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J & K SCIENTIFIC LTD.
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010-82848833 400-666-7788 |
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jkinfo@jkchemical.com |
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Product Name:(1R,1'R,2S,2'S)-(+)-2,2'-Di-t-butyl-2,3,2',3'-tetrahydro-1,1'-bi-1H-isophosphindole, min. 98% (R,R,S,S)-DUANPHOS CAS:528814-26-8 Purity:min. 98% Package:100mg;500mg
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Energy Chemical
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021-021-58432009 400-005-6266 |
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Products Intro: |
Product Name:(1R,1′R,2S,2′S)-DuanPhos CAS:528814-26-8 Package:100MG,500MG
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Company Name: |
Shanghai Aladdin Bio-Chem Technology Co.,LTD
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Tel: |
18521735133 18521732826; |
Email: |
market@aladdin-e.com |
Products Intro: |
Product Name:(1R,1'R,2S,2'S)-(+)-2,2'-Di-t-butyl-2,3,2',3'-tetrahydro-1,1'-bi-1H-isophosphindole CAS:528814-26-8 Package:100mg/RMB 2162.90;500mg/RMB 4960.00;25mg/RMB 772.90
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(1R,1'R,2S,2'S)-DUANPHOS manufacturers
- (1R,1"R,2S,2"S)-DuanPhos
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- $15.00 / 1KG
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2021-07-02
- CAS:528814-26-8
- Min. Order: 1KG
- Purity: 99%+ HPLC
- Supply Ability: Monthly supply of 1 ton
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| (1R,1'R,2S,2'S)-DUANPHOS Basic information | Reactions |
Product Name: | (1R,1'R,2S,2'S)-DUANPHOS | Synonyms: | (1R,1'R,2S,2'S)-2,2'-Bis(1,1-dimethylethyl)-2,2',3,3'-tetrahydro-1,1'-bi-1H-isophosphindole,99%e.e.;(1R,1'R,2S,2'S)- 2,2'-bis(1,1-diMethylethyl)-2,2',3,3'-tetrahydro-1,1'-Bi-1H-isophosphindole;(1R,1'R,2S,2'S)-(+)-2,2'-Di-t-butyl-2,3,2',3'-tetrahydro-1,1'-bi-1H-isophosphindole (R,R,S,S)-DUANPHOS;1,1'-Bi-1H-isophosphindole, 2,2'-bis(1,1-dimethylethyl)-2,2',3,3'-tetrahydro-, (1R,1'R,2S,2'S)-;RcSp-DuanPhos;(1R,1'R,2S,2'S)-2,2'-di-tert-butyl-2,2',3,3'-tetrahydro-1H,1'H-1,1'-biisophosphindole;(1R,1'R,2S,2'S)-(+)-2,2'-Di-t-butyl-2,3,2',3'-tetrahydro-1,1'-bi-1H-isophosphindole;(1R,1'R,2S,2'S)-DUANPHOS | CAS: | 528814-26-8 | MF: | C24H32P2 | MW: | 382.46 | EINECS: | | Product Categories: | | Mol File: | 528814-26-8.mol | |
| (1R,1'R,2S,2'S)-DUANPHOS Chemical Properties |
Melting point | 214-246 °C | Boiling point | 474.5±45.0 °C(Predicted) | alpha | +19.5 | form | crystal | color | white | optical activity | [α]20/D +18°, c = 1 in chloroform | Sensitive | air sensitive | CAS DataBase Reference | 528814-26-8 |
| (1R,1'R,2S,2'S)-DUANPHOS Usage And Synthesis |
Reactions |
- As a highly electron-donating and conformationally rigid ligand, the rhodium complex of DuanPhos has exhibited remarkably high enantioselectivities and reactivities for the hydrogenation of a variety of functionalized olefins.
- Rhodium/DUANPHOS catalyst used in the synthesis of 2-trifluoromethyl lactic acid by asymmetric hydroformylation.
| Uses | Chiral Quest Phosphine Ligands for Asymmetric Hydrogenation
Catalytic ligand used for:
- Stereoselective synthesis of cyano-substituted dihydropyrroles by annulation of cyanoallenes
- Rhodium-catalyzed intermolecular enantioselective hydroacylation of alkynes to give alpha- and beta-substituted unsaturated ketones by kinetic resolution
- Stereoselective preparation of β-amino nitriles via rhodium-catalyzed asymmetric hydrogenation of amino acrylonitriles
- Stereoselective preparation of anti-1,3-amino alcohols via rhodium-catalyzed asymmetric hydrogenation of β-ketoenamide intermediates
- Stereoselective preparation of acetylaminoindane via rhodium-catalyzed asymmetric hydrogenation of acetylaminoindene
| General Description | (1R,1′R,2S,2′S)-DuanPhos is an electron-rich chiral phosphine ligand mainly for transition metal catalyzed asymmetric hydrogenation. |
| (1R,1'R,2S,2'S)-DUANPHOS Preparation Products And Raw materials |
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