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ChemicalBook >> CAS DataBase List >> Trimethyl borate

Trimethyl borate

Trimethyl borate price.
  • $15 - $399
  • Product name: Trimethyl borate
  • CAS: 121-43-7
  • MF: C3H9BO3
  • MW: 103.91
  • EINECS:204-468-9
  • MDL Number:MFCD00008346
  • Synonyms:METHYL BORATE-11B;BORON TRIMETHOXIDE;BORIC ACID TRIMETHYL ESTER;BORON METHOXIDE;TRIMETHYL BORATE;Borester O;borestero ;Boric acid (H3BO3), trimethyl ester
36 prices
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  • AK Scientific
  • Alfa Aesar
  • Oakwood
  • Sigma-Aldrich
  • Strem Chemicals
  • TCI Chemical
  • TRC
  • Usbiological
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  • ManufacturerAK Scientific
  • Product numberA598
  • Product descriptionTrimethyl Borate
  • Packaging25mL
  • Price$21
  • Updated2021-12-16
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberB20215
  • Product descriptionTrimethyl borate, 99%
  • Packaging250ml
  • Price$31.3
  • Updated2023-06-20
  • Buy
  • ManufacturerAlfa Aesar
  • Product number043765
  • Product descriptionTrimethyl borate 99.99% (metals basis)
  • Packaging25g
  • Price$33.65
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product number022975
  • Product descriptionTrimethyl borate 99.9995+% (metals basis)
  • Packaging50g
  • Price$64.65
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberB20215
  • Product descriptionTrimethyl borate, 99%
  • Packaging1000ml
  • Price$87.4
  • Updated2023-06-20
  • Buy
  • ManufacturerAlfa Aesar
  • Product number043765
  • Product descriptionTrimethyl borate 99.99% (metals basis)
  • Packaging100g
  • Price$106.65
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product number022975
  • Product descriptionTrimethyl borate 99.9995+% (metals basis)
  • Packaging250g
  • Price$230.65
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product number043765
  • Product descriptionTrimethyl borate 99.99% (metals basis)
  • Packaging500g
  • Price$378.65
  • Updated2024-03-01
  • Buy
  • ManufacturerOakwood
  • Product number044856
  • Product descriptionTrimethyl Borate
  • Packaging25ml
  • Price$15
  • Updated2021-12-16
  • Buy
  • ManufacturerOakwood
  • Product number044856
  • Product descriptionTrimethyl Borate
  • Packaging500ml
  • Price$40
  • Updated2021-12-16
  • Buy
  • ManufacturerOakwood
  • Product number044856
  • Product descriptionTrimethyl Borate
  • Packaging4L
  • Price$210
  • Updated2021-12-16
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  • ManufacturerSigma-Aldrich
  • Product number447218
  • Product descriptionTrimethyl borate 99.999% (trace metal basis)
  • Packaging100ml
  • Price$39.56
  • Updated2024-03-01
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  • ManufacturerSigma-Aldrich
  • Product number452920
  • Product descriptionTrimethyl borate ≥98%
  • Packaging100ml
  • Price$41.6
  • Updated2024-03-01
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  • ManufacturerSigma-Aldrich
  • Product number92330
  • Product descriptionTrimethyl borate purum, ≥99.0% (GC)
  • Packaging250ml
  • Price$56.8
  • Updated2024-03-01
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  • ManufacturerSigma-Aldrich
  • Product number443999
  • Product descriptionTrimethyl borate purified by redistillation, ≥99.5%
  • Packaging100ml
  • Price$76.6
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number452920
  • Product descriptionTrimethyl borate ≥98%
  • Packaging500ml
  • Price$80.1
  • Updated2024-03-01
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
AK Scientific A598 Trimethyl Borate 25mL $21 2021-12-16 Buy
Alfa Aesar B20215 Trimethyl borate, 99% 250ml $31.3 2023-06-20 Buy
Alfa Aesar 043765 Trimethyl borate 99.99% (metals basis) 25g $33.65 2024-03-01 Buy
Alfa Aesar 022975 Trimethyl borate 99.9995+% (metals basis) 50g $64.65 2024-03-01 Buy
Alfa Aesar B20215 Trimethyl borate, 99% 1000ml $87.4 2023-06-20 Buy
Alfa Aesar 043765 Trimethyl borate 99.99% (metals basis) 100g $106.65 2024-03-01 Buy
Alfa Aesar 022975 Trimethyl borate 99.9995+% (metals basis) 250g $230.65 2024-03-01 Buy
Alfa Aesar 043765 Trimethyl borate 99.99% (metals basis) 500g $378.65 2024-03-01 Buy
Oakwood 044856 Trimethyl Borate 25ml $15 2021-12-16 Buy
Oakwood 044856 Trimethyl Borate 500ml $40 2021-12-16 Buy
Oakwood 044856 Trimethyl Borate 4L $210 2021-12-16 Buy
Sigma-Aldrich 447218 Trimethyl borate 99.999% (trace metal basis) 100ml $39.56 2024-03-01 Buy
Sigma-Aldrich 452920 Trimethyl borate ≥98% 100ml $41.6 2024-03-01 Buy
Sigma-Aldrich 92330 Trimethyl borate purum, ≥99.0% (GC) 250ml $56.8 2024-03-01 Buy
Sigma-Aldrich 443999 Trimethyl borate purified by redistillation, ≥99.5% 100ml $76.6 2024-03-01 Buy
Sigma-Aldrich 452920 Trimethyl borate ≥98% 500ml $80.1 2024-03-01 Buy

Properties

Melting point :-34 °C (lit.)
Boiling point :68-69 °C (lit.)
Density :0.932 g/mL at 20 °C (lit.)
vapor density :3.59 (vs air)
refractive index :n20/D 1.358(lit.)
Flash point :8 °F
storage temp. :Store at <= 20°C.
solubility :Miscible with tetrahydrofuran, ether, isoporpylamine, hexane and methanol.
form :Liquid
Specific Gravity :0.915
color :Colorless
Water Solubility :reacts
Sensitive :Moisture Sensitive
Hydrolytic Sensitivity :7: reacts slowly with moisture/water
Merck :14,9712
BRN :1697939
Dielectric constant :8.2(20℃)
Exposure limits :ACGIH: TWA 200 ppm; STEL 250 ppm (Skin)
OSHA: TWA 200 ppm(260 mg/m3)
NIOSH: IDLH 6000 ppm; TWA 200 ppm(260 mg/m3); STEL 250 ppm(325 mg/m3) Stability :Stable. Incompatible with oxidizing agents. Decomposes slowly in the presence of moisture, rapidly in water. Flammable.
InChIKey :WRECIMRULFAWHA-UHFFFAOYSA-N
CAS DataBase Reference :121-43-7(CAS DataBase Reference)
NIST Chemistry Reference :Boric acid, trimethyl ester(121-43-7)
EPA Substance Registry System :Boric acid (H3BO3), trimethyl ester (121-43-7)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger GHS hazard pictograms P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H370 Causes damage to organs Specific target organ toxicity, single exposure Category 1 Danger GHS hazard pictograms P260, P264, P270, P307+P311, P321,P405, P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

Trimethyl borate is a useful reagent in organic synthesis. It is involved in the production of resins, waxes and paints and acts as a methylation agent. As a boron source, it is used to prepare flame retardants, anti-oxidants and corrosion inhibitors. It reacts with Grignard reagents followed by hydrolysis to prepare boronic acid. It is also used as a precursor of borate esters, which finds application in the Suzuki coupling reaction. It is used as neutron detector gas in the presence of a scintillation counter; as a promoter of diborane reactions.

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