304+P340+P312-P308+P311

Hazard Codes: F,Xn,N,T

Risk Statements: 45-46-11-20/21/22-36/37/38-48/20-50-68-40-39/23/24/25-23/24/25-48/23/24/25

Safety Statements: 53-26-36/37-45-61-46-25-16-7

RIDADR: UN 1100 3/PG 1

WGK Germany: 2

RTECS: UC7350000

F: 19

Autoignition Temperature: 390 °C

Hazard Note: Flammable

TSCA: Yes

HS Code: 2903 29 00

HazardClass: 3

PackingGroup: I

Toxicity: LD50 orally in rats: 0.7 g/kg (Smyth, Carpenter)

IDLA: 250 ppm

Use

Allyl chloride is toxic and flammable. Exposures to allyl chloride cause a cough, sore throat, headache, dizziness, weakness, respiratory distress, abdominal pain, burning sensation, vomiting, and loss of consciousness. After acute inhalation exposures to high levels of allyl chloride, workers developed irritation of the eyes and respiratory passages, loss of consciousness, and fatal injury. Prolonged and intense exposure produced conjunctivitis, reddening of eyelids, and corneal burn, damage to the CNS, causing motor and sensory neurotoxic damage, and the heart and respiratory system, causing the onset of pulmonary edema in humans. Laboratory rabbits exposed to allyl chloride through inhalation developed degenerative changes that included dilation of sinusoids and vacuolar degeneration in the liver, congestion or cloudy swelling and fatty degeneration of the epithelium of the renal convoluted tubules, and thickening of the alveolar septa in the lungs. The exposed cat exhibited only muscle weakness and unsteady gait toward the end of the exposure period.

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