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ChemicalBook >> CAS DataBase List >>Sodium borohydride

Sodium borohydride suppliers

Sodium borohydride

CAS:
16940-66-2
MF:
BH4Na
MW:
37.83

Company Type

Properties

Melting point:
>300 °C (dec.) (lit.)
Boiling point:
500°C
Density 
1.035 g/mL at 25 °C
vapor pressure 
<1 hPa (25 °C)
Flash point:
158 °F
storage temp. 
Store at RT.
solubility 
Methanol (Slightly), Water (Soluble)
form 
tablets
Specific Gravity
1.4
color 
White
PH
11 (10g/l, H2O, 20℃)
explosive limit
3.02%(V)
Water Solubility 
550 g/L (25 ºC)
Sensitive 
Hygroscopic
Merck 
14,8592
Stability:
Stability Stable, but reacts readily with water (reaction may be violent). Incompatible with water, oxidizing agents, carbon dioxide, hydrogen halides, acids, palladium, ruthenium and other metal salts, glass. Flammable solid. Air-sensitive.
InChIKey
YOQDYZUWIQVZSF-UHFFFAOYSA-N

Safety Information

Symbol(GHS) 
GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS02,GHS05,GHS06,GHS08
Signal word 
Danger
Hazard statements 
H260-H301-H314-H360F
Precautionary statements 
P201-P231+P232-P280-P308+P313-P370+P378-P402+P404
Hazard Codes 
F,T,N,C,Xn
Risk Statements 
60-61-15-34-23/24/25-24/25-35-21/22-51/53-42/43-49-63-62-36/38-43-19-68-50/53
Safety Statements 
53-43-45-43A-36/37/39-26-22-50-36/37-61
RIDADR 
UN 3129 4.3/PG 3
WGK Germany 
2
RTECS 
ED3325000
10-21
Autoignition Temperature
220 °C
TSCA 
Yes
HazardClass 
4.3
PackingGroup 
I
HS Code 
28500090
Toxicity
LD50 orally in Rabbit: 160 mg/kg LD50 dermal Rabbit 230 mg/kg

Use

sodium borohydride is relatively mild reducing agent. it has a good efficacy on reducing aldehydes and ketones. its commonly-used solvents include alcohol, tetrahydrofuran, dmf, and water. it generally does not reduce an ester group, a carboxyl group, and amide. however, when combined with appropriate solvent or catalyzed by lewis acid in high temperature, it can be used for reducing weak carbonyl group such as ester.

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