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ChemicalBook >> CAS DataBase List >> (R)-(-)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE, 95%

(R)-(-)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE, 95%

(R)-(-)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE, 95% price.
  • $56 - $1400
  • Product name: (R)-(-)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE, 95%
  • CAS: 791616-55-2
  • MF: C56H41O4PSi2
  • MW: 865.07
  • EINECS:
  • MDL Number:MFCD09265079
  • Synonyms:(R)-(-)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE, 95%;MacMillan TiPSY catalyst, (11bR)-4-Hydroxy-2,6-bis(triphenylsilyl)dinaphtho-[2,1-d:1μ,2μf]-1,3,2-dioxaphosphepin 4-oxide;(S)-3,3μ-Bis(triphenylsilyl)-1,1μ-binaphthyl-2,2μ-diyl hydrogenphosphate;MacMillan TiPSY catalyst, (11bS)-4-Hydroxy-2,6-bis(triphenylsilyl)dinaphtho-[2,1-d1μ,2μf]-[1,3,2]-dioxaphosphepin 4-oxide;(R)-(-)-3,3'-Bis(triphenylsilyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate 96%;Carreira SALDIPAC Ligand;2,6-bis(triphenylsilyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-ol 4-oxide;(11bS)-4-hydroxy-2,6-bis(triphenylsilyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide
15 prices
Selected condition:
Brand
  • Alichem
  • Ambeed
  • American Custom Chemicals Corporation
  • Biosynth Carbosynth
  • Crysdot
  • Sigma-Aldrich
  • Strem Chemicals
Package
  • 5mg
  • 10mg
  • 25mg
  • 50mg
  • 100mg
  • 250mg
  • 1g
  • 5g
  • ManufacturerAlichem
  • Product number791616552
  • Product description(11bS)-4-Hydroxy-2,6-bis(triphenylsilyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide
  • Packaging1g
  • Price$1029
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA759908
  • Product description(11bR)-4-Hydroxy-2,6-bis(triphenylsilyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 95%
  • Packaging100mg
  • Price$56
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA759908
  • Product description(11bR)-4-Hydroxy-2,6-bis(triphenylsilyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 95%
  • Packaging250mg
  • Price$120
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA759908
  • Product description(11bR)-4-Hydroxy-2,6-bis(triphenylsilyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 95%
  • Packaging1g
  • Price$395
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA759908
  • Product description(11bR)-4-Hydroxy-2,6-bis(triphenylsilyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 95%
  • Packaging5g
  • Price$1400
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberORS0003678
  • Product description(R)-(-)-3,3'-BIS-(TRIPHENYLSILYL)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE 95.00%
  • Packaging100MG
  • Price$431.55
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFB158782
  • Product description(R)-(-)-3,3′-Bis(triphenylsilyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate
  • Packaging5mg
  • Price$65
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFB158782
  • Product description(R)-(-)-3,3′-Bis(triphenylsilyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate
  • Packaging10mg
  • Price$100
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFB158782
  • Product description(R)-(-)-3,3′-Bis(triphenylsilyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate
  • Packaging25mg
  • Price$200
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFB158782
  • Product description(R)-(-)-3,3′-Bis(triphenylsilyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate
  • Packaging50mg
  • Price$320
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFB158782
  • Product description(R)-(-)-3,3′-Bis(triphenylsilyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate
  • Packaging100mg
  • Price$500
  • Updated2021-12-16
  • Buy
  • ManufacturerCrysdot
  • Product numberCD51000429
  • Product description(11bS)-4-Hydroxy-2,6-bis(triphenylsilyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 95+%
  • Packaging1g
  • Price$980
  • Updated2021-12-16
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number674745
  • Product description(R)-(–)-3,3′-Bis(triphenylsilyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate 95%
  • Packaging100mg
  • Price$256.8
  • Updated2024-03-01
  • Buy
  • ManufacturerStrem Chemicals
  • Product number15-0340
  • Product description(R)-(-)-3,3'-Bis(triphenylsilyl)-1,1'-binaphthyl-2,2'-diyl hydrogen phosphate, min. 98% [(R)-TiPSY]
  • Packaging10mg
  • Price$65
  • Updated2024-03-01
  • Buy
  • ManufacturerStrem Chemicals
  • Product number15-0340
  • Product description(R)-(-)-3,3'-Bis(triphenylsilyl)-1,1'-binaphthyl-2,2'-diyl hydrogen phosphate, min. 98% [(R)-TiPSY]
  • Packaging100mg
  • Price$493
  • Updated2024-03-01
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Alichem 791616552 (11bS)-4-Hydroxy-2,6-bis(triphenylsilyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 1g $1029 2021-12-16 Buy
Ambeed A759908 (11bR)-4-Hydroxy-2,6-bis(triphenylsilyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 95% 100mg $56 2021-12-16 Buy
Ambeed A759908 (11bR)-4-Hydroxy-2,6-bis(triphenylsilyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 95% 250mg $120 2021-12-16 Buy
Ambeed A759908 (11bR)-4-Hydroxy-2,6-bis(triphenylsilyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 95% 1g $395 2021-12-16 Buy
Ambeed A759908 (11bR)-4-Hydroxy-2,6-bis(triphenylsilyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 95% 5g $1400 2021-12-16 Buy
American Custom Chemicals Corporation ORS0003678 (R)-(-)-3,3'-BIS-(TRIPHENYLSILYL)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE 95.00% 100MG $431.55 2021-12-16 Buy
Biosynth Carbosynth FB158782 (R)-(-)-3,3′-Bis(triphenylsilyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate 5mg $65 2021-12-16 Buy
Biosynth Carbosynth FB158782 (R)-(-)-3,3′-Bis(triphenylsilyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate 10mg $100 2021-12-16 Buy
Biosynth Carbosynth FB158782 (R)-(-)-3,3′-Bis(triphenylsilyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate 25mg $200 2021-12-16 Buy
Biosynth Carbosynth FB158782 (R)-(-)-3,3′-Bis(triphenylsilyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate 50mg $320 2021-12-16 Buy
Biosynth Carbosynth FB158782 (R)-(-)-3,3′-Bis(triphenylsilyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate 100mg $500 2021-12-16 Buy
Crysdot CD51000429 (11bS)-4-Hydroxy-2,6-bis(triphenylsilyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 95+% 1g $980 2021-12-16 Buy
Sigma-Aldrich 674745 (R)-(–)-3,3′-Bis(triphenylsilyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate 95% 100mg $256.8 2024-03-01 Buy
Strem Chemicals 15-0340 (R)-(-)-3,3'-Bis(triphenylsilyl)-1,1'-binaphthyl-2,2'-diyl hydrogen phosphate, min. 98% [(R)-TiPSY] 10mg $65 2024-03-01 Buy
Strem Chemicals 15-0340 (R)-(-)-3,3'-Bis(triphenylsilyl)-1,1'-binaphthyl-2,2'-diyl hydrogen phosphate, min. 98% [(R)-TiPSY] 100mg $493 2024-03-01 Buy

Properties

Melting point :329-335 °C
alpha :-197° (c=1, CHCl3)
Density :1.32±0.1 g/cm3(Predicted)
storage temp. :Sealed in dry,Room Temperature
pka :1.17±0.20(Predicted)
form :Powder
color :white to light-yellow
optical activity :[α]22/D -197°, c = 1 in chloroform

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

Organocatalyst for the first enatioselective organocatalytic reductive amination reaction.