Tris(triphenylphosphine)chlororhodium

Melting point :245-250 °C (dec.)
Boiling point :>170°C
Density :1.363; d 1.379
vapor pressure :0Pa at 25℃
storage temp. :Keep in dark place,Inert atmosphere,Room temperature
solubility :Soluble in most solvents (e.g. benzene, ethanol, chloroform, dichloromethane) but with phosphine dissociation. Reacts with O{2} in solution
form :Crystalline Powder
color :Red-brown to maroon
Water Solubility :insoluble
Hydrolytic Sensitivity :4: no reaction with water under neutral conditions
Sensitive :air sensitive
Merck :14,9758
BRN :4581440
Exposure limits :ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3 InChI :1S/3C18H15P.ClH.Rh/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;/h3*1-15H;1H;/q;;;;+1/p-1
InChIKey :QEYYHUJFSQCTAE-UHFFFAOYSA-M
SMILES :Cl[Rh].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9
LogP :5.69 at 20℃
CAS DataBase Reference :14694-95-2(CAS DataBase Reference)
NIST Chemistry Reference :chlorotris(triphenylphosphine)rhodium(14694-95-2)
EPA Substance Registry System :Rhodium, chlorotris(triphenylphosphine)-, (SP-4-2)- (14694-95-2)

Symbol(GHS):
Signal word:	Warning
Hazard statements:	Code Hazard statements Hazard class Category Signal word Pictogram P-Codes H317 May cause an allergic skin reaction Sensitisation, Skin Category 1 Warning P261, P272, P280, P302+P352,P333+P313, P321, P363, P501 H413 May cause long lasting harmful effects to aquatic life Hazardous to the aquatic environment, long-term hazard Category 4
Precautionary statements:	P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection. P302+P352 IF ON SKIN: wash with plenty of soap and water. P333+P313 IF SKIN irritation or rash occurs: Get medical advice/attention.