N-エチル-N-ベンジル-m-トルイジン(119-94-8)

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N-エチル-N-ベンジル-m-トルイジン 製品概要
化学名:N-エチル-N-ベンジル-m-トルイジン
英語化学名:Ethylbenzyltoluidine
别名:N-ETHYL-N-(M-TOLYL)BENZYLAMINE;N-ETHYL-N-BENZYL-M-TOLUIDINE;n-ethyl-n-(3-methyl phenyl)-benzenemethanamine;3-(N-Benzyl-N-ethylamino)methylbenzene;3-(N-Benzyl-N-ethylamino)toluene;Benzenemethanamine, N-ethyl-N-(3-methylphenyl)-;m-Toluidine, N-benzyl-N-ethyl-;N-Benzyl-N-ethyl-3-methylaniline
CAS番号:119-94-8
分子式:C16H19N
分子量:225.33
EINECS:204-359-6
カテゴリ情報:Amines;C11 to C38;Nitrogen Compounds;Intermediates of Dyes and Pigments
Mol File:119-94-8.mol
N-エチル-N-ベンジル-m-トルイジン
N-エチル-N-ベンジル-m-トルイジン 物理性質
沸点 161-162 °C(lit.)
比重(密度) 0.770 g/mL at 25 °C(lit.)
屈折率 n20/D 1.5870(lit.)
闪点 171 °F
貯蔵温度 2-8°C
外見 Liquid
酸解離定数(Pka)5.40±0.50(Predicted)
CAS データベース119-94-8(CAS DataBase Reference)
NISTの化学物質情報Benzenemethanamine, n-ethyl-n-(3-methylphenyl)-(119-94-8)
EPAの化学物質情報N-Benzyl-N-ethyl-m-toluidine (119-94-8)
安全性情報
主な危険性 T
Rフレーズ 23/24/25
Sフレーズ 23-26-36/37/39-45
RIDADR UN 2753 6.1/PG 3
WGK Germany 2
TSCA Yes
国連危険物分類 6.1
MSDS Information
ProviderLanguage
Ethylbenzyltoluidine English
SigmaAldrich English
N-エチル-N-ベンジル-m-トルイジン Usage And Synthesis
外観淡褐色~赤褐色の液体
用途有機合成原料。
説明Ethylbenzyltoluidine is a yellowish to lightbrown liquid with an unpleasant odor. Boilingpoint = 230℃; Flash point = 167℃. Insoluble in water.
化学的特性Yellow - light brown liquid.
使用Ethylbenzyltoluidine can be used as an intermediate for acid blue 90, 91, 109 and other dyes.
合成The ratio of N-ethyl-m-toluidine to benzyl chloride is 1: (0.95~1.05) (molar ratio), and Ethylbenzyltoluidine can be obtained after reaction.
職業ばく露This compound is used in dyesynthesis
応急処置Eye Contact: Immediately remove any contactlenses and flush with large amounts of water for at least 15 min, occasionally lifting upper and lower lids. Seek medical attention immediately.Skin Contact: Quickly remove contaminated clothing.Immediately wash area with large amounts of soap andwater. Seek medical attention if symptoms develop andremove the person from exposure. Begin rescue breathing(using universal precautions, including resuscitation mask)if breathing has stopped and CPR if heart action hasstopped. Transfer promptly to a medical facility.Note to physician: Treat for methemoglobinemia.Spectrophotometry may be required for precise determination of levels of methemoglobinemia in urine.
貯蔵Color Code—Blue: Health Hazard/Poison: Storein a secure poison location. Prior to working with thischemical you should be trained on its proper handling andstorage. Store in tightly closed containers in a cool, well-ventilated area away from oxidizers and light. Where possible, automatically pump liquid from drums or other storagecontainers to process containers
輸送方法This compound requires a shipping label of“POISONOUS/TOXIC MATERIALS.” It falls in HazardClass 6.1 and Packing Group III.
不和合性Strong oxidizers.
Short Term ExposureExposure can interfere with the ability of the blood to carry oxygen (methemoglobinemia),causing headaches, dizziness, weakness, a bluish skin color,and even death. This substance can damage the kidneys andbladder, causing painful, bloody urine. Eye contact causesirritation and can lead to permanent damage. Skin contactcan cause a rash and burning feeling
Personal Protective MethodsWear protective gloves andclothing to prevent any reasonable probability of skin contact. Safety equipment suppliers/manufacturers can providerecommendations on the most protective glove/clothingmaterial for your operation. All protective clothing (suits,gloves, footwear, headgear) should be clean, available eachday, and put on before work. Contact lenses should not beworn when working with this chemical. Wear splash-proofchemical goggles and face shield unless full face-piecerespiratory protection is worn. Employees should washimmediately with soap when skin is wet or contaminated.Provide emergency showers and eyewash
Fire ExtinguishingEthylbenzyltoluidine may burn butdoes not readily ignite. Poisonous gases are produced infire. Use dry chemical, carbon dioxide, or alcohol foamextinguishers. Vapors in confined areas may explode whenexposed to fire. Containers may explode in fire. Storagecontainers and parts of containers may rocket great distances, in many directions. If material or contaminated runoff enters waterways, notify downstream users ofpotentially contaminated waters. Notify local health and fireofficials and pollution control agencies. From a secure,explosion-proof location, use water spray to cool exposedcontainers. If cooling streams are ineffective (venting soundincreases in volume and pitch, tank discolors, or shows anysigns of deforming), withdraw immediately to a secure position. If employees are expected to fight fires, they must betrained and equipped in OSHA 1910.156. The only respirators recommended for firefighting are self-contained breathing apparatuses that have full face-pieces and are operatedin a pressure-demand or other positive-pressure mode.
Tags:119-94-8