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ChemicalBook >> CAS DataBase List >> TRIS(N N-BIS(TRIMETHYLSILYL)AMIDE)GADO&

TRIS(N N-BIS(TRIMETHYLSILYL)AMIDE)GADO&

TRIS(N N-BIS(TRIMETHYLSILYL)AMIDE)GADO& price.
  • $103 - $386
  • Product name: TRIS(N N-BIS(TRIMETHYLSILYL)AMIDE)GADO&
  • CAS: 35789-03-8
  • MF: C18H54GdN3Si6
  • MW: 638.412
  • EINECS:
  • MDL Number:MFCD03427091
  • Synonyms:TrisN,N-bis(trimethylsilyl)amideügadolinium(III), 98%;TRIS(N N-BIS(TRIMETHYLSILYL)AMIDE)GADO&;GADOLINIUM TRIS(HEXAMETHYLDISILAZIDE);Bis(trimethylsilyl)azanide,gadolinium(3+);Gadolinium bis(trimethylsilyl)amide;Tris[N,N-Bis(trimethylsilyl)amide]gadolinium(III)
Price1 Properties Safety Information Description
1 prices
Selected condition：
Brand
  • Sigma-Aldrich
Package
  • 1g
  • ManufacturerSigma-Aldrich
  • Product number547824
  • Product descriptionTris[N,N-Bis(trimethylsilyl)amide]gadolinium(III) 98%
  • Packaging1g
  • Price$155
  • Updated2023-06-20
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich 547824 Tris[N,N-Bis(trimethylsilyl)amide]gadolinium(III) 98% 1g $155 2023-06-20 Buy

Properties

Melting point :67-90 °C(lit.)
Flash point :36 °F
form :solid
Water Solubility :Soluble in water.
Sensitive :Moisture Sensitive
Hydrolytic Sensitivity :8: reacts rapidly with moisture, water, protic solvents
InChI :1S/3C6H18NSi2.Gd/c3*1-8(2,3)7-9(4,5)6;/h3*1-6H3;/q3*-1;+3
InChIKey :LFWPRLGQJJEPDP-UHFFFAOYSA-N
SMILES :C[Si](C)(C)N([Gd](N([Si](C)(C)C)[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)[Si](C)(C)C

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H228 Flammable solid Flammable solids Category 1
Category 2		 Danger
Warning		 GHS hazard pictograms P210, P240,P241, P280, P370+P378
H261 In contact with water releases flammable gas Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases Category 2
Category 3		 Danger
Warning		 GHS hazard pictograms P231+P232, P280, P370+P378,P402+P404, P501
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P231+P232 Handle under inert gas. Protect from moisture.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

Tris[N,N-bis(trimethylsilyl)amide]gadolinium(III) is used in many asymmetric catalysis applications, glove box and Schlenk techniques should be employed to prevent exposure of the rare earth catalyst to air and moisture, which can be detrimental to the reaction outcome.

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