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ChemicalBook >> CAS DataBase List >> 1,3-Bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene[2-(i-propoxy)-5-(N,N-dimethylaminosulfonyl)phenyl]methyleneruthenium(II)dichloride

1,3-Bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene[2-(i-propoxy)-5-(N,N-dimethylaminosulfonyl)phenyl]methyleneruthenium(II)dichloride

1,3-Bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene[2-(i-propoxy)-5-(N,N-dimethylaminosulfonyl)phenyl]methyleneruthenium(II)dichloride price.
  • $44 - $2116
  • Product name: 1,3-Bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene[2-(i-propoxy)-5-(N,N-dimethylaminosulfonyl)phenyl]methyleneruthenium(II)dichloride
  • CAS: 918870-76-5
  • MF: C33H42Cl2N3O3RuS
  • MW: 732.75
  • EINECS:
  • MDL Number:MFCD08459353
  • Synonyms:Dichloro[1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene][[5-[(dimethylamino)sulfonyl]-2-(1-methylethoxy-O)phenyl]methylene-C]ruthenium(II);Dichloro(1,3-dimesityl-2-imidazolidinylidene)[5-(dimethylsulfamoyl)-2-isopropoxybenzylidene]ruthenium;1,3-Bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene[2-(i-propoxy)-5-(N,N-dimethylaminosulfonyl)phenyl]methyleneruthenium(II)dichloride;RUTHENIUM, [1,3-BIS(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE]DICHLORO-[[2-ISOPROPOXY-5-(N-DIMETHYLAMINOSULFONYL)PHENYL]METHYLENE];1,3-Bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene[2-(i-propoxy)-5-(N,
    N-dimethylaminosulfonyl)phenyl]methyleneruthenium (II) dichloride Zhan Catalyst-1B;1,3-BIS(2,4,6-TRIMETHYLPHENYL)-4,5-DIHYDROIMIDAZOL-2-YLIDENE[2-(I-PROPOXY)-5-(N,N-DIMETHYLAMINOSULFONYL)PHENYL]METHYLENERUTHENIUM(II)DICHLORIDE,ZHANCATALYST-1B,MIN96%;1,3-Bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene[2-(i-propoxy)-5-(N,N-dimethylaminosulfonyl)phenyl]methyleneruthenium (II) dichloride, Zhan Catalyst-1B, min 96%;[1,3-bis(2,4,6-trimethylphenyl)imidazolidin-2-ylidene]-dichloro-[[5-(dimethylsulfamoyl)-2-propan-2-yloxyphenyl]methylidene]ruthenium
8 prices
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Brand
  • American Custom Chemicals Corporation
  • Chemenu
  • Sigma-Aldrich
  • Strem Chemicals
Package
  • 5MG
  • 100mg
  • 500mg
  • 2g
  • 10g
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberCHM0377483
  • Product description1,3-BIS-(2,4,6-TRIMETHYLPHENYL)-4,5-DIHYDROIMIDAZOL-2-YLIDENE-[2-(I-PROPOXY)-5-(N,N-DIMETHYLAMINOSULFONYL)PHENYL]METHYLENERUTHENIUM-(II)-DICHLORIDE 95.00%
  • Packaging5MG
  • Price$502.56
  • Updated2021-12-16
  • Buy
  • ManufacturerChemenu
  • Product numberCM328523
  • Product description[1,3-bis(2,4,6-trimethylphenyl)imidazolidin-2-ylidene]-dichloro-[[5-(dimethylsulfamoyl)-2-propan-2-yloxyphenyl]methylidene]ruthenium 95%+
  • Packaging10g
  • Price$2116
  • Updated2021-12-16
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number762261
  • Product descriptionDichloro[1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene][[5-[(dimethylamino)sulfonyl]-2-(1-methylethoxy-O)phenyl]methylene-C]ruthenium(II)
  • Packaging100mg
  • Price$69.7
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number762261
  • Product descriptionDichloro[1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene][[5-[(dimethylamino)sulfonyl]-2-(1-methylethoxy-O)phenyl]methylene-C]ruthenium(II)
  • Packaging500mg
  • Price$194
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number762261
  • Product descriptionDichloro[1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene][[5-[(dimethylamino)sulfonyl]-2-(1-methylethoxy-O)phenyl]methylene-C]ruthenium(II)
  • Packaging2g
  • Price$583
  • Updated2024-03-01
  • Buy
  • ManufacturerStrem Chemicals
  • Product number44-0082
  • Product description1,3-Bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene[2-(i-propoxy)-5-(N,N-dimethylaminosulfonyl)phenyl]methyleneruthenium (II) dichloride, Zhan Catalyst-1B, min 96%
  • Packaging100mg
  • Price$44
  • Updated2024-03-01
  • Buy
  • ManufacturerStrem Chemicals
  • Product number44-0082
  • Product description1,3-Bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene[2-(i-propoxy)-5-(N,N-dimethylaminosulfonyl)phenyl]methyleneruthenium (II) dichloride, Zhan Catalyst-1B, min 96%
  • Packaging500mg
  • Price$177
  • Updated2024-03-01
  • Buy
  • ManufacturerStrem Chemicals
  • Product number44-0082
  • Product description1,3-Bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene[2-(i-propoxy)-5-(N,N-dimethylaminosulfonyl)phenyl]methyleneruthenium (II) dichloride, Zhan Catalyst-1B, min 96%
  • Packaging2g
  • Price$550
  • Updated2024-03-01
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
American Custom Chemicals Corporation CHM0377483 1,3-BIS-(2,4,6-TRIMETHYLPHENYL)-4,5-DIHYDROIMIDAZOL-2-YLIDENE-[2-(I-PROPOXY)-5-(N,N-DIMETHYLAMINOSULFONYL)PHENYL]METHYLENERUTHENIUM-(II)-DICHLORIDE 95.00% 5MG $502.56 2021-12-16 Buy
Chemenu CM328523 [1,3-bis(2,4,6-trimethylphenyl)imidazolidin-2-ylidene]-dichloro-[[5-(dimethylsulfamoyl)-2-propan-2-yloxyphenyl]methylidene]ruthenium 95%+ 10g $2116 2021-12-16 Buy
Sigma-Aldrich 762261 Dichloro[1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene][[5-[(dimethylamino)sulfonyl]-2-(1-methylethoxy-O)phenyl]methylene-C]ruthenium(II) 100mg $69.7 2024-03-01 Buy
Sigma-Aldrich 762261 Dichloro[1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene][[5-[(dimethylamino)sulfonyl]-2-(1-methylethoxy-O)phenyl]methylene-C]ruthenium(II) 500mg $194 2024-03-01 Buy
Sigma-Aldrich 762261 Dichloro[1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene][[5-[(dimethylamino)sulfonyl]-2-(1-methylethoxy-O)phenyl]methylene-C]ruthenium(II) 2g $583 2024-03-01 Buy
Strem Chemicals 44-0082 1,3-Bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene[2-(i-propoxy)-5-(N,N-dimethylaminosulfonyl)phenyl]methyleneruthenium (II) dichloride, Zhan Catalyst-1B, min 96% 100mg $44 2024-03-01 Buy
Strem Chemicals 44-0082 1,3-Bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene[2-(i-propoxy)-5-(N,N-dimethylaminosulfonyl)phenyl]methyleneruthenium (II) dichloride, Zhan Catalyst-1B, min 96% 500mg $177 2024-03-01 Buy
Strem Chemicals 44-0082 1,3-Bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene[2-(i-propoxy)-5-(N,N-dimethylaminosulfonyl)phenyl]methyleneruthenium (II) dichloride, Zhan Catalyst-1B, min 96% 2g $550 2024-03-01 Buy

Properties

form :solid
color :green
InChIKey :JIZPWEVWTYCVNK-UHFFFAOYSA-L
SMILES :[Cl-][Ru+6]1(=[C-2]C2=CC(S(=O)(=O)N(C)C)=CC=C2O1C(C)C)(=[C-2]1N(C2C(=CC(C)=CC=2C)C)CCN1C1C(=CC(C)=CC=1C)C)[Cl-]

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

Zhan Catalyst-1B (Hoveyda-Grubbs type catalyst) can be used:
  • In the preparation of hybrid olefin metathesis catalysts, with increased catalytic activity via immobilization on molecular seives. supports
  • As a catalyst in the synthesis of divergent dendrimer
  • In ring-closure metathesis (RCM) reaction.


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