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Trimethyl borate

Trimethyl borate
Trimethyl borate structure
CAS No.
121-43-7
Chemical Name:
Trimethyl borate
Synonyms
C3H9BO3;B(OCH3)3;borestero;trimethyl;Borester O;METHYL BORATE;BORON METHOXIDE;Trimthyl borate;Trimethoxyboron;TriMethyl borat
CBNumber:
CB1126251
Molecular Formula:
C3H9BO3
Formula Weight:
103.91
MOL File:
121-43-7.mol

Trimethyl borate Properties

Melting point:
-34 °C (lit.)
Boiling point:
68-69 °C (lit.)
Density 
0.932 g/mL at 20 °C (lit.)
vapor density 
3.59 (vs air)
refractive index 
n20/D 1.358(lit.)
Flash point:
8 °F
storage temp. 
Store at <= 20°C.
solubility 
Miscible with tetrahydrofuran, ether, isoporpylamine, hexane and methanol.
form 
Liquid
color 
Colorless
Specific Gravity
0.915
Specific Gravity
0.883
Water Solubility 
reacts
Sensitive 
Moisture Sensitive
Hydrolytic Sensitivity
7: reacts slowly with moisture/water
Merck 
14,9712
BRN 
1697939
Stability:
Stable. Incompatible with oxidizing agents. Decomposes slowly in the presence of moisture, rapidly in water. Flammable.
InChIKey
WRECIMRULFAWHA-UHFFFAOYSA-N
CAS DataBase Reference
121-43-7(CAS DataBase Reference)
EWG's Food Scores
1
FDA UNII
82U64J6F5N
NIST Chemistry Reference
Boric acid, trimethyl ester(121-43-7)
EPA Substance Registry System
Boric acid (H3BO3), trimethyl ester (121-43-7)
SAFETY
  • Risk and Safety Statements
Symbol(GHS) 
GHS02,GHS07,GHS08,GHS06
Signal word  Danger
Hazard statements  H225-H312-H319-H360FD-H370-H335-H336-H360-H372-H226-H300-H330
Precautionary statements  P301+P310a-P304+P340-P320-P330-P501a-P201-P210-P260-P302+P352+P312-P308+P311-P337+P313-P202-P233-P240-P241+P242+P243-P264-P270-P271-P280-P303+P361+P353-P304+P340+P312-P305+P351+P338+P337+P313-P307+P311-P370+P378-P403+P233-P405-P501-P261-P302+P352+P312+P362+P364-P241
Hazard Codes  Xn,F,T
Risk Statements  11-21-23/25-36/37/38-10-36-61-60
Safety Statements  16-27-36/37/39-45-25-23-2-26-53
RIDADR  UN 2416 3/PG 2
WGK Germany  3
RTECS  ED5600000
21
TSCA  Yes
HazardClass  3
PackingGroup  II
HS Code  29209085
Toxicity LD50 orally in rats: 6.14 ml/kg (Smyth)
NFPA 704
3
1 1

Trimethyl borate price More Price(25)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 443999 Trimethyl borate purified by redistillation, ≥99.5% 121-43-7 100ml $63.3 2021-03-22 Buy
Sigma-Aldrich 443999 Trimethyl borate purified by redistillation, ≥99.5% 121-43-7 1l $228 2021-03-22 Buy
TCI Chemical B0226 Trimethyl Borate (63-65% in Methanol) 121-43-7 25mL $17 2021-03-22 Buy
TCI Chemical B0226 Trimethyl Borate (63-65% in Methanol) 121-43-7 500mL $34 2021-03-22 Buy
Alfa Aesar B20215 Trimethyl borate, 99% 121-43-7 250ml $26.8 2021-03-22 Buy

Trimethyl borate Chemical Properties,Uses,Production

Chemical Properties

Water-white liquid. Miscible with ether, methanol, hexane, tetrahydrofuran; decomposes in presence of water.

Uses

As solvent for waxes, resins, oils; catalyst in the manufacture of ketones; analysis of paint and varnish ingredients; as neutron detector gas in the presence of a scintillation counter; as a promoter of diborane reactions.

Definition

ChEBI: A member of the class of borate esters obtained by the formal condensation of three equivalents of methanol with boric acid.

General Description

A water-white liquid. Denser than water. Flash point 80°F. Vapors heavier than air. Used as a solvent and fungicide for fruit.

Air & Water Reactions

Highly flammable. Rapidly decomposes in water.

Reactivity Profile

Borates, such as Trimethyl borate, behave similarly to esters in that they react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters/borates with alkali metals and hydrides.

Health Hazard

May cause toxic effects if inhaled or absorbed through skin. Inhalation or contact with material may irritate or burn skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.

Fire Hazard

HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.

Safety Profile

Moderately toxic by ingestion, skin contact, and intraperitoneal routes. An eye irritant. A very dangerous fire hazard when exposed to heat, flame, or oxidizers. Moderately explosive when exposed to flame. Will react with water or steam to produce toxic and flammable vapors. To fight fire, use dry chemical, CO2, spray, foam. When heated to decomposition it emits acrid smoke and irritating fumes. See also ESTERS and BORON COMPOUNDS.

Purification Methods

Carefully fractionate the borate through a gauze-packed column. Re-distil and collect it in weighed glass vials and seal them. Keep it away from moisture. It undergoes alkyl exchange with alcohols and forms azeotropes, e.g. with MeOH the azeotrope consists of 70% (MeO)3B and 30% MeOH with b 52-54o/760mm, d 0.87. [Charnley et al. J Chem Soc 2288 1952, Gerrard & Lappert Chem Ind (London) 53 1952, Schlesinger et al. J Am Chem Soc 75 213 1953.] It has also been dried with Na and then distilled. [Beilstein 1 IV 1269.]

Trimethyl borate Preparation Products And Raw materials

Raw materials

Preparation Products


Trimethyl borate Suppliers

Global( 287)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Henan DaKen Chemical CO.,LTD.
+86-371-66670886
info@dakenchem.com China 20914 58
Shanghai Bojing Chemical Co.,Ltd.
+86-21-37122233
+86-21-37127788 Candy@bj-chem.com CHINA 497 55
Henan Tianfu Chemical Co.,Ltd.
0371-55170693
0371-55170693 info@tianfuchem.com CHINA 22607 55
Shanghai Time Chemicals CO., Ltd.
+8618017249410 +86-021-57951555
+86-021-57951555 jack.li@time-chemicals.com CHINA 1365 55
Hefei TNJ Chemical Industry Co.,Ltd.
+86-0551-65418679
86-0551-65418697 info@tnjchem.com China 3000 55
Shanxi Naipu Import and Export Co.,Ltd
+8613734021967
kaia@neputrading.com CHINA 1009 58
career henan chemical co
+86-371-86658258
sales@coreychem.com CHINA 29954 58
Hubei Jusheng Technology Co.,Ltd.
86-18871470254
027-59599243 linda@hubeijusheng.com CHINA 28229 58
Xiamen AmoyChem Co., Ltd
+86 592-605 1114
sales@amoychem.com CHINA 6369 58
Hubei xin bonus chemical co. LTD
86-13657291602
027-59338440 linda@hubeijusheng.com CHINA 23035 58

View Lastest Price from Trimethyl borate manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2021-08-12 Trimethyl borate
121-43-7
US $15.00-10.00 / KG 1KG 99%+ HPLC Monthly supply of 1 ton Zhuozhou Wenxi import and Export Co., Ltd
2021-07-09 Trimethyl borate
121-43-7
1KG 99% 80 Ton/Tons per Month Hebei Xibaijie Biotechnology Co., Ltd.
2021-06-08 Trimethyl borate
121-43-7
US $1.00-10.00 / ASSAYS 10ASSAYS 99% 1000kg/month Shanxi Naipu Import and Export Co.,Ltd

Trimethyl borate Spectrum


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