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ChemicalBook >> CAS DataBase List >>Nitrogen Tetroxide

Nitrogen Tetroxide suppliers

Nitrogen Tetroxide

CAS:
10544-72-6
MF:
N2O4
MW:
92.01

Properties

Melting point:
−11 °C(lit.)
Boiling point:
21 °C(lit.)
Density 
2.62 g/mL at 25 °C(lit.)
vapor density 
1.58 (21 °C, vs air)
vapor pressure 
14.33 psi ( 20 °C)
solubility 
reacts with H2O
form 
gas
color 
colorless liquid; equil with NO
Water Solubility 
reac H2O [CRC10]
Dielectric constant
2.5(15℃)

Safety Information

Symbol(GHS) 
GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS03,GHS05,GHS04,GHS06
Signal word 
Danger
Hazard statements 
H270-H314-H330
Precautionary statements 
P260-P264-P280-P301+P330+P331-P303+P361+P353-P363-P304+P340-P310-P321-P305+P351+P338-P405-P501-P220-P244-P370+P376-P403-P260-P271-P284-P304+P340-P310-P320-P403+P233-P405-P501
Hazard Codes 
T+
Risk Statements 
26-34
Safety Statements 
9-26-28-36/37/39-45
RIDADR 
UN 1067 2.3
WGK Germany 
1
RTECS 
QX1575000
HS Code 
28112900
Toxicity
dog,LC50,inhalation,260mg/m3 (260mg/m3),CARDIAC: OTHER CHANGESLUNGS, THORAX, OR RESPIRATION: ACUTE PULMONARY EDEMABEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD,"Spravochnik po Toksikologii i Gigienicheskim Normativam Vol. -, Pg. 6, 1999.

Use

dinitrogen tetroxide: A colourlessto pale yellow liquid or a brown gas,N2O4; r.d. 1.45 (liquid); m.p. –11.2°C;b.p. 21.2°C. It dissolves in water withreaction to give a mixture of nitricacid and nitrous acid. It may be readilyprepared in the laboratory by thereaction of copper with concentratednitric acid; mixed nitrogen oxidescontaining dinitrogen oxide may alsobe produced by heating metal nitrates.The solid compound is whollyN2O4 and the liquid is about 99%N2O4 at the boiling point; N2O4 is diamagnetic.In the gas phase it dissociatesto give nitrogen dioxideN2O4?2NO2Because of the unpaired electron thisis paramagnetic and brown. LiquidN2O4 has been widely studied as anonaqueous solvent system (selfionizesto NO+ and NO3-). Dinitrogentetroxide, along with other nitrogenoxides, is a product of combustionengines and is thought to be involvedin the depletion of stratosphericozone.

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