(S)-(+)-(8,9,10,11,12,13,14,15-Octahydro-3,5-dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)dimethylamine
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- $45 - $2240
- Product name: (S)-(+)-(8,9,10,11,12,13,14,15-Octahydro-3,5-dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)dimethylamine
- CAS: 389130-06-7
- MF: C22H26NO2P
- MW: 367.42
- EINECS:
- MDL Number:MFCD04117692
- Synonyms:(S)-(+)-(8,9,10,11,12,13,14,15-Octahydro-3,5-dioxa-4-phosphacyclohepta[2.1-a.3.4-a']dinaphthalen-4-yl)dimethylamine;(S)-(+)-(8,9,10,11,12,13,14,15-Octahydro-3,5-dioxa-4-phospha-cyclohepta[2,1-a;3,4-a']dinaphthalen-4-yl)dimethylamine,99%;(11bS)-N,N-dimethyl-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1μ,2μ-f][1,3,2]dioxaphosphepin-4-amine;(S)-N,N-Dimethyl-8,9,10,11,12,13,14,15-octahydrodinaphtho-[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4;(11bS)-8,9,10,11,12,13,14,15-octahydro-N,N-diMethyl-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-aMine;MonoPhos Ligand;(S)-(+)-N,N-Dimethyl(8,9,10,11,12,13,14,15-Octahydro-3,5-Dioxa-4-Phospha-Cyclohe
29 prices
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Brand
- aablocks
- ACHEMBLOCK
- AK Scientific
- Alichem
- Ambeed
- American Custom Chemicals Corporation
- Biosynth
- Crysdot
- Matrix Scientific
- Sigma-Aldrich
- Strem Chemicals
- TRC
Package
- 10mg
- 50mg
- 100mg
- 250.00mg
- 250mg
- 500mg
- 1G
- 1.00g
- 1000mg
- 5G
- Manufactureraablocks
- Product numberAA003BC6
- Product description(S)-N,N-Dimethyl-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine 98%99%ee
- Packaging100mg
- Price$49
- Updated2026-05-28
- Buy
- Manufactureraablocks
- Product numberAA003BC6
- Product description(S)-N,N-Dimethyl-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine 98%99%ee
- Packaging250mg
- Price$100
- Updated2026-05-28
- Buy
- ManufacturerACHEMBLOCK
- Product numberAD244351
- Product description(S)-N,N-Dimethyl-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine 98%
- Packaging250MG
- Price$175
- Updated2026-05-27
- Buy
- ManufacturerACHEMBLOCK
- Product numberAD244351
- Product description(S)-N,N-Dimethyl-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine 98%
- Packaging1G
- Price$560
- Updated2026-05-27
- Buy
- ManufacturerACHEMBLOCK
- Product numberAD244351
- Product description(S)-N,N-Dimethyl-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine 98%
- Packaging5G
- Price$2240
- Updated2026-05-27
- Buy
- ManufacturerAK Scientific
- Product number5047AB
- Product description(S)-N,N-Dimethyl-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
- Packaging1g
- Price$1366
- Updated2021-12-16
- Buy
- ManufacturerAlichem
- Product number389130067
- Product description(S)-N,N-Dimethyl-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
- Packaging1g
- Price$394.32
- Updated2021-12-16
- Buy
- ManufacturerAmbeed
- Product numberA264873
- Product description(S)-N,N-Dimethyl-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine 98%99%ee
- Packaging500mg
- Price$348
- Updated2021-12-16
- Buy
- ManufacturerAmbeed
- Product numberA264873
- Product description(S)-N,N-Dimethyl-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine 98%99%ee
- Packaging1g
- Price$378
- Updated2021-12-16
- Buy
- ManufacturerAmbeed
- Product numberA264873
- Product description(S)-N,N-Dimethyl-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine 98%99%ee
- Packaging250mg
- Price$119
- Updated2021-12-16
- Buy
- ManufacturerAmbeed
- Product numberA264873
- Product description(S)-N,N-Dimethyl-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine 98%99%ee
- Packaging100mg
- Price$58
- Updated2021-12-16
- Buy
- ManufacturerAmerican Custom Chemicals Corporation
- Product numberCHM0004995
- Product description(S)-(+)-(8,9,10,11,12,13,14,15-OCTAHYDRO-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE 95.00%
- Packaging100MG
- Price$646.28
- Updated2021-12-16
- Buy
- ManufacturerAmerican Custom Chemicals Corporation
- Product numberCHM0004995
- Product description(S)-(+)-(8,9,10,11,12,13,14,15-OCTAHYDRO-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE 95.00%
- Packaging500MG
- Price$947.76
- Updated2021-12-16
- Buy
- ManufacturerBiosynth
- Product numberFD163891
- Product description(11bS)-N,N-Dimethyl-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
- Packaging1000mg
- Price$910
- Updated2026-06-04
- Buy
- ManufacturerBiosynth
- Product numberFD163891
- Product description(11bS)-N,N-Dimethyl-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
- Packaging500mg
- Price$580
- Updated2026-06-04
- Buy
- ManufacturerBiosynth
- Product numberFD163891
- Product description(11bS)-N,N-Dimethyl-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-amine
- Packaging1g
- Price$500
- Updated2021-12-16
- Buy
| Manufacturer | Product number | Product description | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|
| aablocks | AA003BC6 | (S)-N,N-Dimethyl-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine 98%99%ee | 100mg | $49 | 2026-05-28 | Buy |
| aablocks | AA003BC6 | (S)-N,N-Dimethyl-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine 98%99%ee | 250mg | $100 | 2026-05-28 | Buy |
| ACHEMBLOCK | AD244351 | (S)-N,N-Dimethyl-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine 98% | 250MG | $175 | 2026-05-27 | Buy |
| ACHEMBLOCK | AD244351 | (S)-N,N-Dimethyl-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine 98% | 1G | $560 | 2026-05-27 | Buy |
| ACHEMBLOCK | AD244351 | (S)-N,N-Dimethyl-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine 98% | 5G | $2240 | 2026-05-27 | Buy |
| AK Scientific | 5047AB | (S)-N,N-Dimethyl-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine | 1g | $1366 | 2021-12-16 | Buy |
| Alichem | 389130067 | (S)-N,N-Dimethyl-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine | 1g | $394.32 | 2021-12-16 | Buy |
| Ambeed | A264873 | (S)-N,N-Dimethyl-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine 98%99%ee | 500mg | $348 | 2021-12-16 | Buy |
| Ambeed | A264873 | (S)-N,N-Dimethyl-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine 98%99%ee | 1g | $378 | 2021-12-16 | Buy |
| Ambeed | A264873 | (S)-N,N-Dimethyl-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine 98%99%ee | 250mg | $119 | 2021-12-16 | Buy |
| Ambeed | A264873 | (S)-N,N-Dimethyl-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine 98%99%ee | 100mg | $58 | 2021-12-16 | Buy |
| American Custom Chemicals Corporation | CHM0004995 | (S)-(+)-(8,9,10,11,12,13,14,15-OCTAHYDRO-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE 95.00% | 100MG | $646.28 | 2021-12-16 | Buy |
| American Custom Chemicals Corporation | CHM0004995 | (S)-(+)-(8,9,10,11,12,13,14,15-OCTAHYDRO-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE 95.00% | 500MG | $947.76 | 2021-12-16 | Buy |
| Biosynth | FD163891 | (11bS)-N,N-Dimethyl-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine | 1000mg | $910 | 2026-06-04 | Buy |
| Biosynth | FD163891 | (11bS)-N,N-Dimethyl-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine | 500mg | $580 | 2026-06-04 | Buy |
| Biosynth | FD163891 | (11bS)-N,N-Dimethyl-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-amine | 1g | $500 | 2021-12-16 | Buy |
Properties
Melting point :112-113°C
alpha :+318° (c 0.63, THF)
Boiling point :523.3±60.0 °C(Predicted)
storage temp. :under inert gas (nitrogen or Argon) at 2-8°C
pka :2.15±0.20(Predicted)
form :Powder
color :white
optical activity :[α]22/D 282.0°, c = 1 in chloroform
Sensitive :moisture sensitive, store cold
InChI :1S/C22H26NO2P/c1-23(2)26-24-19-13-11-15-7-3-5-9-17(15)21(19)22-18-10-6-4-8-16(18)12-14-20(22)25-26/h11-14H,3-10H2,1-2H3
InChIKey :OIZQADYWBXZQKE-UHFFFAOYSA-N
SMILES :CN(C)P1Oc2ccc3CCCCc3c2-c4c(O1)ccc5CCCCc45
CAS DataBase Reference :389130-06-7
alpha :+318° (c 0.63, THF)
Boiling point :523.3±60.0 °C(Predicted)
storage temp. :under inert gas (nitrogen or Argon) at 2-8°C
pka :2.15±0.20(Predicted)
form :Powder
color :white
optical activity :[α]22/D 282.0°, c = 1 in chloroform
Sensitive :moisture sensitive, store cold
InChI :1S/C22H26NO2P/c1-23(2)26-24-19-13-11-15-7-3-5-9-17(15)21(19)22-18-10-6-4-8-16(18)12-14-20(22)25-26/h11-14H,3-10H2,1-2H3
InChIKey :OIZQADYWBXZQKE-UHFFFAOYSA-N
SMILES :CN(C)P1Oc2ccc3CCCCc3c2-c4c(O1)ccc5CCCCc45
CAS DataBase Reference :389130-06-7
Safety Information
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Description
(11bS)-N,N-dimethyl-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-amine is a monodentate phosphoramidite (MonoPhos) chiral ligand that can be used:- In the Cu-catalyzed synthesis of chiral 3-(arylbut-1-yn-1-yl)silane derivatives by reacting N-tosylhydrazones with silyl-substituted alkynes via asymmetric insertion.
- In the Rh-catalyzed asymmetric hydrogenation of R-isopropylcinnamic acid derivative, a key intermediate of renin inhibitor aliskiren.
- In the Rh-catalyzed conjugate addition of arylboronic acids to lactones, enones, and nitroalkenes.
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