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(S)-(+)-(8,9,10,11,12,13,14,15-OCTAHYDRO-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE Suppliers list
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| Company Name: |
Shanghai Daken Advanced Materials Co.,Ltd |
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+86-371-66670886 |
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info@dakenam.com |
| Products Intro: |
Product Name:(S)-(+)-(8,9,10,11,12,13,14,15-OCTAHYDRO-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE
CAS:389130-06-7
Purity:99% Package:100g ;1KG ;5KG 25KG
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| Company Name: |
Henan Tianfu Chemical Co.,Ltd. |
| Tel: |
+86-0371-55170693 +86-19937530512 |
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info@tianfuchem.com |
| Products Intro: |
Product Name:(S)-(+)-(8,9,10,11,12,13,14,15-OCTAHYDRO-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE
CAS:389130-06-7
Purity:99% Package:25KG;5KG;1KG
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| Company Name: |
Alchem Pharmtech,Inc. |
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8485655694 |
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sales@alchempharmtech.com |
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Product Name:(S)-N,N-Dimethyl-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
CAS:389130-06-7
Purity:97+% Package:1g;10g;100g;;1kg Remarks:Z-19252
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| Company Name: |
Shaoxin Catsyn Co., Ltd. |
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+undefined-0575-82040869 +86-0575-82040869; |
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sales@catsyn.com |
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Product Name:(S)-(+)-(8,9,10,11,12,13,14,15-Octahydro-3,5-dioxa-4-phospha-cyclohepta[2,1-a;3,4-a']dinaphthalen-4-yl)dimethylamine
CAS:389130-06-7
Purity:98% Min. Package:1G;1KG;100KG Remarks:SC11378
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| Company Name: |
Qingdao Minzhi Yijie new material Co., LTD |
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+86-13589435123 +86-13589435123 |
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qdmzyj@126.com |
| Products Intro: |
Product Name:(S)-(+)-(8,9,10,11,12,13,14,15-OCTAHYDRO-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE
CAS:389130-06-7
Purity:95% Package:No fixed packaging, according to customer demand
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| | (S)-(+)-(8,9,10,11,12,13,14,15-OCTAHYDRO-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE Basic information | | Reaction |
| Product Name: | (S)-(+)-(8,9,10,11,12,13,14,15-OCTAHYDRO-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE | | Synonyms: | (S)-(+)-(8,9,10,11,12,13,14,15-OCTAHYDRO-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE;(S)-(+)-(8,9,10,11,12,13,14,15-Octahydro-3,5-dioxa-4-phosphacyclohepta[2.1-a.3.4-a']dinaphthalen-4-yl)dimethylamine;(S)-(+)-(8,9,10,11,12,13,14,15-Octahydro-3,5-dioxa-4-phospha-cyclohepta[2,1-a;3,4-a']dinaphthalen-4-yl)dimethylamine,99%;(11bS)-N,N-dimethyl-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1μ,2μ-f][1,3,2]dioxaphosphepin-4-amine;(S)-N,N-Dimethyl-8,9,10,11,12,13,14,15-octahydrodinaphtho-[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4;(11bS)-8,9,10,11,12,13,14,15-octahydro-N,N-diMethyl-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-aMine;MonoPhos Ligand | | CAS: | 389130-06-7 | | MF: | C22H26NO2P | | MW: | 367.42 | | EINECS: | | | Product Categories: | Chiral Phosphine;CPN;Chiral Catalysts, Ligands, and Reagents;DSM MonoPhos Phosphoramidites;Privileged Ligands and Complexes | | Mol File: | 389130-06-7.mol | ![(S)-(+)-(8,9,10,11,12,13,14,15-OCTAHYDRO-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE Structure](CAS/GIF/389130-06-7.gif) |
| | (S)-(+)-(8,9,10,11,12,13,14,15-OCTAHYDRO-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE Chemical Properties |
| Melting point | 112-113°C | | alpha | +318° (c 0.63, THF) | | Boiling point | 523.3±60.0 °C(Predicted) | | storage temp. | under inert gas (nitrogen or Argon) at 2-8°C | | pka | 2.15±0.20(Predicted) | | form | Powder | | color | white | | optical activity | [α]22/D 282.0°, c = 1 in chloroform | | Sensitive | moisture sensitive, store cold | | CAS DataBase Reference | 389130-06-7 |
| | (S)-(+)-(8,9,10,11,12,13,14,15-OCTAHYDRO-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE Usage And Synthesis |
| Reaction | A ligand for enantioselective hydrogenation of prochiral functional olefins.
| | Uses | (11bS)-N,N-dimethyl-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-amine is a monodentate phosphoramidite (MonoPhos) chiral ligand that can be used:
- In the Cu-catalyzed synthesis of chiral 3-(arylbut-1-yn-1-yl)silane derivatives by reacting N-tosylhydrazones with silyl-substituted alkynes via asymmetric insertion.
- In the Rh-catalyzed asymmetric hydrogenation of R-isopropylcinnamic acid derivative, a key intermediate of renin inhibitor aliskiren.
- In the Rh-catalyzed conjugate addition of arylboronic acids to lactones, enones, and nitroalkenes.
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| | (S)-(+)-(8,9,10,11,12,13,14,15-OCTAHYDRO-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE Preparation Products And Raw materials |
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