Chinese Japanese Germany Korea
ChemicalBook >> CAS DataBase List >>(R)-(-)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE, 95%

(R)-(-)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE, 95%

(R)-(-)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE, 95% Structure
(R)-(-)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE, 95% structure
CAS No.
791616-55-2
Chemical Name:
(R)-(-)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE, 95%
Synonyms
)-3，3′(R)-(–-binaphthyl-2，2′-diyl hydrogenphosphate;Carreira SALDIPAC Ligand;-Bis(triphenylsilyl)-1，1′(S)-3,3μ-Bis(triphenylsilyl)-1,1μ-binaphthyl-2,2μ-diyl hydrogenphosphate;(R)-(-)-3,3'Bis(triphenylsilyl)-1,1'binaphthyl-2,2'diyl hydrogenphosphaste;(R)-(-)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BINAPHTHYL-2,2'-DIYLHYDROGENPHOSPHATE,95%;(R)-(-)-3,3'-Bis(triphenylsilyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate 96%
CBNumber:
CB7972898
Molecular Formula:
C56H41O4PSi2
Molecular Weight:
865.07
MDL Number:
MFCD09265079
MOL File:
791616-55-2.mol
MSDS File:
SDS
Last updated:2023-04-23 13:52:06
Request For Quotation

(R)-(-)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE, 95% Properties

Melting point 329-335 °C
alpha -197° (c=1, CHCl3)
Density 1.32±0.1 g/cm3(Predicted)
storage temp. Sealed in dry,Room Temperature
pka 1.17±0.20(Predicted)
form Powder
color white to light-yellow
optical activity [α]22/D -197°, c = 1 in chloroform

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36/37
WGK Germany  3
HS Code  29319090

(R)-(-)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE, 95% price More Price(15)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 674745 (R)-(–)-3,3′-Bis(triphenylsilyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate 95% 791616-55-2 100mg $256.8 2024-03-01 Buy
Strem Chemicals 15-0340 (R)-(-)-3,3'-Bis(triphenylsilyl)-1,1'-binaphthyl-2,2'-diyl hydrogen phosphate, min. 98% [(R)-TiPSY] 791616-55-2 10mg $65 2024-03-01 Buy
Strem Chemicals 15-0340 (R)-(-)-3,3'-Bis(triphenylsilyl)-1,1'-binaphthyl-2,2'-diyl hydrogen phosphate, min. 98% [(R)-TiPSY] 791616-55-2 100mg $493 2024-03-01 Buy
Biosynth Carbosynth FB158782 (R)-(-)-3,3′-Bis(triphenylsilyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate 791616-55-2 100mg $500 2021-12-16 Buy
Biosynth Carbosynth FB158782 (R)-(-)-3,3′-Bis(triphenylsilyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate 791616-55-2 10mg $100 2021-12-16 Buy
Product number Packaging Price Buy
674745 100mg $256.8 Buy
15-0340 10mg $65 Buy
15-0340 100mg $493 Buy
FB158782 100mg $500 Buy
FB158782 10mg $100 Buy

(R)-(-)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE, 95% Chemical Properties,Uses,Production

Reaction

  1. A chiral phosphoric acid catalyst providing a convenient strategy for the enantioselective construction of protected primary amines and a highly stereoselective method for the reductive amination of heterocyclic amines.
  2. Chiral phosphoric acid used for the enantioselective Biginelli and Biginelli-like reactions.
  3. Chiral phosphoric acid organocatalyst used in the asymmetric, three-component Povarov reaction involving 2-hydroxystyrenes. An efficient method to access structurally diverse cis-disubstituted tetrahydroquinolines in high stereoselectivities of up to >99:1 dr and 97% ee.
  4. A gold/chiral phosphoric acid catalyst used for the highly stereoselective, three-component reaction of salicylaldehydes, anilines, and alkynols to give aromatic spiroacetals in high yields and stereoselectivities.
  5. The first highly enantioselective catalytic protocol for the reductive coupling of ketones and hydrozones.
  6. Reagent-controlled regioselectivity enabled by dual activation.
Reactions of 791616-55-2_1
Reactions of 791616-55-2_2
Reactions of 791616-55-2_3

Chemical Properties

Solid

Uses

Organocatalyst for the first enatioselective organocatalytic reductive amination reaction.

(R)-(-)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE, 95% Preparation Products And Raw materials

Raw materials

Preparation Products

(R)-(-)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE, 95% Suppliers

Global( 53)Suppliers
Supplier Tel Email Country ProdList Advantage
Shanghai Daken Advanced Materials Co.,Ltd 		+86-371-66670886 info@dakenam.com China 15932 58
Zhengzhou Alfa Chemical Co.,Ltd 		+8618530059196 sale04@alfachem.cn China 12568 58
Career Henan Chemica Co 		+86-0371-86658258 15093356674; laboratory@coreychem.com China 30255 58
Finetech Industry Limited 		+86-27-87465837 +8618971612321 info@finetechnology-ind.com China 9633 58
CD Chemical Group Limited 		+8615986615575 info@codchem.com China 20356 58
Hangzhou MolCore BioPharmatech Co.,Ltd. 		+86-057181025280; +8617767106207 sales@molcore.com China 49739 58
Hu Bei Jiutian Bio-medical Technology CO.,Ltd 		027-88013699 17354350817 Ryan@jiutian-bio.com China 7433 58
LEAPCHEM CO., LTD. 		+86-852-30606658 market18@leapchem.com China 43348 58
Aladdin Scientific 		+1-833-552-7181 sales@aladdinsci.com United States 57511 58
Tianjin Derchemist Science & Technology Co., Ltd. 22-58627059 13920586291 zdcomcon@126.com China 2918 50
Supplier Advantage
Shanghai Daken Advanced Materials Co.,Ltd 		58
Zhengzhou Alfa Chemical Co.,Ltd 		58
Career Henan Chemica Co 		58
Finetech Industry Limited 		58
CD Chemical Group Limited 		58
Hangzhou MolCore BioPharmatech Co.,Ltd. 		58
Hu Bei Jiutian Bio-medical Technology CO.,Ltd 		58
LEAPCHEM CO., LTD. 		58
Aladdin Scientific 		58
Tianjin Derchemist Science & Technology Co., Ltd. 50

View Lastest Price from (R)-(-)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE, 95% manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
(R)-(–)-3,3′-Bis(triphenylsilyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate pictures 2021-07-02 (R)-(–)-3,3′-Bis(triphenylsilyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate
791616-55-2
 US $15.00-10.00 / KG 1KG 99%+ HPLC Monthly supply of 1 ton Zhuozhou Wenxi import and Export Co., Ltd

791616-55-2((R)-(-)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE, 95%)Related Search:

(11bR)-2,6-Di-9-anthracenyl-4-hydroxy-dinaphtho[2,1-d:1μ,2μ-f][1,3,2]dioxaphosphepin-4-oxide R-4-oxide-4-hydroxy-2,6-bis(4-nitrophenyl)- Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin (11bR)-2,6-Di-1-pyrenyl-4-hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin R-4-oxide-4-hydroxy-2,6-di-1-naphthalenyl-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin (R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH&
R-3,3'-Bis(phenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate (11bR)-4-Hydroxy-2,6-bis[2,3,4,5,6-pentafluorophenyl]-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin R-4-oxide-4-hydroxy-2,6-di-2-naphthalenyl-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin R- 4-oxide-2,6-bis([1,1'-biphenyl]-4-yl)-4-hydroxy-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin (11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide
1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate Tetraphenylsilane (R)-(+)-1,1'-Bi-2-naphthol Triphenylsilane (R)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BI-2-&
2,2'-BIPHENYLDIOL, CYCLIC PHOSPHATE (R)-(-)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE, 95% o-(Trimethylsilyl)phenol

1of4

(R)-(-)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE, 95% MacMillan TiPSY catalyst, (11bR)-4-Hydroxy-2,6-bis(triphenylsilyl)dinaphtho-[2,1-d:1μ,2μf]-1,3,2-dioxaphosphepin 4-oxide (S)-3,3μ-Bis(triphenylsilyl)-1,1μ-binaphthyl-2,2μ-diyl hydrogenphosphate MacMillan TiPSY catalyst, (11bS)-4-Hydroxy-2,6-bis(triphenylsilyl)dinaphtho-[2,1-d1μ,2μf]-[1,3,2]-dioxaphosphepin 4-oxide (R)-(-)-3,3'-Bis(triphenylsilyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate 96% Carreira SALDIPAC Ligand 2,6-bis(triphenylsilyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-ol 4-oxide (11bS)-4-hydroxy-2,6-bis(triphenylsilyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide (R)-(-)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BINAPHTHYL-2,2'-DIYLHYDROGENPHOSPHATE,MIN.98%[(R)-TIPSY] (R)-3,3'-Bis(triphenylsilyl)-1,1'-binaphthyl-2,2'-diyl Hydrogen Phosphate,99%e.e. (R)-(-)-3,3'Bis(triphenylsilyl)-1,1'binaphthyl-2,2'diyl hydrogenphosphaste (R)-(-)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BINAPHTHYL-2,2'-DIYLHYDROGENPHOSPHATE,95% (11bR)-4-Hydroxy-2,6-bis(triphenylsilyl)-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin (11bR)-2,6-Bis(triphenylsilyl)-4-hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 4-hydroxy-2,6-bis(triphenylsilyl)-, 4-oxide, (11bR)- (11bR)-4-Hydroxy-2,6-bis(triphenylsilyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide 4-hydroxy-2,6-bis(triphenylsilyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide (R)-(– )-3，3′ -binaphthyl-2，2′ -Bis(triphenylsilyl)-1，1′ -diyl hydrogenphosphate (R)-(-)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE, 95% (R)-(-)-3,3''-Bis(triphenylsilyl)-1,1''-binaphthyl-2,2''-diyl hydrogen phosphate (11bR)-4-Hydroxy-2,6-bis(triphenylsilyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide 791616-55-2 C56H41O4PSi2