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ChemicalBook >> CAS DataBase List >> (S)-(+)-(2,6-DIMETHYL-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE

(S)-(+)-(2,6-DIMETHYL-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE

(S)-(+)-(2,6-DIMETHYL-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE price.
  • $98 - $2273
  • Product name: (S)-(+)-(2,6-DIMETHYL-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE
  • CAS: 185449-86-9
  • MF: C24H22NO2P
  • MW: 387.41
  • EINECS:
  • MDL Number:MFCD04117683
  • Synonyms:(S)-(+)-(2,6-DIMETHYL-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE;(S)-(+)-(2,6-Dimethyl-3,5-dioxa-4-phospha-cyclohepta[2,1-a;3,4-a']dinaphthalen-4-yl)dimethylamine,min.98%;3,4-a']dinaphthalen-4-yl)dimethylamine, min. 98%;N,N,2,6-Tetramethyldinaphtho-[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine;(11bS)-N,N,2,6-tetraMethyl-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-aMine;3,4-a']dinaphthalen-4-yl)dimethylamine,98%;(11bS)-N,N,2,6-Tetramethyl-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine,99%e.e.
Price13 Properties Safety Information Description
13 prices
Selected condition：
Brand
  • AK Scientific
  • Alichem
  • Ambeed
  • American Custom Chemicals Corporation
  • Chemenu
  • Crysdot
  • Matrix Scientific
  • Strem Chemicals
Package
  • 100mg
  • 250mg
  • 500MG
  • 1g
  • ManufacturerAK Scientific
  • Product number9701AA
  • Product descriptionN,N,2,6-Tetramethyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
  • Packaging1g
  • Price$2273
  • Updated2021-12-16
  • Buy
  • ManufacturerAlichem
  • Product number185449869
  • Product descriptionN,N,2,6-Tetramethyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
  • Packaging1g
  • Price$634.28
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA775837
  • Product description(11bS)-N,N,2,6-Tetramethyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine 98%+99%ee
  • Packaging100mg
  • Price$98
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA775837
  • Product description(11bS)-N,N,2,6-Tetramethyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine 98%+99%ee
  • Packaging250mg
  • Price$188
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA775837
  • Product description(11bS)-N,N,2,6-Tetramethyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine 98%+99%ee
  • Packaging1g
  • Price$470
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberING0001353
  • Product description(S)-(+)-(2,6-DIMETHYL-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE 95.00%
  • Packaging100MG
  • Price$288.75
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberING0001353
  • Product description(S)-(+)-(2,6-DIMETHYL-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE 95.00%
  • Packaging500MG
  • Price$1127.86
  • Updated2021-12-16
  • Buy
  • ManufacturerChemenu
  • Product numberCM141224
  • Product descriptionN,N,2,6-Tetramethyldinaphtho-[2,1-d:1'',2''-f][1,3,2]dioxaphosphepin-4-amine 95%
  • Packaging1g
  • Price$729
  • Updated2021-12-16
  • Buy
  • ManufacturerCrysdot
  • Product numberCD51001670
  • Product descriptionN,N,2,6-Tetramethyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine 95+%
  • Packaging1g
  • Price$772
  • Updated2021-12-16
  • Buy
  • ManufacturerMatrix Scientific
  • Product number090119
  • Product descriptionN,N,2,6-Tetramethyldinaphtho-[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine 95+%
  • Packaging250mg
  • Price$742
  • Updated2021-12-16
  • Buy
  • ManufacturerMatrix Scientific
  • Product number090119
  • Product descriptionN,N,2,6-Tetramethyldinaphtho-[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine 95+%
  • Packaging1g
  • Price$1647
  • Updated2021-12-16
  • Buy
  • ManufacturerStrem Chemicals
  • Product number15-1255
  • Product description(S)-(+)-(2,6-Dimethyl-3,5-dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)dimethylamine, min. 98%
  • Packaging100mg
  • Price$195
  • Updated2024-03-01
  • Buy
  • ManufacturerStrem Chemicals
  • Product number15-1255
  • Product description(S)-(+)-(2,6-Dimethyl-3,5-dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)dimethylamine, min. 98%
  • Packaging500mg
  • Price$779
  • Updated2024-03-01
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
AK Scientific 9701AA N,N,2,6-Tetramethyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine 1g $2273 2021-12-16 Buy
Alichem 185449869 N,N,2,6-Tetramethyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine 1g $634.28 2021-12-16 Buy
Ambeed A775837 (11bS)-N,N,2,6-Tetramethyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine 98%+99%ee 100mg $98 2021-12-16 Buy
Ambeed A775837 (11bS)-N,N,2,6-Tetramethyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine 98%+99%ee 250mg $188 2021-12-16 Buy
Ambeed A775837 (11bS)-N,N,2,6-Tetramethyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine 98%+99%ee 1g $470 2021-12-16 Buy
American Custom Chemicals Corporation ING0001353 (S)-(+)-(2,6-DIMETHYL-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE 95.00% 100MG $288.75 2021-12-16 Buy
American Custom Chemicals Corporation ING0001353 (S)-(+)-(2,6-DIMETHYL-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE 95.00% 500MG $1127.86 2021-12-16 Buy
Chemenu CM141224 N,N,2,6-Tetramethyldinaphtho-[2,1-d:1'',2''-f][1,3,2]dioxaphosphepin-4-amine 95% 1g $729 2021-12-16 Buy
Crysdot CD51001670 N,N,2,6-Tetramethyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine 95+% 1g $772 2021-12-16 Buy
Matrix Scientific 090119 N,N,2,6-Tetramethyldinaphtho-[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine 95+% 250mg $742 2021-12-16 Buy
Matrix Scientific 090119 N,N,2,6-Tetramethyldinaphtho-[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine 95+% 1g $1647 2021-12-16 Buy
Strem Chemicals 15-1255 (S)-(+)-(2,6-Dimethyl-3,5-dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)dimethylamine, min. 98% 100mg $195 2024-03-01 Buy
Strem Chemicals 15-1255 (S)-(+)-(2,6-Dimethyl-3,5-dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)dimethylamine, min. 98% 500mg $779 2024-03-01 Buy

Properties

Melting point :228-229°C
Boiling point :571.0±53.0 °C(Predicted)
alpha :+636° (c 0.30, CH2Cl2)
storage temp. :under inert gas (nitrogen or Argon) at 2-8°C
form :Powder
pka :1.32±0.20(Predicted)
color :off-white
Sensitive :moisture sensitive
InChI :1S/C24H22NO2P/c1-15-13-17-9-5-7-11-19(17)21-22-20-12-8-6-10-18(20)14-16(2)24(22)27-28(25(3)4)26-23(15)21/h5-14H,1-4H3
InChIKey :MXASPZVRFOFONU-UHFFFAOYSA-N
SMILES :CN(C)P1Oc2c(C)cc3ccccc3c2-c4c(O1)c(C)cc5ccccc45

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P321 Specific treatment (see … on this label).
P332+P313 IF SKIN irritation occurs: Get medical advice/attention.
P362 Take off contaminated clothing and wash before reuse.

Description

1. Ligand used in the enantioselective, rhodium-catalyzed hydrogenation of substituted olefins, such as N-acetyldihydroamino acids, enamides, and unsaturated acids.
2. Ligand used in the enantioselective, iridium-catalyzed allylic substitution of allyl acetates containing only a single substituent in the 1 or 3 position.
3. Ligand use in the rhodium-catalyzed, amide directed, asymmetric hydroboration reaction.
4. Ligand used in asymmetric conjugate addition of aryl boronic acids to dihydronitronaphthalenes.
5. Ligand used in the rhodium-catalyzed asymmetric intramolecular 1,4 addition.

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Suppliers and manufacturers

Shanghai Daken Advanced Materials Co.,Ltd
Hangzhou MolCore BioPharmatech Co.,Ltd.
Aladdin Scientific J & K SCIENTIFIC LTD. Meryer (Shanghai) Chemical Technology Co., Ltd. Daicel Chiral Technologies (China)CO.,LTD Tianjin Derchemist Science & Technology Co., Ltd. Shanghai Incat Chemtech Co.,Ltd. Shanghai Chiral bio-compound co., Ltd. Shanghai YuanYe Biotechnology Co., Ltd.