ChemicalBook >> CAS DataBase List >>(S)-(+)-(2,6-DIMETHYL-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE

(S)-(+)-(2,6-DIMETHYL-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE

(S)-(+)-(2,6-DIMETHYL-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE structure

CAS No.: 185449-86-9

Chemical Name:: (S)-(+)-(2,6-DIMETHYL-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE

Synonyms: 3,4-a'']dinaphthalen-4-yl)dimethylamine;3,4-a']dinaphthalen-4-yl)dimethylamine,98%;3,4-a']dinaphthalen-4-yl)dimethylamine,min.98%;3,4-a']dinaphthalen-4-yl)dimethylamine, min. 98%;(S)-(+)-(2,6-Dimethyl-3,5-dioxa-4-phospha-cyclohepta[2,1-a;N,N,2,6-Tetramethyldinaphtho-[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine;(11bS)-N,N,2,6-Tetramethyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine;(11bS)-N,N,2,6-tetraMethyl-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-aMine;Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine, N,N,2,6-tetramethyl-, (11bS)-;(11bS)-N,N,2,6-Tetramethyl-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine,99%e.e.

CBNumber:: CB6487814

Molecular Formula:: C24H22NO2P

Molecular Weight:: 387.41

MDL Number:: MFCD04117683

MOL File:: 185449-86-9.mol

Last updated:2023-05-04 15:16:43

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(S)-(+)-(2,6-DIMETHYL-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE Properties

Melting point	228-229°C
Boiling point	571.0±53.0 °C(Predicted)
alpha	+636° (c 0.30, CH2Cl2)
storage temp.	under inert gas (nitrogen or Argon) at 2-8°C
pka	1.32±0.20(Predicted)
form	Powder
color	off-white
Sensitive	moisture sensitive

SAFETY

Risk and Safety Statements

Symbol(GHS)	GHS07
Signal word	Warning
Hazard statements	H319-H335-H315
Precautionary statements	P264-P280-P302+P352-P321-P332+P313-P362-P264-P280-P305+P351+P338-P337+P313P
Hazard Codes	Xn
Risk Statements	36/37/38-22
Safety Statements	26-36/37/39

(S)-(+)-(2,6-DIMETHYL-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE price More Price(13)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Strem Chemicals	15-1255	(S)-(+)-(2,6-Dimethyl-3,5-dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)dimethylamine, min. 98%	185449-86-9	100mg	$195	2024-03-01	Buy
Strem Chemicals	15-1255	(S)-(+)-(2,6-Dimethyl-3,5-dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)dimethylamine, min. 98%	185449-86-9	500mg	$779	2024-03-01	Buy
American Custom Chemicals Corporation	ING0001353	(S)-(+)-(2,6-DIMETHYL-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE 95.00%	185449-86-9	500MG	$1127.86	2021-12-16	Buy
Matrix Scientific	090119	N,N,2,6-Tetramethyldinaphtho-[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine 95+%	185449-86-9	1g	$1647	2021-12-16	Buy
AK Scientific	9701AA	N,N,2,6-Tetramethyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine	185449-86-9	1g	$2273	2021-12-16	Buy

Product number	Packaging	Price	Buy
15-1255	100mg	$195	Buy
15-1255	500mg	$779	Buy
ING0001353	500MG	$1127.86	Buy
090119	1g	$1647	Buy
9701AA	1g	$2273	Buy

(S)-(+)-(2,6-DIMETHYL-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE Chemical Properties,Uses,Production

Description

1. Ligand used in the enantioselective, rhodium-catalyzed hydrogenation of substituted olefins, such as N-acetyldihydroamino acids, enamides, and unsaturated acids.
2. Ligand used in the enantioselective, iridium-catalyzed allylic substitution of allyl acetates containing only a single substituent in the 1 or 3 position.
3. Ligand use in the rhodium-catalyzed, amide directed, asymmetric hydroboration reaction.
4. Ligand used in asymmetric conjugate addition of aryl boronic acids to dihydronitronaphthalenes.
5. Ligand used in the rhodium-catalyzed asymmetric intramolecular 1,4 addition.

(S)-(+)-(2,6-DIMETHYL-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE Preparation Products And Raw materials

Raw materials

Preparation Products

(S)-(+)-(2,6-DIMETHYL-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE Suppliers

Global( 37)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
CR Corporation Lomited		fred.wen@crcorporation.cn	CHINA	12069	58
Hangzhou MolCore BioPharmatech Co.,Ltd.	+86-057181025280; +8617767106207	sales@molcore.com	China	49739	58
Shaoxin Catsyn Co., Ltd.	+undefined-0575-82040869 +86-0575-82040869;	sales@catsyn.com	China	6116	58
Aladdin Scientific	+1-833-552-7181	sales@aladdinsci.com	United States	57511	58
J & K SCIENTIFIC LTD.	010-82848833 400-666-7788	jkinfo@jkchemical.com	China	96815	76
Meryer (Shanghai) Chemical Technology Co., Ltd.	4006608290; 18621169109	market03@meryer.com	China	40241	62
Daicel Chiral Technologies (China)CO.,LTD	021-50460086-9 15921403865	han_yajun@dctc.daicel.com	China	6818	65
Tianjin Derchemist Science & Technology Co., Ltd.	22-58627059 13920586291	zdcomcon@126.com	China	2918	50
Shanghai Incat Chemtech Co.,Ltd.	021-57603038 13601791340	307593986@qq.com	China	475	58
Bide Pharmatech Ltd.	400-1647117 15221909166	product02@bidepharm.com	China	41438	60

Supplier	Advantage
CR Corporation Lomited	58
Hangzhou MolCore BioPharmatech Co.,Ltd.	58
Shaoxin Catsyn Co., Ltd.	58
Aladdin Scientific	58
J & K SCIENTIFIC LTD.	76
Meryer (Shanghai) Chemical Technology Co., Ltd.	62
Daicel Chiral Technologies (China)CO.,LTD	65
Tianjin Derchemist Science & Technology Co., Ltd.	50
Shanghai Incat Chemtech Co.,Ltd.	58
Bide Pharmatech Ltd.	60

185449-86-9((S)-(+)-(2,6-DIMETHYL-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE)Related Search:

(R)-MONOPHOS (11bS)-N,N-dimethyl-2,6-diphenyl-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin- 4-amine 3,4-a']dinaphthalen-4-yl)dipropylaMine (11bS)-N,N-Bis[(R)-1-phenylethyl]-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine (11bS)-8,9,10,11,12,13,14,15-octahydro-N,N-bis[(1S)-1-phenylethyl]-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-aMine

(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a N,N-diisopropyl-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine (S)-(+)-(2,6-DIMETHYL-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE (R)-MONOPHOS

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(S)-(+)-(2,6-DIMETHYL-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE (S)-(+)-(2,6-Dimethyl-3,5-dioxa-4-phospha-cyclohepta[2,1-a 3,4-a']dinaphthalen-4-yl)dimethylamine,min.98% 3,4-a']dinaphthalen-4-yl)dimethylamine, min. 98% N,N,2,6-Tetramethyldinaphtho-[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine (11bS)-N,N,2,6-tetraMethyl-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-aMine 3,4-a']dinaphthalen-4-yl)dimethylamine,98% (11bS)-N,N,2,6-Tetramethyl-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine,99%e.e. (S)-(+)-(2,6-Dimethyl-3,5-dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)dimethylamine, min. 98% (S)-(+)-(2,6-DIMETHYL-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A;3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE,MIN.98% Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine, N,N,2,6-tetramethyl-, (11bS)- (S)-(+)-(2,6-DIMETHYL-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE 3,4-a'']dinaphthalen-4-yl)dimethylamine (11bS)-N,N,2,6-Tetramethyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine 185449-86-9 C24H22NO2P Chiral Phosphine CPN