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(S)-4,4-DIBUTYL-2,6-BIS(3,4,5-TRIFLUOROPHENYL)-4,5-DIHYDRO-3H-DINAPHTHO[7,6,1,2-CDE]AZEPINIUM BROMIDE

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(S)-4,4-DIBUTYL-2,6-BIS(3,4,5-TRIFLUOROPHENYL)-4,5-DIHYDRO-3H-DINAPHTHO[7,6,1,2-CDE]AZEPINIUM BROMIDE Suppliers list
Company Name: Aladdin Scientific
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Products Intro: Product Name:(11bS)-4,4-Dibutyl-2,6-bis(3,4,5-trifluorophenyl)-4,5-dihydro-3H-dinaphtho[2,1-c:1'',2''-e]azepinium bromide
CAS:851942-89-7
Purity:>=98% Package:$276.9/50mg;$1244.9/250mg;Bulk package Remarks:98%
Company Name: J & K SCIENTIFIC LTD.  
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Products Intro: Product Name:(11bS)-4,4-Dibutyl-2,6-bis(3,4,5-trifluorophenyl)-4,5-dihydro-3H-dinaphtho[2,1-c:1',2'-e]azepinium bromide
CAS:851942-89-7
Package:250mg;50mg
Company Name: Tianjin Derchemist Science & Technology Co., Ltd.  
Tel: 22-58627059 13920586291
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Products Intro: Product Name:(11bS)-4,4-Dibutyl-4,5-dihydro-2,6-bis(3,4,5-trifluorophenyl)-3H-dinaphth[2,1-c:1′,2′-e]azepinium bromide
CAS:851942-89-7
Purity:98% Package:1g；5g；10g；25g；50g；100g；500g；1kg；5kg；10kg；25kg
Company Name: Sigma-Aldrich  
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Products Intro: Product Name:(11bS)-(+)-4,4-Dibutyl-4,5-dihydro-2,6-bis(3,4,5-trifluorophenyl)-3H-dinaphth[2,1-c:1',2'-e]azepinium bromide
CAS:851942-89-7
Purity:Nagase purity Package:50MG Remarks:677086-50MG
Company Name: Alfa Chemistry  
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Products Intro: Product Name:(11bS)-4,4-Dibutyl-2,6-bis(3,4,5-trifluorophenyl)-4,5-dihydro-3H-dinaphtho[2,1-c:1',2'-e]azepinium bromide
CAS:851942-89-7
Package:1g;10g;100g;1KG;5KG
(S)-4,4-DIBUTYL-2,6-BIS(3,4,5-TRIFLUOROPHENYL)-4,5-DIHYDRO-3H-DINAPHTHO[7,6,1,2-CDE]AZEPINIUM BROMIDE Basic information
Reaction
Product Name:(S)-4,4-DIBUTYL-2,6-BIS(3,4,5-TRIFLUOROPHENYL)-4,5-DIHYDRO-3H-DINAPHTHO[7,6,1,2-CDE]AZEPINIUM BROMIDE
Synonyms:(S)-4,4-DIBUTYL-2,6-BIS(3,4,5-TRIFLUOROPHENYL)-4,5-DIHYDRO-3H-DINAPHTHO[7,6,1,2-CDE]AZEPINIUM BROMIDE;(S)-4,4-Dibutyl-2,6-bis(3,4,5-trifluorophenyl)-4,5-dihydro-3H-dinaphtho[7,6,1,2-cde]azepiniumbromide;(11bS)-(+)-4,4-Dibutyl-4,5-dihydro-2,6-bis(3,4,5-trifluorophenyl)-3H-dinaphth[2,1-c:1',2'-e]azepinium bromide Nagase purity;(11BS)-4,4-DIBUTYL-2,6-BIS(3,4,5-TRIFLUOROPHENYL)-4,5-DIHYDRO-3H-DINAPHTHO[2,1-C:1',2'-E]AZEPINIUMBROMIDE;(S)-4,4-Dibutyl-2,6-bis(3,4,5-trifluorophenyl)-4,5-dihydro-3H-dinaphtho[2,1-c:1',2'-e]azepiniuM broMide;Reaxys ID: 23187641;13,13-Dibutyl-10,16-bis(3,4,5-trifluorophenyl)-13-azoniapentacyclo[13.8.0.02,11.03,8.018,23]tricosa-1(15),2(11),3,5,7,9,16,18,20,22-decaene;(11bS)-4,4-dibutyl-4,5-dihydro-2,6-bis(3,4,5-trifluorophenyl)-3H-Dinaphth[2,1-c:1,2-e]azepinium brom
CAS:851942-89-7
MF:C42H36F6N.Br
MW:748.645
EINECS:
Product Categories:Asymmetric Synthesis;Chiral Catalysts, Ligands, and Reagents;Phase Transfer Reaction
Mol File:851942-89-7.mol
(S)-4,4-DIBUTYL-2,6-BIS(3,4,5-TRIFLUOROPHENYL)-4,5-DIHYDRO-3H-DINAPHTHO[7,6,1,2-CDE]AZEPINIUM BROMIDE Structure
(S)-4,4-DIBUTYL-2,6-BIS(3,4,5-TRIFLUOROPHENYL)-4,5-DIHYDRO-3H-DINAPHTHO[7,6,1,2-CDE]AZEPINIUM BROMIDE Chemical Properties
Melting point 224-229 °C
form Powder
color brown
CAS DataBase Reference851942-89-7
Safety Information
WGK Germany 3
MSDS Information
(S)-4,4-DIBUTYL-2,6-BIS(3,4,5-TRIFLUOROPHENYL)-4,5-DIHYDRO-3H-DINAPHTHO[7,6,1,2-CDE]AZEPINIUM BROMIDE Usage And Synthesis
Reaction
  1. 2nd Generation Maruoka chiral phase transfer catalyst, for enantioselective alkylation of α-amino acid derivatives, that is easily recovered for recycle by extraction with fluorous solvent.
  2. Catalyst for asymmetric conjugate addition of α-substituted-α-cyanoacetates to α,β-unsaturated acetylenic esters.
  3. Phase transfer catalyzed enantioselective α-alkylation.
  4. Asymmetric amination of β-keto esters.
  5. Diastereo- and enantioselective conjugate addition of α-substituted nitroacetates to maleimides.
  6. Cyclization of β-alkynyl hydrazines.
Reactions of 851942-89-7
Uses(S)-4,4-Dibutyl-2,6-bis(3,4,5-trifluorophenyl)-4,5-dihydro-3H-dinaphtho[2,1-c:1'',2''-e]azepinium Bromide is a chiral phase-transfer catalyst for asymmetrical alkylation of glycine and alanine Schiff bases.
(S)-4,4-DIBUTYL-2,6-BIS(3,4,5-TRIFLUOROPHENYL)-4,5-DIHYDRO-3H-DINAPHTHO[7,6,1,2-CDE]AZEPINIUM BROMIDE Preparation Products And Raw materials
Tag:(S)-4,4-DIBUTYL-2,6-BIS(3,4,5-TRIFLUOROPHENYL)-4,5-DIHYDRO-3H-DINAPHTHO[7,6,1,2-CDE]AZEPINIUM BROMIDE(851942-89-7) Related Product Information
3,3'-DIPHENYLBIPHENYL 2-Methyl-1,1'-binaphthalene (S)-4,4-DIBUTYL-2,6-BIS(3,4,5-TRIFLUOROPHENYL)-4,5-DIHYDRO-3H-DINAPHTHO[7,6,1,2-CDE]AZEPINIUM BROMIDE (4'-FLUORO[1,1'-BIPHENYL]-2-YL)METHANAMINE 5H-Dibenz[c,e]azepine, 6,7-dihydro-