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Phenethylzinc bromide

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Phenethylzinc bromide Basic information
Product Name:Phenethylzinc bromide
Synonyms:phenethylzinc bromide solution;Phenethylzinc bromide solution 0.5 in THF;PHENETHYLZINC BROMIDE, 0.5M SOLUTION IN;2-Phenylethylzinc broMide, 0.5M in THF, packaged under Argon in resealable CheMSeal^t bottles;Phenethylzinc bromide solution 0.5 M in THF;2-Phenylethylzinc bromide;Phenethylzinc bromide, 0.50 M in THF;2-Phenylethylzinc bromide, Packaged under Argon in resealable ChemSeal? bottles
CAS:308796-14-7
MF:C8H9BrZn
MW:250.45
EINECS:
Product Categories:Chemical Synthesis;Organometallic Reagents;Alkyl;Organozinc Halides;Organozinc Halides;Rieke and Organozinc Reagents;Reike and Organozinc Reagents
Mol File:308796-14-7.mol
Phenethylzinc bromide Structure
Phenethylzinc bromide Chemical Properties
Boiling point 65 °C
density 0.965 g/mL at 25 °C
Fp 1 °F
storage temp. 2-8°C
Water Solubility Reacts with water.
Sensitive Air Sensitive
InChI1S/C8H9.BrH.Zn/c1-2-8-6-4-3-5-7-8;;/h3-7H,1-2H2;1H;/q;;+1/p-1
InChIKeySEXSOTWHLBYVNF-UHFFFAOYSA-M
SMILESBr[Zn]CCc1ccccc1
CAS DataBase Reference308796-14-7
Safety Information
Hazard Codes F,Xn
Risk Statements 14-19-22-36/38-40-36/37-11
Safety Statements 16-26-33-36-36/37
RIDADR UN 2056 3/PG 2
WGK Germany 1
HazardClass 4.3
Storage Class3 - Flammable liquids
Hazard ClassificationsCarc. 2
Eye Irrit. 2
Flam. Liq. 2
STOT SE 3
MSDS Information
ProviderLanguage
SigmaAldrich English
Phenethylzinc bromide Usage And Synthesis
UsesPhenethylzinc bromide can be used as a reagent:
  • In the transition metal-catalyzed Negishi cross-coupling reaction to prepare aryl or heteroaryl derivatives by reacting with organic halides or triflates via carbon-carbon bond formation.
  • To prepare (4-phenyl-1-butyn-1-yl)benzene by reacting with phenylacetylene via palladium-catalyzed cross-coupling reaction.
  • To synthesize benzyl substituted thienopyrimidine derivatives.

Phenethylzinc bromide Preparation Products And Raw materials
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