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6-アミノペニシラン酸(551-16-6)

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6-アミノペニシラン酸 製品概要
化学名:6-アミノペニシラン酸
英語化学名:6-Aminopenicillanic acid
别名:6-AMINO-3,3-DIMETHYL-7-OXO-4-THIA-1-AZABICYCLO[3.2.0]HEPTANE-2-CARBOXYLIC ACID;(+)-6-AMINOPENICILLANIC ACID;6-AMINOPENICILLANIC ACID;6-AMINO PENICILLINIC ACID;7-AMINO-3,3-DIMETHYL-6-OXO-2-THIA-5-AZABICYCLO[3.2.0]HEPTANE-4-CARBOXYLIC ACID;(25,5R,6R)-6-AMINO-3,3-DIMETHYL-7-OXO-4-THIA-1-AZABICYCLO[3.2.0]HEPTANE-2-CARBOXYLIC ACID;(2S,5R,6R)-6-AMINO-3,3-DIMETHYL-7-OXO-4-THIA-1-AZABICYCLO-[3.2.0]HEPTANE-2-CARBOXYLIC ACID;aminopenicillanicacid
CAS番号:551-16-6
分子式:C8H12N2O3S
分子量:216.26
EINECS:208-993-4
カテゴリ情報:Chemical Intermediate;Antibiotics for Research and Experimental Use;beta-Lactams (Antibiotics for Research and Experimental Use);Biochemistry;Used as pharmaceutical intermediates;API;Organic acids
Mol File:551-16-6.mol
6-アミノペニシラン酸
6-アミノペニシラン酸 物理性質
融点 198-200 °C (dec.)(lit.)
比旋光度 276.3 º (c=1.2, 0.1N HCl 22 ºC)
沸点 460.2±45.0 °C(Predicted)
比重(密度) 1.3418 (rough estimate)
屈折率 1.6300 (estimate)
貯蔵温度 2-8°C
溶解性2.46g/l
外見 Fine Powder
酸解離定数(Pka)pKa 2.3 (Uncertain)
色White to cream
PH3.4 (100g/l, H2O)
光学活性 (optical activity)[α]22/D +276.3°, c = 1.2 in 0.1 M HCl
水溶解度 Soluble in water and hydrochoric acid.
Merck 14,458
BRN 15080
安定性：Light sensitive
InChIKeyNGHVIOIJCVXTGV-SDKNWNMFSA-N
LogP-3.87 at 22.5℃
CAS データベース551-16-6(CAS DataBase Reference)
EPAの化学物質情報6-Aminopenicillanic acid (551-16-6)
安全性情報
主な危険性 Xn
Rフレーズ 42/43
Sフレーズ 22-36/37-45-37-24-36
WGK Germany 2
RTECS 番号XH8225000
F 10
TSCA Yes
HSコード 29349990
MSDS Information
ProviderLanguage
6-Aminopenicillanic acid English
SigmaAldrich English
ACROS English
ALFA English
6-アミノペニシラン酸 Usage And Synthesis
外観白色～わずかにうすい褐色、結晶～粉末
化学的特性WHITE TO CREAM FINE POWDER
使用(+)-6-Aminopenicillanic Acid is the core structure in penicillins, obtained from the fermentation brew of the Penicillium mold. (+)-6-Aminopenicillanic Acid is used as the main starting block for the preparation of numerous semisynthetic penicillins.
使用6-Aminopenicillanic acid is the basic unit in penicillin?s, which is obtained from the fermentation brew of the Penicillium mold. It acts as a starting material for the preparation of many semisynthetic penicillins. Further, it serves as apharmaceutical intermediate. In addition to this, it is used in antibiotics research and experimental application.
定義ChEBI: A penicillanic acid compound having a (6R)-amino substituent. The active nucleus common to all penicillins, it may be substituted at the 6-amino position to form the semisynthetic penicillins, resulting in a variety of antibacterial and ph rmacologic characteristics.
一般的な説明Chemical structure: ?-lactam
燃焼性と爆発性Non flammable
安全性プロファイルQuestionable carcinogen with experimental tumorigenic data. When heated to decomposition it emits very toxic fumes of NOx and SOx.
純化方法This acid crystallises from water. [Kleppe & Stroninger J Biol Chem 254 4856 1979,Beilstein 27 III/IV 2858.]
Tags:551-16-6